Method of watering plants and/or feeding nutrients to plants

• US 4,067,714 A
• Filed: 12/13/1976
• Issued: 01/10/1978
• Est. Priority Date: 07/07/1975
• Status: Expired due to Term

• Current Assignee: CAW Industries Incorporated
• Original Assignee: CAW Industries Incorporated
• Inventors: Willard, John Wesley Sr.
• Primary Examiner(s): Hart, Charles N.
• Assistant Examiner(s): Lander, Ferris H.
• Application Number:
  US05/750,240
• Time in Patent Office: 393 Days
• Field of Search: 44/1 R, 44/1 B, 44/6, 44/27, 252/446, 71/1, 71/24, 71/27, 71/63, 71/64 C, 71/64 SC, 47/1 R, 47/48.5, 47/58, 47/DIG. 10
• US Class Current: 71/24
• CPC Class Codes: A01G 23/02 Transplanting, uprooting, felling or delimbing trees delimbing standing trees A01G3/00
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 3/02 Keeping cut flowers fresh chemically
• CPC Class Codes: A01N 59/00 Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
• CPC Class Codes: A01N 59/06 Aluminium; Calcium; Magnesium; Compounds thereof
• CPC Class Codes: A01N 65/00 Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof containing compounds of determined constitution A01N27/00 - A01N59/00
• CPC Class Codes: C05D 3/00 Calcareous fertilisers C05D7/00 takes precedence
• CPC Class Codes: C05D 5/00 Fertilisers containing magnesium C05D7/00 takes precedence
• CPC Class Codes: C05F 11/02 from peat, brown coal, and similar vegetable deposits
• CPC Class Codes: C05G 1/00 Mixtures of fertilisers belonging individually to different subclasses of C05
• CPC Class Codes: C05G 3/00 Mixtures of one or more fertilisers with additives not having a specially fertilising activity
• CPC Class Codes: C09K 17/12 Water-soluble silicates, e.g. waterglass
• CPC Class Codes: C09K 17/48 Organic compounds mixed with inorganic active ingredients, e.g. polymerisation catalysts
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y10S 47/11 The application of protective coatings to plants
• CPC Class Codes: Y10S 71/903 Soil conditioner

Abstract

Plants are watered with water containing a catalytically effective amount of a novel catalyst to promote growth, yield and/or beauty. The watered plants are more vigorous and resistant to disease and/or adverse environmental conditions. In a preferred variant, the water may also contain water soluble catalyst treated lignite. Plant nutrients may be present in the water and fed to the plants at the time of watering. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. The preparation of the novel catalyst and the water soluble catalyst treated lignite is described in detail hereinafter.

Claims

1. A method of watering plants comprising watering the plants with water containing a catalytically effective amount of a catalyst, the said catalyst being prepared by a process comprising

admixing a water soluble alkali metal silicate with an aqueous medium containing a dissolved substance which is a source of calcium ion and a dissolved substance which is a source of magnesium ion,

the aqueous medium containing said dissolved substances in amounts to provide between about 1 ×

10^-4 and 1 ×

10^-1 mole per liter each of calcium ion and magnesium ion,

the aqueous medium containing said dissolved substances in amounts to provide a molar ratio of calcium ion to magnesium ion between about 2.0;

1.0 and 1.0;

2.0,

the alkali metal silicate having an alkali metal oxide to silicon dioxide ratio between about 0.9;

1.0 and less than 2.0;

1.0 and being admixed with the aqueous medium in an amount of about 0.05-2 moles per liter,

reacting the alkali metal silicate with said dissolved substances providing calcium ion and magnesium ion to produce an aqueous suspension of finely divided particles of the reaction product,

admixing a micelle-forming surfactant with the aqueous medium in an amount to form catalyst micelles comprising said finely divided particles upon agitating the aqueous medium, and

agitating the aqueous medium containing the finely divided particles and surfactant to form said catalyst micelles.

2. The method of claim 1 wherein in the process for preparing the catalyst, said ratio of calcium ion to magnesium ion is between about 1.5:

1.0 and 1.0;

1.5.

3. The method of claim 1 wherein in the process for preparing the catalyst, said ratio of calcium ion to magnesium ion is about 1.0:

1.0.

4. The method of claim 1 wherein in the process for preparing the catalyst, the alkali metal silicate is admixed with an aqueous medium containing said dissolved substances in amounts to provide between about 1 ×

10^-3 and 6 ×

10^-3 mole per liter each of calcium ion and magnesium ion.

5. The method of claim 1 wherein in the process for preparing the catalyst, the alkali metal silicate is admixed with an aqueous medium containing said dissolved substances in amounts to provide between about 2.5 ×

10^-3 and 3.0 ×

10^-3 mole per liter each of calcium ion and magnesium ion.

6. The method of claim 1 wherein in the process for preparing the catalyst, about 0.2-0.3 mole per liter of the alkali metal silicate is admixed with the aqueous medium.

