Energy conversion

• US 4,069,371 A
• Filed: 05/10/1976
• Issued: 01/17/1978
• Est. Priority Date: 05/10/1976
• Status: Expired due to Term

• Current Assignee: Synergy Research Corporation
• Original Assignee: The Gel Company
• Inventors: Zito, Ralph
• Primary Examiner(s): Mack, John H.
• Assistant Examiner(s): Feeley, H. A.
• Application Number:
  US05/678,638
• Time in Patent Office: 617 Days
• Field of Search: 429/15, 429/19, 429/20, 429/101, 429/107
• US Class Current: 429/409
• CPC Class Codes: H01M 10/36 Accumulators not provided for in groups H01M10/05-H01M10/34
• CPC Class Codes: H01M 10/484 for measuring electrolyte level, electrolyte density or electrolyte conductivity
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

An instantly refuelable energy conversion system comprises a multicell array wherein each cell has a cathode, a solid anode fuel selected from the class consisting of iron, zinc and nickel and a ferric (and/or +3 valence nickel or zinc) chloride liquid oxidizer. In power delivery (discharging) e.g., using iron alone, the reactions are:

At the anode, Fe→Fe⁺⁺ + 2e yielding 0.44 volts,

At the cathode, Fe⁺⁺⁺ +e→Fe⁺⁺ yielding 0.75 volts, the overall reaction being:

Fe + 2FeCl₃ →3FeCl₂, i.e., 1.2 volts overall.

These reactions are reversible for electrical charging purposes. The oxidizer is recirculated continuously and chemical reaction between the oxidizer and solid fuel in the fully charged or partially charged system is limited by a diffusion barrier between the oxidizer and fuel so that reactions therebetween are predominantly electrochemical. The system is characterized by continuously countering the tendency of rising pH of anolyte, and/or of contaminant accumulation therein, to maintain stable operation over long periods, e.g., by using a main energy conversion system anolyte as a catholyte in an auxiliary, overdriven energy conversion system which at the same time the catholyte of the main system serves as anolyte of the auxiliary system with reliance on the richness of the liquid in hydrogen ion and Fe⁺⁺⁺ ion to chemically attack any elemental iron formed in the auxiliary system thereby further preserving stability. The iron may be substituted in whole or in part by zinc and/or nickel.

Claims

1. Energy conversion apparatus comprising,

means defining at least a single electrolytic cell comprising anolyte and catholyte compartments separated by a diffusion barrier,

means defining anode and cathode plastic carbon composite electrodes, respectively in said analyte and catholyte compartments,

means defining analyte and catholyte liquid recirculating in closed loops which contain said compartments respectively, and recirculating the bulk storage means for said fluids, the fluids being solutions of metal salt which plate out metal on the anode during application of charging potential to the electrodes and deplate metal and redissolve it into the anolyte during discharge of the system and which change valence states within the catholyte without plating,

electrolytic means for maintaining catholyte molarity between 2.0 and 4.0,

means for preventing oxidation of the plating/deplating metal to combat polarization and maintain reversibility over extended charge/discharge cycling.

2. Energy conversion apparatus in accordance with claim 1 and further comprising,

means defining an auxiliary electrolytic device with at least a single cell pair of anolyte and catholyte compartments separated by diffusion barrier means and comprising therein anode and cathode electrode means, respectively, and a power supply connected to said anode and cathode electrodes for maintaining across said electrodes an overvoltage (compared to the full charge potential of the electrochemical pair of the main electrolytic device),

means for bleeding a minor portion of the recirculating anolyte of the main electrolytic device through said auxiliary electrolytic device and returning it to the recirculating loop of the main electrolytic device,

the auxiliary electrolytic device being poled so that said anolyte from the main electrolytic device passes through the catholyte compartment of the auxiliary electrolytic device and so that pH of main electrolytic device anolyte is decreased by electrolytic production of hydrogen ion the auxiliary electrolytic device to counteract the pH-increasing tendency of the main electrolytic device,

whereby stable operation at high efficiency is enabled over long periods of time,

and means for essentially continuously passing an electrolyte through the anolyte compartment of the auxiliary device.

3. Energy conversion apparatus in accordance with claim 2 wherein said means for continuously pasing electrolyte through the anolyte compartment of the auxiliary electrolytic device comprises a bleed from, and return to, the recirculating catholyte, of the main electrolyte device, of a minor portion of the said catholyte.

4. Energy conversion apparatus in accordance with claim 3 wherein said bleed electrolyte flows comprise less than 10% of main flows of the respective electrolytes from which they are bled.

5. Energy conversion apparatus in accordance with claim 1 wherein said anolyte and catholyte comprise at least one cation selected from the group consisting of iron, nickel and zinc and a chloride anion.

6. Energy conversion apparatus in accordance with claim 5 wherein said anolyte comprises iron and zinc components which plate out as an alloy layer on the anode in charging and substantially reversibly redissolve in the anolyte on discharge.

7. Energy conversion apparatus in accordance with claim 1, and further comprising means for draining catholyte from said catholyte compartments back to its reservoir to turn off power generation.

8. Energy conversion apparatus in accordance with claim 1 and further comprising,

means defining filters in the recirculating anolyte and catholyte loops, and

means for periodically switching the filters between loops to allow chemical cleansing of such filters.

9. Energy conversion apparatus in accordance with claim 1 comprising an aqueous solvent in said anolyte solution.

10. Energy conversion apparatus in accordance with claim 1 comprising a non-aqueous solvent in said an anolyte solution.

11. Energy conversion apparatus in accordance with claim 1 comprising a chelating agent in said anolyte solution to sequester the plating/deplating metal thereby enhancing plating and redissolution thereof and preventing its oxidation.

12. Energy conversion apparatus in accordance with claim 1 comprising a multi-cell array.

13. Energy conversion apparatus in accordance with claim 12 wherein individual cells of the array are arranged back-to-back using bipolar electrodes.