Flat battery

• US 4,042,760 A
• Filed: 04/02/1975
• Issued: 08/16/1977
• Est. Priority Date: 04/02/1975
• Status: Expired due to Term

• Current Assignee: Polaroid Corporation (PLR IP Holdings LLC)
• Original Assignee: Polaroid Corporation (PLR IP Holdings LLC)
• Inventors: Land, Edwin H.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US05/564,227
• Time in Patent Office: 867 Days
• Field of Search: 136/111, 136/175, 136/138, 136/10, 136/108, 136/134-135, 136/10, 429/162, 429/199, 429/200, 429/201, 429/209, 429/229, 429/232
• US Class Current: 429/162
• CPC Class Codes: H01M 4/06 Electrodes for primary cells
• CPC Class Codes: H01M 6/48 with bipolar electrodes

Abstract

A planar primary battery particularly suited for a photographic application characterized in exhibiting high current drain capacities and improved manufacturability. The battery structure incorporates at least one electrode present in aqueous slurry form as a particulate dispersion of active material and an inorganic particulate additive in combination with electrolyte. This slurry combination, functioning in the absence of dispersing or binding agents present in the form of hydrophilic polymers and the like, provides for batteries exhibiting enhanced performance characteristics.

Claims

1. In a planar battery of a variety having at least one cell including positive and negative electrodes and a planar electrolyte ion permeable separator positioned therebetween, the improvement wherein at least one of said electrodes is formed comprising:

a planar current collector having a surface for association with active electrode material; and

an aqueous slurry of active electrode material particles in aqueous electrolyte, said slurry including an inorganic substantially nonconductive particulate dispersant.

2. The improved battery of claim 1, in which said dispersant is titanium dioxide.

3. The improved battery of claim 1 in which said aqueous slurry electrode is characterized by the absence of a hydrophilic binder agent.

4. The improved battery of claim 1 in which said dispersant is present in an amount effective to disperse said active electrode material particles and promote the adhesion thereof with said current collector surface.

5. The improved battery of claim 1 in which said active electrode material particles are manganese dioxide and carbon.

6. The improved battery of claim 5 in which said aqueous electrolyte includes ammonium chloride and zinc chloride.

7. The improved battery of claim 6 in which said dispersant is titanium dioxide.

8. The improved battery of claim 7 in which said manganese dioxide and carbon are present, respectively, in a weight-to-weight ratio from between about 6:

1 and 12;

1.

9. The improved battery of claim 8 in which said titanium dioxide is present with respect to said carbon in a weight-to-weight ratio of about 4:

1.

10. The improved battery of claim 1 in which said active electrode material particles are zinc.

11. The improved battery of claim 10 in which said aqueous electrolyte includes ammonium chloride, zinc chloride and mercuric chloride.

12. The improved primary battery of claim 1 in which said inorganic additive is selected as a material nonreactive with said aqueous electrolyte.

13. In a planar primary battery of a variety having at least one cell including positive and negative electrodes and a planar electrolyte ion permeable separator positioned therebetween, the improvement comprising:

a positive electrode including;

a planar cathode current collector carrying on one surface, in order, a first cathode stratum comprising a particulate dispersion of cathode mix particles in a binder matrix, and

a second cathode stratum comprising a slurry of particulate cathode mix particles and a substantially nonconducting particulate inorganic additive disposed within aqueous electrolyte.

14. The improved primary battery of claim 13 in which said particulate inorganic additive of said second cathode stratum is titanium dioxide.

15. The improved primary battery of claim 14 in which said second cathode stratum is characterized by the absence of a hydrophilic polymer binder agent.

16. In a planar primary battery of a variety having at least one cell including positive and negative electrodes and a planar electrolyte ion permeable separator positioned therebetween, the improvement comprising:

a negative electrode including;

a planar anode current collector carrying on one surface, in order, a first anode stratum comprising a particulate dispersion of metallic anode particles in a binder matrix, and

a second anode stratum comprising a slurry of metallic anode particles and a particulate substantially nonconducting inorganic additive disposed within aqueous electrolyte.

17. The improved primary battery of claim 16 in which said particulate inorganic additive of said anode second stratum is titanium dioxide.

18. A planar primary battery comprising at least one cell including, in combination:

a positive electrode comprising a planar cathode current collector carrying, in order, a first cathode stratum comprising a particulate dispersion of manganese dioxide and carbon particles in a binder matrix, and a second cathode stratum comprising a slurry of manganese dioxide and carbon particles in aqueous electrolyte, said slurry including a quantity of titanium dioxide effective to disperse said manganese dioxide and said carbon particles and to promote the adherence of said slurry to said first cathode stratum, and said electrolyte including ammonium chloride and zinc chloride;

a planar negative electrode including a planar anode current collector carrying a zinc anode stratum; and

a planar electrolyte ion permeable separator positioned intermediate said positive and negative electrodes, aqueous electrolyte including ammonium chloride and zinc chloride being present intermediate said separator and said zinc anode stratum.

19. The improved primary battery of claim 18 in which said first cathode stratum manganese dioxide and carbon particles are present, respectively, in a weight-to-weight ratio of about 25:

1 and said second cathode stratum manganese dioxide and carbon particles are present, respectively, in a weight-to-weight ratio from between about 6;

1 and 12;

1.

20. The improved primary battery of claim 19 in which said titanium dioxide is present with respect to said carbon of said slurry in a weight-to-weight ratio of about 4:

1.

21. A planar primary battery including at least one cell positioned intermediate the opposed surfaces of a first and a second current collector, and which includes, in combination:

a negative aqueous slurry electrode comprising a substantially uniform particulate dispersion of metallic anode particles and a particulate inorganic additive in aqueous electrolyte, the metallic particles present in a concentration per unit area effective to provide an electrically conductive dispersion, said additive being present in an amount effective as a dispersant promoting adherence of said dispersion with said first collector and the electrolyte present in intimate surface contact with the metallic particles in a concentration effective to provide an ionically conductive dispersion;

a positive aqueous slurry electrode comprising a substantially uniform particulate dispersion of cathodic mix particles and a particulate inorganic additive in a substantially uniform distribution of aqueous electrolyte, the cathodic particles present in a concentration per unit area effective to provide an electrically conductive dispersion, said additive present in an amount effective as a dispersant promoting adherence of said positive electrode dispersion with said second collector, and the electrolyte present in intimate surface contact with the cathodic particles in a concentration effective to provide an ionically conductive dispersion; and

an electrolyte ion permeable separator positioned intermediate the negative and positive electrodes and in contact with said electrolyte of the electrodes.

22. The planar primary battery of claim 21 in which the said particulate inorganic additive of at least one of said slurry electrodes is titanium dioxide.

23. The planar primary battery of claim 22 in which said slurry electrodes are characterized in the absence of a hydrophilic binder agent.

24. The planar primary battery of claim 21 in which said metallic anode particles are zinc;

said cathodic mix particles are manganese dioxide and carbon; and

said aqueous electrolyte includes ammonium chloride and zinc chloride.