Hot melt thermoplastic adhesive foam system

• US 4,059,714 A
• Filed: 08/02/1976
• Issued: 11/22/1977
• Est. Priority Date: 08/02/1976
• Status: Expired due to Term

• Current Assignee: Nordson Corporation
• Original Assignee: Nordson Corporation
• Inventors: Stumphauzer, William C., Scholl, Charles H., Janner, John R. Jr.
• Primary Examiner(s): Whitby, Edward G.
• Application Number:
  US05/710,377
• Time in Patent Office: 477 Days
• Field of Search: 264/45.9, 264/46.4, 259/95, 259/6, 156/78, 156/79, 156/331, 156/334, 156/500, 222/146 HE, 261/28, 261/84, 261/93, 261/DIG. 26, 428/310, 428/339
• US Class Current: 428/317.5
• CPC Class Codes: B27G 11/00 Applying adhesives or glue to surfaces of wood to be joined
• CPC Class Codes: B29C 65/40 Applying molten plastics, e.g. hot melt using welding bar combined with hot gases B29C65/12; by moulding B29C65/70
• CPC Class Codes: B29C 65/4815 Hot melt adhesives, e.g. thermoplastic adhesives
• CPC Class Codes: B29C 66/43 Joining a relatively small portion of the surface of said articles B29C66/45 takes precedence
• CPC Class Codes: B29C 66/472 said single elements being substantially flat
• CPC Class Codes: C09J 5/08 using foamed adhesives
• CPC Class Codes: Y10S 261/26 Foam
• CPC Class Codes: Y10T 428/249984 Adhesive or bonding component contains voids
• CPC Class Codes: Y10T 428/249987 With nonvoid component of specified composition
• CPC Class Codes: Y10T 428/269 including synthetic resin or polymer layer or component

Abstract

A novel method and several different unique modifications of apparatus are disclosed for manufacturing a novel adhesive product. The product which results from use of the foam is a pair of substrates adhered together by compressed foam. The adhesive foam is created by intimately mixing air or any relatively inert gas with thermoplastic adhesive while the adhesive is in the liquid state and then pressurizing the liquid/gas mixture so as to force the gas into solution with the liquid adhesive. The liquid adhesive is subsequently dispensed at atmospheric pressure with the result that the gas is released from the solution and becomes entrapped in the adhesive to form a homogenous closed cellular adhesive foam.

Claims

1. The method of bonding with a hot melt thermoplastic adhesive foam which comprises,

heating solid thermoplastic adhesive to convert it to a liquid state,

mechanically agitating the liquid adhesive in the presence of a gas so as to obtain a mixture of said gas in the liquid adhesive,

pressurizing the mixture of liquid and gas so as to force the gas into solution with the liquid adhesive,

dispensing the liquid and gas solution at atmospheric pressure whereby said gas is released from solution and forms a hot adhesive foam, and

compressing said hot adhesive foam between two substrates to force gas from the foam and to form a bond between said substrates.

2. The method of claim 1 in which said mixture is placed under a pressure of at least 90 pounds per square inch to force said gas into solution.

3. The method of claim 1 in which said mixture is placed under a pressure of approximately 300 pounds per square inch to force said gas into solution.

4. The method of adhering a pair of substrates which comprises

heating a solid thermoplastic adhesive to convert it to a liquid state,

mechanically agitating the liquid adhesive in the presence of a gas so as to obtain a suspension of said gas in the liquid adhesive,

pressurizing the suspension of liquid and gas so as to force the gas into solution with the liquid adhesive,

dispensing the liquid and gas solution onto a first substrate at a pressure below the solution maintenance pressure of said gas and adhesive solution whereby said gas is released from solution and forms an adhesive foam, and

compressing said adhesive foam between said first substrate and a second substrate before it cools so as to effect adhesion of said substrate upon subsequent cooling of said adhesive foam.

