Silicone contact lens with hydrophilic surface treatment

• US 4,055,378 A
• Filed: 04/10/1975
• Issued: 10/25/1977
• Est. Priority Date: 12/31/1971
• Status: Expired due to Term

• Current Assignee: Agfa-Gevaert AG (Agfa-Gevaert N.V.)
• Original Assignee: Agfa-Gevaert AG (Agfa-Gevaert N.V.)
• Inventors: Feneberg, Paul, Krekeler, Ulrich
• Primary Examiner(s): Rubin, David H.
• Application Number:
  US05/566,603
• Time in Patent Office: 929 Days
• Field of Search: 351/160, 351/177, 204/164, 204/165
• US Class Current: 351/160.00R
• CPC Class Codes: B29D 11/00038 Production of contact lenses
• CPC Class Codes: C08J 2383/04 Polysiloxanes
• CPC Class Codes: C08J 7/123 Treatment by wave energy or particle radiation C08J7/18 takes precedence
• CPC Class Codes: C08J 7/18 using wave energy or particle radiation
• CPC Class Codes: G02C 7/04 Contact lenses for the eyes disinfection or sterilisation of contact lenses A61L12/00

Abstract

A contact lens has a concave surface which is adapted to contact the cornea of an eye and a convex surface which is adapted to contact the eyelid. At least the convex surface of the lens possesses hydrophilic characteristics although the concave surface of the lens preferably possesses such characteristics also. In any event, the convex surface of the lens has a greater wettability than the concave surface thereof. The more highly hydrophilic character of the convex surface prevents the deposition thereon of fatty substances carried by the tear fluid which may cause opacity of the lens. The less highly hydrophilic character of the concave surface decreases the forces responsible for maintaining the lens in position in the eye, although not to such an extent that the lens does not remain properly positioned. These forces have been found to be a source of irritation in that they produce the feeling of a foreign body in the eye and the decrease in these forces occasioned by the less highly hydrophilic character of the concave surface of the lens enables this feeling to be eliminated. The concave surface of the lens need not be as highly hydrophilic as the convex surface thereof since the quantity of tear fluid which comes into contact with the concave surface is considerably less than that which comes into contact with the convex surface. The maximum contact angle for the convex surface of the lens, as measured with distilled water, should be about 65°. The surfaces of the lens may be made hydrophilic by chemical means or by bombardment with charged particles.

Claims

1. A contact lens, comprising a body which includes a silicone elastomer and silicone dioxide as a filler, said body having a concave surface adapted to face the cornea of an eye, and said body having a convex surface adapted to face the eyelid, said convex surface possessing hydrophilic characteristics, and the contact angle for said convex surface being smaller than the contact angle for said concave surface, said contact angles being measured with distilled water, and said contact angle for said concave surface having a value such that said body is movable relative to the cornea of an eye when said body is positioned on the cornea, said convex surface having been made hydrophilic by a treatment which included subjecting said convex surface to the action of activated gas ions in an atmosphere consisting at least predominantly of oxygen when said convex surface had an outer layer of said silicon elastomer, and said gas ions having impinged first regions of said outer layer and having had an energy such that said outer layer was destroyed at said first regions and the silicon dioxide filler of said body was exposed at said first regions, said gas ions also having impinged second regions of said outer layer and having had an energy such that said outer layer transformed to silicon dioxide at said second regions, and said convex surface having undergone an improvement in the hydrophilic characteristics thereof due to the exposure of the silicon dioxide filler at said first regions and the transformation to silicon dioxide at said second regions.

2. A lens as defined in claim 1, said impingements imparting a roughened texture to said convex surface;

and wherein said treatment is carried out in such a manner that substantially the entire surface area of the convex surface of said body has a roughened texture.

3. A lens as defined in claim 1, wherein said concave surface has been subjected to said treatment.

4. A lens as defined in claim 3, impingements imparting a roughened texture to said surfaces;

and wherein said treatments of said convex and concave surfaces are carried out in such a manner that substantially the entire surface areas of the concave and convex surfaces of said body have roughened textures.

5. A lens as defined in claim 1, wherein said ions are formed and activated by gaseous discharge and comprise oxygen ions.

6. A lens as defined in claim 1, said silicon elastomer including a silicon-oxygen and a silicon-carbon bond;

and wherein the kinetic energy of said ions is at least equal to the energy of one of said bonds.

7. A lens as defined in claim 6, wherein said kinetic energy is between about 3 and 50 electron volts.

8. A lens as defined in claim 1, wherein the pressure in said atmosphere is between about 10^-1 and 10³ torr.

9. A lens as defined in claim 1, wherein said atmosphere consists essentially of oxygen.

10. A lens as defined in claim 1, wherein said convex surface is contacted with water subsequent to subjecting said convex surface to said action.

11. A lens as defined in claim 10, wherein the contacting step is carried out for a period of at least 12 hours.

12. A lens as defined in claim 10, wherein said water is in the form of water vapor.

13. A lens as defined in claim 1, said concave surface having been subjected to said treatment, and said impingements imparting a roughened texture to said surfaces;

and wherein the roughness of said convex surface exceeds the roughness of said concave surface.

14. A lens as defined in claim 13, wherein the roughness of said convex surface is of the order of micron.

15. A lens as defined in claim 13, wherein the roughness of said concave surface is a maximum of about 0.5 microns.

16. A lens as defined in claim 15, wherein the roughness of said concave surface is a maximum of about 0.2 microns.

17. A lens as defined in claim 1, wherein said contact angle for said convex surface is at most about 65°

.

18. A lens as defined in claim 17, wherein said contact angle for said convex surface is a minimum of about 10°

.

19. A lens as defined in claim 18, wherein said contact angle for said convex surface is between about 30°

and 45°

.

20. A lens as defined in claim 1, wherein said contact angle for said concave surface is at most about 75°

.

21. A lens as defined in claim 20, wherein said contact angle for said concave surface is a minimum of about 60°

.

22. A lens as defined in claim 21, wherein said contact angle for said concave surface is a minimum of about 70°

.

23. A lens as defined in claim 1, wherein said contact angles for said surface portions differ by a minimum of about 10°

.

24. A lens as defined in claim 1, wherein said contact angles for said surface portions differ by a minimum of about 5°

.