Low viscosity poly(epoxide-caprolactone) polyols

• US 4,045,474 A
• Filed: 10/07/1975
• Issued: 08/30/1977
• Est. Priority Date: 10/07/1975
• Status: Expired due to Term

• Current Assignee: Union Carbide Corporation (Dow, Inc.)
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Taller, Robert Arthur, Elder, Decker Kuykendall
• Primary Examiner(s): Anderson, Harold D.
• Assistant Examiner(s): Nielsen, E. A.
• Application Number:
  US05/620,399
• Time in Patent Office: 693 Days
• Field of Search: 260/78.3 R, 260/484 A
• US Class Current: 560/126
• CPC Class Codes: C08G 18/4277 Caprolactone and/or substituted caprolactone
• CPC Class Codes: C08G 18/6407 Reaction products of epoxy resins with at least equivalent amounts of compounds containing active hydrogen with amines C08G18/643; C08G18/42, C08G18/48 take precedence
• CPC Class Codes: C08G 63/08 Lactones or lactides
• CPC Class Codes: C08L 2666/18 Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C08L 67/04 Polyesters derived from hydroxycarboxylic acids, e.g. lactones C08L67/06 takes precedence

Abstract

High functionality polyol compositions that have a low viscosity of less than 5,000 cks. at 130° F. and an equivalent weight of at least 150 are useful for the formation of high performance coatings. These are produced by reacting a mixture of at least two polycaprolactone polyols having a hydroxyl number from about 180 to about 600 and a diepoxide.

Claims

1. An adduct of a polycaprolactone polyol and a cycloaliphatic diepoxide comprising the reaction product of (a) at least two polycaprolactone polyols differing in average hydroxyl number by an amount from 250 to 400 and having average hydroxyl numbers from about 180 to about 600 and (b) a cycloaliphatic diepoxide, said adduct having a viscosity of less than 5,000 cks. at 130°

F. and an equivalent weight of at least 150.

2. An adduct as claimed in claim 1, wherein the mole ratio of polycaprolactone polyols to cycloaliphatic diepoxide is from 2.5:

1 to 4;

1.

3. An adduct as claimed in claim 1 wherein the mole ratio of the two polycaprolactone polyols to the cycloaliphatic diepoxide is 2:

2;

1, respectively.

4. An adduct as claimed in claim 1 wherein the mole ratio of the two polycaprolactone polyols to the cycloaliphatic diepoxide is 1.5:

1;

1, respectively.

5. An adduct as claimed in claim 1 wherein the difference in average hydroxyl numbers between said polycaprolactone polyols is from 250 to 350.

6. An adduct as claimed in claim 1 wherein said cycloaliphatic diepoxide has the structure:

##STR4## wherein R is hydrogen or alkyl of 1 to 4 carbon atoms;

R°

is a valence bond or a hydrocarbon radical having from 1 to 5 carbon atoms; and

a is zero or one.