Electroplating method

• US 4,043,878 A
• Filed: 06/14/1976
• Issued: 08/23/1977
• Est. Priority Date: 06/14/1976
• Status: Expired due to Term

• Current Assignee: John L. Raymond, Nayan S. Shah
• Original Assignee: John L. Raymond, Robert Z. Reath
• Inventors: Ehrsam, Robert F.
• Primary Examiner(s): Tufariello, T. M.
• Application Number:
  US05/696,073
• Time in Patent Office: 435 Days
• Field of Search: 204/16, 204/45 R, 204/DIG. 2
• US Class Current: 205/109
• CPC Class Codes: C25D 15/02 Combined electrolytic and electrophoretic processes with charged materials

Abstract

A layer of metal having a plurality of discrete particles of a finely divided solid non-metallic material uniformly dispersed throughout the metal layer is electrodeposited onto the surface of a substrate metal by first applying a tertiary amine oxide surfactant to the surface of the particles of finely divided non-metallic solid material, or by first introducing the said tertiary amine oxide surfactant into the electrolyte solution. The said particles and the said metal are then co-deposited onto the said substrate from an aqueous electrolyte solution containing metaliferous cations of the said metal in solution and the said particles in suspension therein. Specifically, the tertiary amine oxide surfactant employed is selected from the group having the chemical structure: ##STR1## Where R₁ is an alkyl, alkene or alkyne radical having from 6 to 22 carbon atoms,

R₂ is an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms, and

R₃ is alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms.

Claims

1. In the method of electrolytically depositing on the surface of a substrate metal a layer of a metal having a plurality of discrete particles of a finely divided solid non-metallic material uniformly dispersed throughout said layer, said metal layer and said particles being co-deposited from an aqueous electrolyte solution containing said metal in solution and said particles in suspension therein, said electrolyte solution containing a surface active agent deposition promoter for the non-metallic material and being agitated to maintain the particles uniformly in suspension therein, the improvement which comprises employing as said deposition promoter a surface active agent selected from the group having the chemical structure:

##STR4## Where R₁ is an alkyl, alkene or alkyne radical having from 6 to 22 carbon atoms,

R₂ is an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms, and

R₃ is an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms.

2. The method according to claim 1 in which the surface active agent employed as the deposition promoter is cetyl dimethyl amine oxide.

3. The method according to claim 1 in which the surface active agent employed as the deposition promoter is oleyl dimethyl amine oxide.

4. The method according to claim 1 in which the surface active agent employed as the deposition promoter is n-decyl dimethyl amine oxide.

5. The method according to claim 1 in which the surface active agent employed as the deposition promoter is myristyl dipropyl amine oxide.

6. The method according to claim 1 in which the surface active agent employed as the deposition promoter is cetyl diethyl amine oxide.

7. The method according to claim 1 in which the surface active deposition promoter and the particles of non-metallic material are vigorously mixed together with an approximately equal amount of water prior to being introduced into the aqueous electrolyte solution.

8. The method according to claim 1 in which the surface active deposition promoter and the particles of non-metallic material are introduced directly into the aqueous electrolyte solution.

9. The method according to claim 1 in which the finely divided non-metallic material has a particle size of from about 5 to about 150 microns.

10. The method according to claim 1 in which the amount of the surface active deposition promoter employed comprises from about 0.05 to about 5.0% by weight of the finely divided non-metallic material.

11. The method according to claim 1 in which the amount of the surface active deposition promoter employed comprises from about 0.5 to about 0.75% by weight of the finely divided non-metallic material.