Silver halide element with an antistatic layer

• US 4,070,189 A
• Filed: 10/04/1976
• Issued: 01/24/1978
• Est. Priority Date: 10/04/1976
• Status: Expired due to Term

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Campbell, Gerald Allan, Kelley, Richard Norman
• Primary Examiner(s): Brammer, Jack P.
• Application Number:
  US05/729,554
• Time in Patent Office: 477 Days
• Field of Search: 96/87 R, 96/87 A, 252/500
• US Class Current: 430/527
• CPC Class Codes: G03C 1/89 Macromolecular substances therefor

Abstract

Antistatic compositions comprising a highly crosslinked vinylbenzyl quaternary ammonium polymer and a hydrophobic binder are described. Elements, particularly photographic elements, having a layer of the antistatic compositions are also described. The compositions are characterized by a binder to antistatic polymer ratio of about 10:1 to 1:1. The compositions are highly conductive in thin layers and retain substantial conductivity at low relative humidity. Layers of the antistatic compositions are particularly useful for photographic elements because they can be contacted over a wide range of conditions with a hydrophilic layer without resulting in ferrotyping.

Claims

1. A photographic element comprising a support having coated on one side a radiation sensitive silver halide layer or layers and coated on the other side an antistatic layer comprising:

##STR11## wherein;

A represents units of an addition polymerizable monomer containing at least two ethylenically unsaturated groups;

B represents units of a copolymerizable α

,β

-ethylenically unsaturated monomer;

Q is N or P;

R¹, r² and R³ are independently selected from the group consisting of carbocyclic and alkyl groups;

M is an anion;

x is from about 0.1 to about 20 mole percent;

y is from about 0 to about 90 mole percent; and

z is from about 10 to about 99 mole percent and a polymeric hydrophobic binder wherein the weight ratio of said hydrophobic binder to said antistatic polymer is about 5;

1 to 2;

1 and wherein the total coverage of said antistatic polymer and said binder is about 0.25 g/m² to 20 g/m².

2. An element according to claim 1 wherein the total coverage of said antistatic polymer and said binder is about 0.5 g/m² to 1.0 g/m².

3. A photographic element of claim 1 wherein x is from about 5 to 10 mole percent.

4. A photographic element of claim 1 wherein A is a unit of ethylene glycol dimethacrylate.

5. A photographic element of claim 1 wherein R¹, R² and R³ are methyl.

6. A photographic element of claim 1 wherein said antistatic polymer is copoly[N-vinylbenzyl-N,N,N-trimethylammonium chloride-co-ethylene glycol dimethacrylate] (93:

7).

7. A photographic element of claim 1 wherein said hydrophobic binder is selected from the group consisting of acetylated cellulose, poly(methylmethacrylate) and poly(vinyl acetal).

8. A photographic element of claim 1 wherein said support is a cellulose acetate and wherein said hydrophobic binder is an acetylated cellulose.

9. A photographic element of claim 1 wherein said antistatic polymer is copoly[N-vinylbenzyl-N,N,N-trimethylammonium chloride-co-ethylene glycol dimethacrylate] (93:

7) and said hydrophobic binder is 39% acetylated cellulose.