Method for producing a laminated high strength sheet

• US 4,039,364 A
• Filed: 07/01/1975
• Issued: 08/02/1977
• Est. Priority Date: 07/05/1974
• Status: Expired due to Term

• Current Assignee: Ole-Bendt Rasmussen
• Original Assignee: Ole-Bendt Rasmussen
• Inventors: Rasmussen, Ole-Bendt
• Primary Examiner(s): Thurlow, Jeffery R.
• Application Number:
  US05/592,273
• Time in Patent Office: 763 Days
• Field of Search: 264/171, 264/173, 264/147, 264/DIG. 47, 264/146, 156/244, 156/229, 156/291, 156/164
• US Class Current: 156/164
• CPC Class Codes: B29C 43/305 Making multilayered articles
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/10 flexible, e.g. blown foils
• CPC Class Codes: B29C 48/19 the layers being joined at their edges
• CPC Class Codes: B29C 48/20 one of the layers being a strip, e.g. a partially embedded strip
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/23 with means for avoiding adhesion of the layers, e.g. for forming peelable layers
• CPC Class Codes: B29C 48/33 with parts rotatable relative to each other
• CPC Class Codes: B29C 48/335 Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles
• CPC Class Codes: B29C 55/023 using multilayered plates or sheets
• CPC Class Codes: B32B 2270/00 Resin or rubber layer containing a blend of at least two different polymers
• CPC Class Codes: B32B 27/00 Layered products comprising a layer of synthetic resin fibrous or filamentary layer made of a synthetic resin B32B5/02; particulate layer made of a synthetic resin B32B5/16; foamed layer made of a synthetic resin B32B5/18
• CPC Class Codes: B32B 27/06 as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to a layer of a particular substance B32B9/045; next to a bituminous or tarry layer B32B11/046; next to a water setting substance layer B32B13/12; next to a metal layer B32B15/08; next to a glass layer B32B17/10; next to a layer formed of natural mineral fibres or particles B32B19/045; next to a wood layer B32B21/08; next to a cellulosic plastic layer B32B23/08; next to a natural or synthetic rubber layer B32B25/08
• CPC Class Codes: B32B 37/00 Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
• CPC Class Codes: Y10S 264/47 Processes of splitting film, webs or sheets

Abstract

A high-strength laminate comprising generally weakly adhered biaxially oriented films, each formed of a blend which exhibits a distinct fibrous morphology with the fibres forming a distinct unidirectional grain when measured on a macro-scale but with the fibre-portions strongly deflected from this direction as seen on a micro-scale and with the unidirectional grain in at least two of the films criss-crossing each other. Producing this laminate by melt attenuating the blend(s) while extruding the latter to films, cross-laminating the layers before or after solidification while they are still in molecularly unoriented state -- except for the weak orientation produced by the melt-attenuation -- and finally strongly biaxially orienting the laminate by stretching in several steps, whereby the stretching is generally uniaxial during each step.

Claims

1. Method for producing a laminated high strength sheet comprising the steps of attenuating while extruding each of at least two layers of at least a blend of two or more polymers containing not more than about 85% of any one of such polymer and at least about 15% of one or more different polymer, the polymers in said blend being sufficiently incompatible as to form upon extrusion of the blend a microscopically visible grain and impart upon solidification a pronounced direction of splittability, before or after solidification of said layers uniting the layers into a common sheet with the grain direction of adjacent layers herein extending in criss-crossing relationship while forming a generally weak bond between said layers, solidifying if not already solid and finally biaxially orienting the solid laminated sheet thus obtained in at least two separate steps each of which is essentially unidirectional with the directions crossing one another at a temperature sufficiently low for maintaining a significant splittability in each layer.

2. A method according to claim 1 characterized in making said bonding a strong adhesive bonding in spots or lines while avoiding adhesive bonding or producing a weak bonding between the remaining portions of the adjacent surfaces.

3. A method according to claim 1, characterized in that the step of uniting the layers comprises supplying to one or both of adjacent sides of at least two layers a release or adhesive substance in spots or stripes.

