Catalyst withdrawal

• US 4,059,502 A
• Filed: 12/17/1975
• Issued: 11/22/1977
• Est. Priority Date: 12/17/1975
• Status: Expired due to Term

• Current Assignee: Cities Service Research and Development Company
• Original Assignee: Cities Service Research and Development Company
• Inventors: James, Lewis C.
• Primary Examiner(s): Levine, Herbert
• Application Number:
  US05/641,852
• Time in Patent Office: 706 Days
• Field of Search: 208/143, 208/157, 208/152, 208/DIG. 1, 222/54, 302/16, 302/66, 302/14
• US Class Current: 208/152
• CPC Class Codes: B01J 8/0015 Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
• CPC Class Codes: Y10S 208/01 Automatic control

Abstract

In an upflow, ebullated bed reactor using a heterogeneous catalyst, a transport liquid compatible with the catalyst and the reactor feedstock is used. During the addition of fresh catalyst, a heated slurry of catalyst and transport liquid is pumped into the reactor under conditions to minimize (a) the temperature difference between the slurry and the reactor and (b) exposure of the fresh catalyst to a deactivating elevated temperature. During catalyst withdrawal, the temperature of the reactor effluent stream is controlled by mixing with a transport liquid. Measurement and flowability of the resultant mixture is thus assured.

Claims

1. In a heterogeneous catalytic process wherein a solid catalyst is withdrawn from a reactor during normal operations, a method controlling the catalyst withdrawal from the reactor comprising

pumping a transport fluid in a first conduit line equipped with a temperature controller and temperatures sensor, at a temperature T₁,

exiting a portion of the reactor contents, comprising catalyst and liquid reactants at a temperature T₂, through a second conduit line that joins said first line, thus mixing the transport fluid and reactor effluent,

measuring the temperature of the mixture, and

controlling the flow of transport liquid and reactor effluent, and thus the flow of said catalyst, by controlling the temperature of the resultant stream, until sufficient catalyst is withdrawn from the reactor.

2. The method of claim 1 wherein the solid catalyst is used in the hydroprocessing of heavy residual hydrocarbons and the transport liquid is a liquid stream resulting from the downstream processing of said hydroprocessed heavy residual hydrocarbons.