Thin film electrochemical electrode and cell

• US 4,062,750 A
• Filed: 12/18/1974
• Issued: 12/13/1977
• Est. Priority Date: 12/18/1974
• Status: Expired due to Term

• Current Assignee: James Francis Butler
• Original Assignee: James Francis Butler
• Inventors: Butler, James Francis
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US05/534,049
• Time in Patent Office: 1,091 Days
• Field of Search: 204/195 P, 204/195 B, 204/15, 204/279, 204/280, 204/195, 204/290 R, 204/290 F
• US Class Current: 257/253
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors

Abstract

A thin film polarographic oxygen sensor, in which a number of thin film microcathodes are deposited in holes in a thin film layer of silicon dioxide formed on a silicon substrate. A single thin film anode layer is deposited on the insulating layer and is insulated thereby from the cathodes. Preferably the microcathodes and the anode are located in a well in the thin film insulating layer, the well being filled flush to its surface with electrolyte, and having a thin film polymer filter membrane deposited thereover. Contacts to the anode and cathodes may be punched through a thin film insulating layer on the back of the wafer, the cathode contact being thereby connected to the substrate, and the anode contact being insulated from the substrate by an encircling thin film layer of silicon dioxide and extending through to the anode metallization layer. With appropriate choice of electrode, electrolyte and membrane materials, the cell may also be used as a pH sensor, a CO₂ sensor, a specific ion sensor, or to detect or sense other substances in solution. Single electrode units may also be formed by depositing thin film electrode materials on appropriate substrates.

Claims

1. An electro-chemical cell comprising:

a. a conducting substrate having a first face having a first thin film insulating layer thereon,

b. said first insulating layer having a plurality of small holes therein, and a plurality of thin film microcathodes located in said holes, said microcathodes being electrically connected to said substrate,

c. a continuous thin film anode layer on said first insulating layer and surrounding said microcathodes, said anode layer being electrically insulated from said microcathodes and said substrate by said first insulating layer,

d. a cathode contact connected electrically to said substrate and thereby being electrically connected to said cathodes,

e. an anode contact electrically connected to said anode layer,

f. a layer of electrolyte located over said microcathodes and said anode layer and connecting the same,

3. An electro-chemical cell according to claim 1 wherein said substrate includes a second face opposite said first face and having a second insulating layer thereon, said second insulating layer having a cathode contact hole therein, said cathode being located in said cathode contact hole.

5. An electro-chemical cell according to claim 3 wherein said conductive substrate is doped silicon, and said first and second insulating layers and said wall are all silicon dioxide.

6. An electro-chemical cell according to claim 1 wherein said microcathodes are of gold, and said anode layer is of silver, said cell further including a layer of silver chloride on said anode layer, said membrane being a gas permeable membrane.

7. An electro-chemical cell according to claim 1 wherein said membrane is a polymer membrane formed by depositing a selected material over said electrolyte and then polymerizing such material.

9. An electro-chemical cell according to claim 1 wherein said first insulating layer includes a well therein, at least said first electrode being located in said well.

2. g. and a membrane of selected permeability covering said electrolyte.

4. An electro-chemical cell according to claim 2 wherein said second insulating layer, said substrate, and said first insulating layer include aligned holes therein extending through to said anode layer, said anode contact being located in said aligned holes, said hole in said conductive substrate having a wall of a thin film insulating material which insulates said anode contact against contact with said conductive substrate.

8. An electro-chemical cell having a conductive substrate having first and second opposed faces, a first thin film insulating layer on said first face and a second thin film insulating layer on said second face, first and second electrodes arranged over said first face, said first electrode being electrically connected to said substrate and said second electrode being insulated from said substrate and said first electrode by said first insulating layer, said second insulating layer having a hole therein, a contact in second hole and electrically connected to said substrate thereby forming an electrical connection to said first electrode, said second insulating layer, said substrate and said first insulating layer having aligned holes therein, a further contact in said aligned holes and extending to said second electrode, the hole in said substrate having a wall of a thin film insulating material to insulate said further contact from said substrate.

10. An electro-chemical cell according to claim 8 wherein said first electrode comprises a plurality of thin film microcathodes located in small holes in said first insulating layer, said second electrode comprises a continuous thin film anode on said first insulating layer in said well and surrounding said microcathodes but insulated therefrom by said first insulating layer, a layer of electrolyte filling said well to a level flush with its top, and a thin film membrane of selected permeability covering said well and said first insulating layer surrounding said well.

12. The invention according to claim 10 including an electrolyte filling said well, and a membrane of selected permeability covering said well and the insulating layer surrounding said well.

11. A thin film electrode structure comprising a conductive substrate having a first face and a second face opposed to said first face, a first thin film insulating layer on said first face and having a well therein, a second thin film insulating layer on said second face, a thin film electrode in said well and electrically connected to said substrate, said second insulating layer having a hole therein, and a contact located in said hole and being in electrical contact with said substrate, said contact thereby being electrically connected to said electrode.

13. A thin film electrode structure comprising a conductive substrate having a first face and a second face opposed to said first face, a first thin film insulating layer on said first face, a second thin film insulating layer on said second face, an electrode over said first face and insulated from said substrate by said first insulating layer, said first and second insulating layers and said substrate including aligned holes therein, a contact located in said aligned holes and extending from said second insulating layer through to said electrode and being connected thereto, said substrate having a thin film insulating layer defining the wall of the hole therein and insulating said contact from said substrate.