Sulfolanyloxy alkyl-polyalkyl-siloxanes

• US 4,049,675 A
• Filed: 06/30/1975
• Issued: 09/20/1977
• Est. Priority Date: 06/30/1975
• Status: Expired due to Term

• Current Assignee: OSI Specialties, Inc.
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Kanner, Bernard, Prokai, Bela
• Primary Examiner(s): Thomas, Jr., James O.
• Assistant Examiner(s): Siegel, A.
• Application Number:
  US05/592,128
• Time in Patent Office: 813 Days
• Field of Search: 260/332.1, 260/448.2 S, 260/448.2 H, 260/448.2 N
• US Class Current: 549/4
• CPC Class Codes: C08G 77/28 sulfur-containing groups
• CPC Class Codes: C08G 77/392 containing sulfur
• CPC Class Codes: C08J 2375/08 from polyethers
• CPC Class Codes: C08J 2483/00 Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
• CPC Class Codes: C08J 9/0061 characterized by the use of several polymeric components
• CPC Class Codes: C08L 75/08 from polyethers
• CPC Class Codes: C08L 83/08 containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen

Abstract

A particular class of sulfolanyloxyalkyl-polyalkylsiloxanes are provided which consists essentially of: (1) monofunctional siloxy units (M°) the respective silicon atoms of which have two alkyls bonded thereto, the third silicon-bonded organic group being alkyl or sulfolanyloxyalky; (2) an average of from about 0.5 to about 10 moles of difunctional dialkylsiloxy units for every two moles of M°; from zero up to an average of about 10 moles, for every two moles of M°, of difunctional monoalkylsiloxy units in which the second organic group bonded to silicon is sulfolanyloxyalkyl, provided an average of at least about 0.5 and no more than about 10 moles of sulfolanyloxyalkyl groups are present in the sulfolanyloxyalkyl-polyalkylsiloxanes for every two moles of M°. The sulfolanyloxyalkyl-polyalkylsiloxanes are generally useful as surfactant providing compositions and find particular application as foam-stabilizing components of high resilience polyurethane foam formulations in which the organic polyol reactant comprises a polyether polyol reactant having an average primary hydroxyl content of at least about 35 mole percent based on the total moles of hydroxyl groups contained in said polyether polyol. The siloxanes of the invention are also useful as surfactant components of high resilience foam formulations in which the polyol reactant additionally comprises a polymer/polyether polyol.

Claims

1. Sulfolanyloxyalkyl-polyalkylsiloxanes having the average composition, ##STR19## wherein:

R is alkyl of one to four carbon atoms;

c has a value from two to eight;

x has an average value from about 0.5 to about 10;

y has an average value from about 0.5 to about 10; and

R'"'"', R², R³ and R⁴ are independently hydrogen or alkyl having from one to four carbon atoms

2. Sulfolanyloxyalkyl-polyalkylsiloxanes as defined in claim 1 in which c has a value of no more than six.

3. Sulfolanyloxyalkyl-polyalkylsiloxanes as defined in claim 1 in which c has a value of three.

4. Sulfolanyloxyalkyl-polyalkylsiloxanes as defined in claim 1 in which x has an average value from about one to about 8.5, and y has an average value no more than about six.

5. Sulfolanyloxyalkyl-polyalkylsiloxanes as defined in claim 4 in which c has a value of three or four.

6. Sulfolanyloxyalkyl-polyalkylsiloxanes as defined in claim 1 in which each of R¹ through R⁴ of said sulfolanyloxyalkyl groups is hydrogen.

7. Sulfolanyloxyalkyl-polymethylsiloxanes having the average composition. ##STR20## wherein:

Me is methyl;

x has an average value from about 0.5 to about 10;

y has an average value from about 0.5 to about 10; and

Q has the formula, ##STR21## in which c has a value from two to six.

8. Sulfolanyloxyalkyl-polymethylsiloxanes as defined in claim 7 in which c has a value of three.

9. Sulfolanyloxyalkyl-polymethylsiloxanes as defined in claim 7 in which x has an average value of from about one to about 8.5, y has an valve no more than about six, and c has a value of three or four.

10. Sulfolanyloxyalkyl-polymethylsiloxanes having the average composition. ##STR22## wherein:

Me is methyl;

x has an average value from about 0.5 to about 10;

y is zero or has an average value up to about 8; and

Q has the formula, ##STR23## in which c has a value from two to six.

11. Sulfolanyloxyalkyl-polymethylsiloxanes having the average composition, ##STR24## wherein:

q and r are positive numbers provided the sum q+r per average mole of said composition is two;

x has an average value from about 0.5 to about 10;

y is zero or a positive number provided the average value of the sum y+q is at least about 0.5 and no more than about 10;

Me is methyl; and

Q has the formula, ##STR25## in which c has a value from two to six.