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Photocurable compositions containing group via aromatic onium salts

  • US 4,058,401 A
  • Filed: 12/09/1975
  • Issued: 11/15/1977
  • Est. Priority Date: 05/02/1974
  • Status: Expired due to Term
First Claim
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1. Photocurable compositions consisting essentially ofA. an epoxy resin polymerizable to a higher molecular weight state,B. from 0.1 to 15% by weight of a photodecomposable aromatic onium salt of a Group VIa element capable of effecting the cure of epoxy resin when exposed to radiant energy wherein said aromatic onium salt has the formula


  • space="preserve" listing-type="equation">[(R).sub.a (R.sup.1).sub.b (R.sup.2).sub.c X].sub.d .sup.+ [MQ.sub.e ].sup.-(e-f)
where R is a monovalent aromatic organic radical, R1 is a monovalent organic aliphatic radical selected from alkyl, cycloalkyl and substituted alkyl, R2 is a polyvalent organic radical forming a heterocyclic or fused ring structure selected from aliphatic radicals and aromatic radicals, X is a Group VIa element selected from sulfur, selenium and tellurium, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive, c is a whole number equal to 0 or 1, where the sum of a + b + c is a value equal to 3 or the valence of X,d = e - ff = valence of M and is an integer equal to from 2 to 7 inclusivee is >

f and is an integer having a value up to 8 andC. from 0 to 100 parts by weight of filler, per 100 parts of epoxy resin.

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