System for obtaining hydrogen and oxygen from water using solar energy

• US 4,053,576 A
• Filed: 05/19/1975
• Issued: 10/11/1977
• Est. Priority Date: 05/19/1975
• Status: Expired due to Term

• Current Assignee: Regents of The University of Minnesota (University of Minnesota)
• Original Assignee: Regents of The University of Minnesota (University of Minnesota)
• Inventors: Fletcher, Edward A.
• Primary Examiner(s): Vertiz, O. R.
• Assistant Examiner(s): Langel, Wayne A.
• Application Number:
  US05/578,404
• Time in Patent Office: 876 Days
• Field of Search: 203/DIG. 1, 202/234, 159/1.5, 23/252 R, 23/260, 423/648, 423/579
• US Class Current: 423/579
• CPC Class Codes: C01B 13/0207 Water
• CPC Class Codes: C01B 3/045 in gaseous phase
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02P 20/133 Renewable energy sources, e.g. sunlight

Abstract

A system for producing and separating hydrogen and oxygen from water in which water is pumped through a preferentially permeable walled vessel heated to a high temperature by a solar energy concentrator. The water dissociates at high temperatures. Lower molecular weight components, especially hydrogen, diffuse preferentially through the vessel walls and are drawn off and separated. Oxygen may be separated from the products which do not diffuse through the walls by conventional separation techniques. A system is provided for making use of solar energy to produce storable fuels for use during periods of no sunshine.

Claims

1. Apparatus for obtaining hydrogen and oxygen from water utilizing solar energy, said apparatus comprising:

A. a water-dissociation chamber having a wall preferentially permeable to the passage of lower molecular weight dissociation components including hydrogen,

B. means connected to the dissociation chamber for supplying water to said chamber,

C. solar energy concentrating means focused on said dissociation chamber for heating said chamber to a temperature at which water is dissociated into steam, molecular hydrogen, molecular oxygen, atomic hydrogen, atomic oxygen and hydroxyl,

D. means connected to the dissociation chamber for withdrawing oxygen enriched dissociation products from said chamber,

E. a non-permeable casing spaced from and enclosing said dissociation chamber wall and forming a hydrogen enriched dissociation product collection chamber,

F. means connected to said collection chamber for withdrawing hydrogen enriched dissociation product from said chamber,

G. cooling means for cooling said oxygen enriched dissociation products and partially liquefying the same, and

H. gas-liquid separation means for separating gaseous oxygen from the cooled oxygen enriched dissociation products.

2. Apparatus according to claim 1 further characterized in that said dissociation chamber wall is opaque and radiation absorptive.

3. Apparatus according to claim 2 further characterized in that said dissociation chamber wall consists essentially of a platinum group metal.

4. Apparatus according to claim 1 further characterized in that:

A. said dissociation chamber wall is porous, whereby hydrogen-enriched dissociation products are preferentially diffused through said wall,

B. cooling means are provided for cooling said hydrogen enriched dissociation products and partially liquefying the same, and

C. separate gas-liquid separation means are provided for separating gaseous hydrogen from the cooled hydrogen-enriched dissociation products.

5. Apparatus according to claim 4 further characterized in that said dissociation chamber wall consists essentially of a refractory metal oxide.

6. Apparatus according to claim 1 further characterized in that:

A. said cooling means is a heat exchanger,

B. said water supply means passes through said heat exchanger, and

C. said dissociation product withdrawing means pass through said heat exchanger in heat exchanging relation to said supply means.

7. Apparatus according to claim 1 further characterized in that said solar energy concentrating means is a concave reflector.

8. Apparatus according to claim 1 further characterized in that said non-permeable casing is transparent to solar radiation.

9. A method for obtaining hydrogen and oxygen from water utilizing solar energy, said method comprising:

A. supplying water to a dissociation zone, having a wall preferentially permeable to the passage of lower molecular weight dissociation components, including hydrogen

B. causing said water within said zone to dissociate into steam, molecular hydrogen, molecular oxygen, atomic hydrogen, atomic oxygen and hydroxyl by heating by means of concentrated solar energy to a temperature at which water is dissociated,

C. separating hydrogen enriched dissociation product from said dissociation zone by preferential diffusion through said wall, and collecting said hydrogen enriched product,

D. withdrawing said hydrogen enriched dissociation product,

E. withdrawing oxygen enriched dissociation products remaining in said dissociation zone and cooling to liquefy a portion of the same, and

F. separating gaseous oxygen from the resulting mixture.

10. A method according to claim 9 further characterized in that said water is at least partially vaporized prior to introduction to said dissociation zone.

11. A method according to claim 10 further characterized in that said water is at least partially vaporized and said dissociation products are cooled by passage of the water and said dissociation products in heat exchanging relation.

12. A method according to claim 9 further characterized in that:

A. the hydrogen enriched dissociation products are cooled to reliquefy a portion of the same, and

B. gaseous hydrogen is separated from the resulting mixture.

13. A method according to claim 12 further characterized in that the liquefied dissociation mixture from which hydrogen and oxygen have been separated is recyled to said dissociation zone.

14. A method according to claim 9 further characterized in that said water is heated to a dissociation temperature between about 1500°

to 3000°

K.