Degumming process for triglyceride oils

• US 4,049,686 A
• Filed: 03/10/1976
• Issued: 09/20/1977
• Est. Priority Date: 03/10/1975
• Status: Expired due to Term

• Current Assignee: Lever Brothers Company (Unilever PLC)
• Original Assignee: Lever Brothers Company (Unilever PLC)
• Inventors: Segers, Jacobus Cornelis, Ringers, Hendrik Johan
• Primary Examiner(s): Douglas, Winston A.
• Assistant Examiner(s): Niebling, John F.
• Application Number:
  US05/665,526
• Time in Patent Office: 559 Days
• Field of Search: 260/424, 260/420
• US Class Current: 554/204
• CPC Class Codes: C11B 3/04 with acids

Abstract

Triglyceride oils are degummed according to a two-stage process, in which in the first step a substantially concentrated solution of an acid or an anhydride, having a pH of at least 0.5 as measured at 20° C in a one molar aqueous solution, is dispersed in the oil, and in a second step 0.2 to 5 wt.% of water is dispersed in the mixture obtained and an aqueous sludge is separated from the oil after the water has been in contact with the oil-acid-mixture for at least 5 minutes at a temperature below 40° C.

Claims

1. A process for removing phosphatides from triglyceride oils which are substantially liquid at 40°

C. comprising the steps of dispersing an acid or acid anhydride in the oil, said acid or acid anhydride having a pH of from 0.5 to 7 as measured at 20°

C. in a one molar aqueous solution and said oil at a temperature of from 20°

to 100°

C., adjusting the temperature of the mixture to the range of from the lowest temperature at which the oil remains a liquid to 40°

C., dispersing from 0.2 to 5 percent by weight of water in the mixture;

maintaining the temperature of the mixture of oil, acid and water from 5 minutes to several days; and

, thereafter separating an aqueous sludge containing the phosphatides from the oil.

2. Process according to claim 1 in which the temperature of the oil is from 65°

to 90°

C. when the acid or anhydride is added.

3. Process according to claim 1 in which an aqueous solution of an edible acid containing 10 to 50% of the acid of water is used.

4. Process according to claim 3, in which an aqueous citric acid solution is used.

5. Process according to claim 4, in which from 0.001 to 0.5% by weight of citric acid, calculated as dry acid, is added to the oil.

6. Process according to claim 5, in which 0.001 to 0.01% by weight of citric acid is added to a crude extracted oil.

7. Process according to claim 5, in which 0.1 to 0.3% by weight of citric acid is added to an oil, from which the hydratable phosphatides have been substantially removed.

8. Process according to claim 1, in which before separating the aqueous sludge, the oil, water and acid mixture is adjusted to 20°

C. - 35°

C.

9. Process according to claim 1, in which 0.5 to 3% by weight of water is added to the oil.

10. Process according to claim 9, in which 1 to 2% by weight of water is added to the oil.

11. Process according to claim 8, in which before the separation of the aqueous sludge, the mixture of oil, water and acid is maintained for at least 0.5 hours.

12. Process according to claim 1, in which the aqueous sludge is separated from the oil by centrifuging.

13. Process according to claim 12, in which the mixture of oil, acid and water after the contact time is heated to a temperature of 60°

C. to 90°

C. in a sufficiently short time to avoid conversion of the gums to their high temperature phase and thereafter the mixture is immediately centrifuged.

14. Process according to claim 13, in which the heating is carried our in about from 1 second to about 1 minute.

15. Process according to claim 1, in which the process is carried out continuously.

16. Process according to claim 1, in which an oil chosen from the group consisting of soybean oil, rapeseed oil, sesame seed oil, sunflower seed oil, rice bran oil, grapeseed oil, coconut oil, cottonseed oil, groundnut oil, linseed oil, maize oil, palm oil, palm kernel oil, safflower oil, sal fat and shea fat is used.