Polyamide blends having improved processing characteristics

• US 4,062,819 A
• Filed: 09/07/1976
• Issued: 12/13/1977
• Est. Priority Date: 09/07/1976
• Status: Expired due to Term

• Current Assignee: Union Carbide Corporation (Dow, Inc.)
• Original Assignee: Emery Industries, Inc.
• Inventors: O'Brien, William L., Mains, Harold E., Williams, Frederick R.
• Primary Examiner(s): Rzucidlo, Eugene C.
• Application Number:
  US05/720,535
• Time in Patent Office: 462 Days
• Field of Search: 260/18 N, 260/857 TW, 260/78 A, 260/78 L
• US Class Current: 525/420.5
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers

Abstract

The flow characteristics and rheological properties of high molecular weight thermoplastic polyamides are significantly improved by blending therewith a small amount of a polyamide derived from high molecular weight dibasic acids. In addition to improving the processability of the thermoplastic resin, the blends and manufactured articles produced therefrom have other desirable properties.

Claims

1. A method for improving the flow characteristics and rheological properties of a nylon resin which comprises blending therewith from 0.01% to 20% by weight of a high molecular weight polyamide additive having an amine value less than 3 and obtained by the reaction of a high molecular weight aliphatic or cycloaliphatic dibasic acid containing from 18 to 52 carbon atoms and up to 30 weight percent, based on total dibasic acid charge, of a short-chain, saturated, aliphatic dibasic acid having from 2 to 13 carbon atoms with a stoichiometric amount of an aliphatic, saturated diamine having from 2 to 10 carbon atoms or a mixture of said diamines.

2. The method of claim 1 where the polyamide additive has a number average molecular weight from about 5,000 to 50,000 and a softening point in the range 100°

C to 240°

C.

3. The method of claim 1 wherein the nylon resin is selected from the group consisting of nylon 4, nylon 6, nylon 6,6, nylon 6,9, nylon 6,10, nylon 6,12, nylon 9, nylon 11 and nylon 12.

4. The method of claim 1 wherein the polyamide is derived from a high molecular weight dibasic acid containing 75% or more C₃₆ dimer acid obtained by the dimerization of C₁₈ unsaturated monocarboxylic acids.

5. The method of claim 4 wherein the high molecular weight dibasic acid has an acid value in the range 180 to 215, saponification value in the range 190 to 205 and neutral equivalent from 265 to 310.

6. The method of claim 5 wherein the high molecular weight dibasic acid is hydrogenated and contains 90% or more C₃₆ dimer acid.

7. The method of claim 4 wherein the short-chain, saturated, aliphatic dibasic acid contains from 6 to 13 carbon atoms and constitutes from 1 to 20 weight percent of the total dibasic acid charge and the diamine is a mixture of two diamines, said diamines differing by at least three carbon atoms with the longer chain diamine constituting from about 5% to 35%, based on equivalents, of the total diamine charge.

8. The method of claim 7 wherein the polyamide additive has a number average molecular weight in the range 10,000 to 35,000, a softening point in the range 150°

C to 210°

C and amine value less than 1.

9. The method of claim 8 wherein the nylon resin is selected from the group consisting of nylon 4, nylon 6, nylon 6,6, nylon 6,9, nylon 6,10, nylon 6,12, nylon 9, nylon 11 and nylon 12.

10. A thermoplastic polyamide resin blend having improved flow characteristics and rheological properties comprising 80% to 99.99% by weight of a nylon resin and 0.01% to 20% by weight of a polyamide additive having an amine value less than 3 and obtained by the reaction of a high molecular weight aliphatic or cycloaliphatic dibasic acid having from 18 to 52 carbon atoms and up to 30 weight percent, based on the total dibasic acid charge, of a short-chain, saturated aliphatic dibasic acid having from 2 to 13 carbon atoms with a stoichiometric amount of an aliphatic, saturated diamine having from 2 to 10 carbon atoms or a mixture of said diamines.

11. The resin blend of claim 10 wherein the nylon is selected from the group consisting of nylon 4, nylon 6, nylon 6,6, nylon 6,9, nylon 6,10, nylon 6,12, nylon 9, nylon 11, and nylon 12 and the polyamide additive has a number average molecular weight from about 5,000 to 50,000 and a softening point in the range 100°

C - 240°

C.

12. The resin blend of claim 11 wherein the polyamide additive is derived from a high molecular weight dibasic acid containing 75% or more C₃₆ dimer acid obtained by the dimerization of C₁₈ unsaturated monocarboxylic acids, 1 to 20 weight percent, based on the total dibasic acid charge, of a short-chain, saturated, aliphatic dibasic acid having from 6 to 13 carbon atoms and a mixture of two diamines, said diamines differing by at least three carbon atoms with the longer chain diamine constituting from about 5% to 35%, based on equivalents, of the total diamine charge.

13. The resin blend of claim 12 wherein the polyamide additive comprises from 0.1% to 10% by weight of the blend and has a number average molecular weight in the range 10,000 to 35,000, a softening point in the range 150°

C to 210°

C and amine value less than 1.

14. The resin blend of claim 13 wherein the polyamide is derived from a high molecular weight dibasic acid having an acid value in the range 180 to 215, saponification in the range 190 to 205 and neutral equivalent from 265 to 310 and the diamine is a mixture of ethylenediamine and hexamethylenediamine.

15. The resin blend of claim 14 wherein the high molecular weight dibasic acid is hydrogenated and contains 90% or more C₃₆ dimer acid.