Lithium ferrite catalysed oxidative dehydrogenation process

• US 4,067,922 A
• Filed: 06/28/1976
• Issued: 01/10/1978
• Est. Priority Date: 05/19/1975
• Status: Expired due to Term

• Current Assignee: Texas Petrochemicals Corp.
• Original Assignee: Petro-TEX Chemical Corp.
• Inventors: Foster, Alan W.
• Primary Examiner(s): Vertiz, O. R.
• Assistant Examiner(s): Hearn, Brian E.
• Application Number:
  US05/700,575
• Time in Patent Office: 561 Days
• Field of Search: 260/680 E, 260/668 D, 260/683.3, 252/62.61, 252/470, 252/474, 252/465
• US Class Current: 585/625
• CPC Class Codes: B01J 23/78 with alkali- or alkaline earth metals
• CPC Class Codes: B01J 23/86 Chromium
• CPC Class Codes: B01J 23/862 Iron and chromium
• CPC Class Codes: C07C 5/48 with oxygen as an acceptor

Abstract

Oxidative dehydrogenation catalysts containing lithium, iron and oxygen, with or without aluminum or chromium, and containing the corresponding ferrite, give superior results and operate at generally lower temperatures than many other ferrite oxidative dehydrogenation catalysts.

Claims

1. A process for oxidative dehydrogenation comprising contacting oxygen and organic compounds having 2 to 20 carbon atoms, at least one ##STR2##grouping and boiling point below about 350°

C, in vapor phase at a temperature of at least about 250°

C in the presence of a catalyst composition containing a lithium ferrite consisting essentially of lithium, iron and oxygen;

lithium, iron oxygen and aluminum or chromium;

or lithium, iron, oxygen, aluminum and chromium the mole ratio of lithium to iron being in the range between 2;

5 to 1;

7, said catalyst composition having a surface area of at least 8.1 m² /gram.

2. The process according to claim 1 wherein aluminum or chromium may comprise up to 48 mole % of the total of iron, aluminum or chromium present in said catalyst.

3. The process according to claim 2 wherein the aluminum or chromium may comprise up to about 40 mole % of the total of iron, aluminum or chromium.

4. The process according to claim 1 wherein the mole ratio of lithium to iron is in the range of 1:

4 to 1;

6.

5. The process according to claim 1 wherein said organic compounds comprise hydrocarbons.

6. The process according to claim 1 wherein a product is recovered, corresponding to said organic compounds and having a higher degree of ethylenic unsaturation than said organic compounds.

7. The process according to claim 1 wherein said catalyst composition consists essentially of lithium, iron and oxygen.

8. The process according to claim 1 wherein said catalyst composition consists essentially of lithium, iron, oxygen and aluminum or chromium.

9. The process according to claim 8 wherein said catalyst composition consists essentially of lithium, iron, oxygen and aluminum.

10. The process according to claim 8 wherein said catalyst composition consists essentially of lithium, iron, oxygen and chromium.

11. The process according to claim 1 wherein the catalyst composition has a surface area of at least 10.5 m² /gram.