7. The method of claim 1 wherein in the process for preparing the catalyst, the alkali metal silicate has an alkali metal oxide to silicon dioxide ratio between about 0.9:

1.0 and 1.2;

1.0.

8. The method of claim 1 wherein in the process for preparing the catalyst, the alkali metal silicate has an alkali metal oxide to silicon dioxide ratio of about 1.0:

1.0.

9. The method of claim 1 wherein in the process for preparing the catalyst, about 0.001-0.1 mole per liter of the surfactant is admixed with the aqueous medium.

10. The method of claim 1 wherein in the process for preparing the catalyst, the surfactant comprises sulfated castor oil.

11. The method of claim 1 wherein in the process for preparing the catalyst, the alkali metal silicate is admixed with an aqueous medium containing said dissolved substances in amounts to provide between about 1 ×

10^-3 and 6 ×

10^-3 mole per liter each of calcium ion and magnesium ion, the ratio of calcium ion to magnesium ion is between about 1.5;

1.0 and 1.0;

1.5, about 0.1-1 mole per liter of the alkali metal silicate is admixed with the aqueous medium, and the alkali metal silicate has an alkali metal oxide to silicon dioxide ratio between about 0.9;

1.0 and 1.2;

1.0.

12. The method of claim 1 wherein in the process for preparing the catalyst, the alkali metal silicate is admixed with an aqueous medium containing said dissolved substances in amounts to provide between about 2.5 ×

10^-3 and 3.0 ×

10^-3 mole per liter each of calcium ion and magnesium ion, the aqueous medium contains about equimolar amounts of calcium ion and magnesium ion, about 0.2-0.3 mole per liter of the alkali metal silicate is admixed with the aqueous medium, and the alkali metal silicate has an alkali metal oxide to silicon dioxide ratio of about 1.0;

1.0.

13. The method of claim 12 wherein in the process for preparing the catalyst, the alkali metal metasilicate is sodium metasilicate having an alkali metal oxide to silicon dioxide ratio of about 1.0:

1.0.

14. The method of claim 12 wherein in the process for preparing the catalyst about 0.03-0.07 mole per liter of the surfactant is admixed with the aqueous medium.

15. The method of claim 14 wherein in the process for preparing the catalyst, the surfactant comprises sulfated castor oil.

16. The method of claim 15 wherein in the process for preparing the catalyst, the alkali metal metasilicate is sodium metasilicate having a sodium oxide to silicon dioxide ratio of about 1.0:

1.0.

17. The method of claim 16 wherein in the process for preparing the catalyst, at least 25% of the hydroxy groups of the castor oil are sulfated, and about 0.03-0.07 mole per liter of the sulfated castor oil is admixed with the aqueous medium.

18. The method of claim 12 wherein in the process for preparing the catalyst, the alkali metal silicate is sodium metasilicate and it is admixed with an aqueous medium containing said dissolved substances in amounts to provide about 2.9 ×

10^-3 mole per liter of calcium ion and about 2.7 ×

10^-3 mole per liter of magnesium ion, about 0.25 mole per liter of sodium metasilicate having a sodium oxide to silicon dioxide ratio of about 1.0;

1.0 is admixed with the aqueous medium, the aqueous medium contains not more than 10 parts per million by weight of carbonate ion and bicarbonate ion, the surfactant comprises sulfated castor oil and at least 50% of the hydroxy groups of the castor oil are sulfated, and about 0.05 mole per liter of the sulfated castor oil is admixed with the aqueous medium.

19. The method of claim 1 wherein the water used in watering the said plants also contains catalyst treated lignite, the lignite being pretreated with an aqueous medium containing the said catalyst defined in claim 1 until it is soluble in the said water.

20. The method of claim 19 wherein in the process for preparing the catalyst, the alkali metal silicate is admixed with an aqueous medium containing said dissolved substances in amounts to provide between about 1 ×

10^-3 and 6 ×

10^-3 mole per liter each of calcium ion and magnesium ion, the ratio of calcium ion to magnesium ion is between about 1.5;

1.0 and 1.0;

1.5, about 0.1-1 mole per liter of the alkali metal silicate is admixed with the aqueous medium, and the alkali metal silicate has an alkali metal oxide to silicon dioxide ratio between about 0.9;

1.0 and 1.2;

1.0.

21. The method of claim 19 wherein in the process for preparing the catalyst, the alkali metal silicate is sodium metasilicate and it is admixed with an aqueous medium containing said dissolved substances in amounts to provide between about 2.5 ×

10^-3 and 3.0 ×

10^-3 mole per liter each of calcium ion and magnesium ion, the aqueous medium contains about equimolar amounts of calcium ion and magnesium ion, about 0.2-0.3 mole per liter of the sodium metasilicate is admixed with the aqueous medium, and the sodium metasilicate has a sodium oxide to silicon dioxide ratio of about 1.0;

1.0.

