Method for treatment of corn hulls

• US 4,038,481 A
• Filed: 05/24/1976
• Issued: 07/26/1977
• Est. Priority Date: 05/24/1976
• Status: Expired due to Term

• Current Assignee: Standard Brands, Inc. (Mondelez International, Inc.)
• Original Assignee: Standard Brands, Inc. (Mondelez International, Inc.)
• Inventors: Harris, Donald Wayne, Antrim, Richard Lee
• Primary Examiner(s): Griffin, Ronald W.
• Application Number:
  US05/689,232
• Time in Patent Office: 428 Days
• Field of Search: 536/1, 536/114, 536/120, 536/56, 127/34, 127/37, 127/29
• US Class Current: 536/56
• CPC Class Codes: B01D 11/0288 Applications, solvents
• CPC Class Codes: C08B 1/00 Preparatory treatment of cellulose for making derivatives thereof , e.g. pre-treatment, pre-soaking, activation
• CPC Class Codes: C08B 37/0057 beta-D-Xylans, i.e. xylosaccharide, e.g. arabinoxylan, arabinofuronan, pentosans; (beta-1,3)(beta-1,4)-D-Xylans, e.g. rhodymenans; Hemicellulose; Derivatives thereof
• CPC Class Codes: D21C 5/00 Other processes for obtaining cellulose, e.g. cooking cotton linters obtaining fibres for spinning D01C; Processes characterised by the choice of cellulose-containing starting materials

Abstract

Corn hulls are subjected to a treatment to obtain three fractions therefrom comprising a cellulosic fraction, a hemicellulose fraction and a noncarbohydrate fraction. The noncarbohydrate fraction is characterized as being an organic solvent extract comprising at least about 15 percent of the dry weight of the corn hulls and containing above about 10 percent by weight ferulic acid.

Claims

1. A method for treating corn hulls to obtain a cellulose fraction, a hemicellulose fraction and a noncarbohydrate fraction comprising treating corn hulls with a sufficient amount of alkali to hydrolyze the corn hulls to affect liberation of the hemicellulose fraction so that it may be solubilized in water and to solubilize the noncarbohydrate fraction, recovering a hemicellulose fraction, an organic solvent extract of the noncarbohydrate fraction and an insoluble residue comprising the cellulose fraction.

2. A method for treating corn hulls as defined in claim 1, wherein the treatment is performed under conditions to obtain an amount of the noncarbohydrate fraction comprising at least about 15 percent by weight of the dry weight of the corn hulls, said fraction containing above about 10 percent by weight ferulic acid.

3. A method for treating corn hulls as defined in claim 2, wherein the treatment is performed under conditions to obtain an amount of the noncarbohydrate fraction comprising at from about 20 percent to 30 percent by weight of the dry weight of the corn hulls, said fraction containing from about 10 to about 20 percent by weight ferulic acid.

4. A method for treating corn hulls as defined in claim 2, wherein the corn hulls are subjected to an aqueous alkaline hydrolysis treatment to solubilize the noncarbohydrate and hemicellulose fractions, contacting the resulting solution with a sufficient amount of a water miscible organic solvent to precipitate the hemicellulose and recovering the noncarbohydrate fraction from the organic solvent.

5. A method for treating corn hulls as defined in claim 2, wherein the corn hulls are subjected to an alkaline hydrolysis treatment to dissolve the noncarbohydrate fraction and to liberate the hemicellulose fraction so that it may be solubilized in water, contacting the alkaline hydrolysis reaction product with a water miscible organic solvent to extract the noncarbohydrate fraction and treating the insoluble residue with water to separate the hemicellulose fraction from the cellulose fraction.

6. A method for treating corn hulls as defined in claim 2, wherein the corn hulls are contacted with an alkaline aqueous-miscible organic solvent system which contains insufficient water to substantially solubilize the hemicellulose fraction and thereby extracting the noncarbohydrate fraction and treating the insoluble residue with water to separate the hemicellulose fraction from the cellulose fraction.

7. A method for treating corn hulls as defined in claim 6, wherein the alkaline hydrolysis treatment is performed at a temperature of from about ambient to about 140°

C.

8. A method for treating corn hulls as defined in claim 7, wherein the alkaline hydrolysis treatment is performed at a temperature of from about ambient to about 100°

C.

9. A method for treating corn hulls as defined in claim 6, wherein the resulting solution is contacted with a water miscible solvent having a pH below about 4.

10. A method for treating corn hulls as defined in claim 9, wherein the alkaline aqueous miscible organic solvent containing solubilized noncarbohydrate fraction has a pH below about 3.