4. A method according to claim 3, where the sheet consists of at least three layers, characterized in that the stripes or dots of release or adhesive substance are staggered on the two sides of a midlayer.

5. A method according to claim 1, characterized in that it comprises the steps of extruding and attenuating the layers mutually independently before uniting them to a common sheet.

6. A method according to claim 5, characterized in that at least one layer is extruded from a rotating circular extrusion exit slot and given a grain forming an angle with the machine direction while still fluid and is applied to and forewarded by one or more solid preproduced films or tubes with a different direction of grain.

7. A method according to claim 5, characterized in the steps of rotating at least two concentrical tubular streams of molten polymer blends relative to one another during and immediately after the passage through the exit part of an extrusion-die while strongly attenuating said streams to form in each stream a grain of different direction than that of the adjacent stream(s), and subsequently uniting said tubular grainy, still fluid streams after they have left the die through their respective exit slots.

8. A method according to claim 5, characterized in that each grainy layer is solidified before being united to a common sheet.

9. A method according to claim 8, characterized in the steps of extruding a tubular film, attenuating it longitudinally while still fluid, and solidifying it and cutting it helically, unfolding it to a flat film with an oblique grain and uniting said film with one or more equally produced films with the grain of at least two adjacent films in criss-crossing relationship.

10. A method according to claim 8, characterized in the steps of extruding a film, attenuating it predominantly in the transverse direction while still fluid by lateral entering thus giving it a grain of lateral direction, solidifying said film and uniting it with one or more solid films at least one of which has a different direction of grain.

11. A method according to claim 8, characterized in that at least the first phase of the uniting process is combined with at least the first phase of the lateral stretching process.

12. A process according to claim 5, characterized in that the uniting of the layers comprises coextrusion of a lower-melting adhesive polymer on at least one surface of at least one layer.

13. A process according to claim 12, characterized in chosing for the coextruded adhesive polymer a material sufficiently sticky for adjacent layers to be united solely by the stretching process during pressure.

14. A process according to claim 12, characterized in that the adhesive polymer is coextruded in stripes.

15. A process according to claim 12, characterized in the step of coextruding on one of the adjacent surfaces of two layers a continuous ply of an adhesive polymer, and further to provide stripewise or spotwise the other of said surfaces with a release component.

16. A process according to claim 12, characterized in that the adhesive polymer is coextruded in stripes on two adjacent surfaces of two layers with the stripes on one layer lying in criss-crossing relationship with those of the other layer.

17. A process according to claim 1, characterized in that the step of biaxially stretching comprises applying the lateral stretching forces generally evenly distributed over the plane of the sheet.

18. A process according to claim 17, characterized in that the biaxially stretching is carried out in form of several steps of lateral stretching by linear impression to deflect the sheet to a temporarily, evenly distributed pleated configuration of cross section, and one or several steps of longitudinal stretching.

19. A process according to claim 18, characterized in that the temporarily pleated configuration is effectuated by several steps of lateral stretching between grooved rollers, the pleats forming striations that are parallel to or forming a small angle with the longitudinal direction of the sheet, and that the longitudinal stretching is effectuated continuously preferably over a short stretching zone.

20. A process according to claim 19, characterized in that a substantial lateral contraction of the sheet is being allowed during the longitudinal stretching.

21. A process according to claim 19, characterized in that the steps of lateral stretching are essentially finished before the start of longitudinal stretching.

22. A process according to claim 1, characterized in that it comprises the steps of rotating at least two concentrical, tubular streams of molten polymer blends relatively to one another during the passage through an extrusion-die while strongly attenuating said streams to form in each stream a grain of different direction than that of the adjacent stream(s), and subsequently uniting into a laminated sheet said tubular grainy streams while still fluid before leaving the extrusion-die.

23. A process according to claim 22, characterized in that a polymer for controlling the adhesive strength is coextruded between adjacent layers.

24. A process according to claim 1, characterized in that it further comprises th step of collapsing voids formed by the stretching process by pressure-rolling the sheet after the biaxially stretching.