5. The method of bonding with a hot melt thermoplastic adhesive foam which comprises

heating solid thermoplastic adhesive to convert it to a liquid state,

mechanically agitating the liquid adhesive in the presence of air so as to obtain a suspension of air in the liquid adhesive,

pressurizing the suspension of liquid and air so as to force the air into solution with the liquid adhesive,

dispensing the liquid and air solution at atmospheric pressure whereby said air is released from solution and forms a hot adhesive foam,

compressing said hot melt adhesive foam between two substrates to force gas from the foam, and

cooling the compressed adhesive to form upon solidification a bond between said substrates.

6. The method of claim 5 in which said suspension is placed under a pressure of at least 90 pounds per square inch to force said air into solution.

7. The method of claim 5 in which said suspension is placed under a pressure of approximately 300 pounds per square inch to force said air into solution.

8. The method of adhering a pair of substrates which comprises

heating a solid thermoplastic adhesive to convert it to a liquid state,

mechanically agitating the liquid adhesive in the presence of air so as to obtain a suspension of air in the liquid adhesive,

pressurizing the suspension of liquid and air so as to force the air into solution with the liquid adhesive,

dispensing the liquid and air solution onto a first substrate at atmospheric pressure whereby said air is released from solution and forms an adhesive foam, and

compressing said adhesive foam between said first substrate and a second substrate so as to force a portion of said air from said foam and upon cooling of said foam, effect adhesion of said substrates.

9. The method of bonding with a hot melt thermoplastic adhesive foam which comprises

heating solid thermoplastic adhesive to convert it to a liquid state,

mechanically agitating the liquid in the presence of a gas so as to obtain a suspension of said gas in the liquid adhesive,

pressurizing the suspension of liquid and gas so as to force the gas into solution with the liquid adhesive,

dispensing the liquid and gas solution at a pressure below the solution maintenance pressure of said gas and adhesive solution whereby said gas is released from solution and forms a hot adhesive foam, and

compressing said hot adhesive foam between two substrates to force gas from the foam and to form a bond between the substrates.

10. The method of claim 9 in which said suspension is placed under a pressure of at least 90 pounds per square inch to force said gas into solution.

11. The method of claim 9 in which said suspension is placed under a pressure of approximately 300 pounds per square inch to force said gas into solution.

12. An article of manufacture comprising,

a first substrate,

a second substrate adhered to said first substrate by a hot melt thermoplastic adhesive foam compressed between said substrate by the method of claim 9 in which said adhesive foam has a thickness of as little as approximately 0.009 in. after being subjected to four pounds per square inch while in the open state.

13. Apparatus for manufacturing a hot melt thermoplastic adhesive foam comprising

means for heating solid thermoplastic adhesive to convert said solid adhesive to a liquid state,

means for agitating said liquid adhesive in the presence of a gas so as to distribute said gas throughout said liquid adhesive,

means for pressurizing said liquid and gas dispersion so as to force said gas into solution with the liquid adhesive, and

means for dispensing the liquid and gas solution at a pressure below the solution maintenance pressure of said gas and adhesive solution whereby said gas is released from solution as said liquid cools and forms a solid adhesive foam.

14. The apparatus of claim 13 in which said agitating and pressurizing means comprises a gear pump.

15. The apparatus of claim 13 in which said agitating and pressurizing means comprises a two stage gear pump.

16. The apparatus of claim 13 in which said heating means comprises a heated reservoir for receiving and melting solid thermoplastic adhesive.

17. The apparatus of claim 13 in which said dispensing means comprises a dispensing gun having a outlet nozzle and a selectively openable valve for controlling flow from said gun.

18. The apparatus of claim 13 in which said dispensing gun is a continuous flow gun in which gas and liquid adhesive solution is continuously circulated through said gun when said valve is closed.

19. The apparatus of claim 18 in which said continuous flow gun includes a pair of tubes for flowing gas and liquid adhesive solution between said pressurizing and said gun.