22. The method of claim 19 wherein in the process for preparing the catalyst, the alkali metal silicate is sodium metasilicate and it is admixed with an aqueous medium containing said dissolved substances in amounts to provide about 2.9 ×

10^-3 mole per liter of calcium ion and about 2.7 ×

10^-3 mole per liter of magnesium ion, about 0.25 mole per liter of sodium metasilicate having a sodium oxide to silicon dioxide ratio of about 1.0;

1.0 is admixed with the aqueous medium, the aqueous medium contains not more than 10 parts per million by weight of carbonate ion and bicarbonate ion, the surfactant comprises sulfated castor oil and at least 50% of the hydroxy groups of the castor oil are sulfated, and about 0.05 mole per liter of the sulfated castor oil is admixed with the aqueous medium.

23. The method of claim 1 wherein the water used in watering the said plants also contains plant nutrients and the plant nutrients are fed to the plants at the time of watering.

24. The method of claim 23 wherein in the process for preparing the catalyst, the alkali metal silicate is admixed with an aqueous medium containing said dissolved substances in amounts to provide between about 1 ×

10^-3 and 6 ×

10^-3 mole per liter each of calcium ion and magnesium ion, the ratio of calcium ion to magnesium ion is between about 1.5;

1.0 and 1.0;

1.5, about 0.1-1 mole per liter of the alkali metal silicate is admixed with the aqueous medium, and the alkali metal silicate has an alkali metal oxide to silicon dioxide ratio between about 0.9;

1.0 and 1.2;

1.0.

25. The method of claim 23 wherein in the process for preparing the catalyst, the alkali metal silicate is sodium metasilicate and it is admixed with an aqueous medium containing said dissolved substances in amounts to provide between about 2.5 ×

10^-3 and 3.0 ×

10^-3 mole per liter each of calcium ion and magnesium ion, the aqueous medium contains about equimolar amounts of calcium ion and magnesium ion, about 0.2-0.3 mole per liter of the sodium metasilicate is admixed with the aqueous medium, and the sodium metasilicate has a sodium oxide to silicon dioxide ratio of about 1.0;

1.0.

26. The method of claim 23 wherein in the process for preparing the catalyst, the alkali metal silicate is sodium metasilicate and it is admixed with an aqueous medium containing said dissolved substances in amounts to provide about 2.9 ×

10^-3 mole per liter of calcium ion and about 2.7 ×

10^-3 mole per liter of magnesium ion, about 0.25 mole per liter of sodium metasilicate having a sodium oxide to silicon dioxide ratio of about 1.0;

1.0 is admixed with the aqueous medium, the aqueous medium contains not more than 10 parts per million by weight of carbonate ion and bicarbonate ion, the surfactant comprises sulfated castor oil and at least 50% of the hydroxy groups of the castor oil are sulfated, and about 0.05 mole per liter of the sulfated castor oil is admixed with the aqueous medium.

27. The method of claim 1 wherein the water used in watering the said plants also contains catalyst treated lignite and plant nutrients, the lignite being pretreated with an aqueous medium containing the said catalyst defined in claim 1 until it is soluble in the said water, and the plant nutrients being fed to the plants at the time of watering.

28. The method of claim 27 wherein in the process for preparing the catalyst, the alkali metal silicate is admixed with an aqueous medium containing said dissolved substances in amounts to provide between about 1 ×

10^-3 and 6 ×

10^-3 mole per liter each of calcium ion and magnesium ion, the ratio of calcium ion to magnesium ion is between about 1.5;

1.0 and 1.0;

1.5, about 0.1-1 mole per liter of the alkali metal silicate is admixed with the aqueous medium, and the alkali metal silicate has an alkali metal oxide to silicon dioxide ratio between about 0.9;

1.0 and 1.2;

1.0.

29. The method of claim 27 wherein the process for preparing the catalyst, the alkali metal silicate is sodium metasilicate and it is admixed with an aqueous medium containing said dissolved substances in amounts to provide between about 2.5 ×

10^-3 and 3.0 ×

10^-3 mole per liter each of calcium ion and magnesium ion, the aqueous medium contains about equimolar amounts of calcium ion and magnesium ion, about 0.2-0.3 mole per liter of the sodium metasilicate is admixed with the aqueous medium, and the sodium metasilicate has a sodium oxide to silicon dioxide ratio of about 1.0;

1.0.

30. The method of claim 27 wherein in the process for preparing the catalyst, the alkali metal silicate is sodium metasilicate and it is admixed with an aqueous medium containing said dissolved substances in amounts to provide about 2.9 ×

10^-3 mole per liter of calcium ion and about 2.7 ×

10^-3 mole per liter of magnesium ion, about 0.25 mole per liter of sodium metasilicate having a sodium oxide to silicon dioxide ratio of about 1.0;

1.0 is admixed with the aqueous medium, the aqueous medium contains not more than 10 parts per million by weight of carbonate ion and bicarbonate ion, the surfactant comprises sulfated castor oil and at least 50% of the hydroxy groups of the castor oil are sulfated, and about 0.05 mole per liter of the sulfated castor oil is admixed with the aqueous medium.