Pneumatic chromatograph

• US 4,059,994 A
• Filed: 11/26/1976
• Issued: 11/29/1977
• Est. Priority Date: 11/26/1976
• Status: Expired due to Term

• Current Assignee: The Foxboro Company (Schneider Electric SE)
• Original Assignee: The Foxboro Company (Schneider Electric SE)
• Inventors: Kalinoski, Richard W., Karas, Edwin L., Prescott, Robert C., Annino, Raymond
• Primary Examiner(s): Myracle, Jerry W.
• Assistant Examiner(s): Kreitman, Stephen A.
• Application Number:
  US05/745,392
• Time in Patent Office: 368 Days
• Field of Search: 73/23.1, 73/23, 23/232 R, 23/232 C, 23/254 R, 137/624.14
• US Class Current: 73/23.35
• CPC Class Codes: G01N 30/20 using a sampling valve
• CPC Class Codes: G01N 30/24 Automatic injection systems
• CPC Class Codes: G01N 30/461 with serial coupling of separation columns
• CPC Class Codes: G01N 30/8658 Optimising operation parameters

Abstract

An all-pneumatic process chromatograph having a pneumatically-actuated sample-injection valve, an orifice connected in the column output line to develop a pressure signal corresponding to fluid density, a pneumatic amplifier for strengthening the pressure signal, and pneumatically-operated control means for developing a periodic sample-valve actuating signal and for selecting a particular peak of interest at a controllable time following injection of the sample. The pneumatic control means includes means automatically operable to adjust the time of peak selection in response to changes in actual peak elution time. The temperature-sensitive elements of the apparatus are contained in a chamber which is heated by a source of steam heat, with the rate of heat transfer being regulated pneumatically to maintain a relatively constant temperature within the chamber.

Claims

1. In industrial instrumentation apparatus of the type including a pressure line arranged to carry a pneumatic measurement signal representing a measurement such as the concentration of eluting components from a chromatographic analyzer and wherein the measurement signal passes through maximum and/or minimum values at least one of which is desired to be detected and retained for subsequent functions;

that improvement which comprises;

a force-balanceable member;

means for applying to said member a first force corresponding to said measurement signal;

feedback means to apply to said balanceable member a feedback force opposing said first force;

said feedback means including pressure storage means to receive a pneumatic feedback signal for developing said feedback force;

pneumatic sensing means adjacent said balanceable member for producing a pneumatic feedback signal responsive to changes in the force balance of said member; and

pressure-transmitting means connecting said sensing means to said pressure storage means;

said pressure-transmitting means including check-valve means to allow flow of pneumatic fluid in one direction between said sensing means and said pressure storage means to provide that the feedback pressure in said pressure storage means tracks said measurement signal as said measurement signal varies towards one of said values, said check-valve means serving to prevent flow in the opposite direction between said sensing means and said pressure storage means so as to trap in said pressure storage means a pressure corresponding to said one value after the measurement varies away from said one value.

2. Apparatus as claimed in claim 1, wherein said check-valve means is operative to permit the flow of fluid from said sensing means to said pressure storage means, whereby to detect and store a measurement peak.

3. Apparatus as claimed in claim 1, including a second pressure storage means for developing a second feedback force on said balanceable member;

second check-valve means connected between said sensing means and said second pressure storage means permitting the flow of fluid in said opposite direction between said second pressure storage means and said sensing means; and

means for activating one of said check-valve means prior to activation of the other check-valve means to provide for the detection and storage of a minimum signal value prior to the detection and storage of a subsequent signal peak.