20. The apparatus of claim 19 in which one of said tubes is contained within the other of said tubes.

21. Apparatus for manufacturing a hot melt thermoplastic adhesive foam comprising

means for heating solid thermoplastic adhesive to convert said solid adhesive to a liquid state,

means for agitating and pressurizing said liquid in the presence of a gas so as to force said gas into solution with the liquid adhesive, and

means for dispensing the liquid and gas solution at a pressure below the solution maintenance pressure of said gas and adhesive solution whereby said gas is released from solution as said liquid cools and forms a solid adhesive foam.

22. The apparatus of claim 21 in which said agitating and pressurizing means comprises a gear pump.

23. The apparatus of claim 21 in which said agitating and pressurizing means comprises a two stage gear pump.

24. The apparatus of claim 21 in which said heating means comprises a heated reservoir for receiving and melting solid thermoplastic adhesive.

25. The apparatus of claim 21 in which said dispersion means comprises a dispensing gun having an outlet nozzle and a selectively openable valve for controlling flow from said gun.

26. The apparatus of claim 25 in which said dispensing gun is a continuous flow gun in which gas and liquid adhesive solution is continuously circulated between said pressurizing means and said gun when said valve is closed.

27. The apparatus of claim 26 in which said continuous flow gun includes a pair of tubes for flowing gas and liquid adhesive solution between said pressurizing means and said gun.

28. The apparatus of claim 27 in which one of said tubes is contained within the other of said tubes.

29. The method of bonding with a hot melt thermoplastic adhesive having an extended open time in a formed uncompressed state and a short set time in a formed compressed state, which method comprises:

heating solid thermoplastic adhesive to convert it to a liquid state,

mechanically agitating the liquid adhesive in the presence of a gas so as to obtain a suspension of gas in the liquid adhesive,

pressurizing the suspension of liquid and gas so as to force the gas into solution with the liquid adhesive,

dispensing the liquid and gas solution at atmospheric pressure onto a substrate such that the dissolved gas comes out of solution and forms a hot cellular foam adhesive of extended open time,

compressing the hot cellular foam adhesive between said substrate and second substrate such that a substantial portion of the gas entrapped in said foam is released to atmosphere and the set time of the adhesive foam is substantially reduced by said compression, and

cooling the compressed adhesive to form upon solidification a bond between said substrates.

30. The method of claim 29 in which a compressive pressure of four pounds per square inch upon said adhesive foam is operative to reduce the adhesive to a thin film of approximately 0.009 in. thickness disposed between the substrates.

31. The method of bonding with a hot melt thermoplastic adhesive foam which comprises

heating solid thermoplastic adhesive to convert it to a liquid state,

obtaining a suspension of gas in the liquid adhesive,

pressurizing the suspension of liquid and gas so as to force the gas into solution with the liquid adhesive,

dispensing the liquid and gas solution at a pressure below the solution maintenance pressure of said gas and adhesive solution whereby said gas is released from solution and forms a hot adhesive foam, and

compressing said hot adhesive foam between two substrates to force gas from the foam and to form a bond between said substrates.

32. The method of claim 31 in which said suspension is placed under a pressure of at least 90 pounds per square inch to force said gas into solution.

33. The method of claim 31 in which said suspension is placed under a pressure of approximately 300 pounds per square inch to force said gas into solution.

34. The method of adhering a pair of substrates which comprises

heating a solid thermoplastic adhesive to convert it to a liquid state,

obtaining a suspension of gas in the liquid adhesive,

pressurizing the suspension of liquid and gas so as to force the gas into solution with the liquid adhesive,

dispensing the liquid and gas solution onto a first substrate at a pressure below the solution maintenance pressure of said gas and adhesive solution whereby said gas is released from solution and forms an adhesive foam, and

compressing said adhesive foam between said first substrate and a second substrate so as to force a portion of the gas from said foam and upon cooling of said foam, effect adhesion of said substrates.

35. The method of claim 34 in which said suspension is placed under a pressure of at least 90 pounds per square inch to force said gas into solution.

36. The method of claim 35 in which said suspension is placed under a pressure of approximately 300 pounds per square inch to force said gas into solution.