Cementitious compositions

• US 4,070,199 A
• Filed: 10/27/1976
• Issued: 01/24/1978
• Est. Priority Date: 10/28/1975
• Status: Expired due to Term

• Current Assignee: Imperial Chemical Industries Limited (Nouryon BV)
• Original Assignee: Imperial Chemical Industries Limited (Nouryon BV)
• Inventors: Downing, Stephen Barry, Osmond, Desmond Wilfred John, Dawson, David George, Skinner, Maurice Wainwright, West, Edmund James
• Primary Examiner(s): Poer, J.
• Application Number:
  US05/736,350
• Time in Patent Office: 454 Days
• Field of Search: 106/93, 106/99, 260/29.6 S, 260/42.13
• US Class Current: 106/696
• CPC Class Codes: C04B 16/06 fibrous
• CPC Class Codes: C04B 20/0048 Fibrous materials
• CPC Class Codes: C04B 24/26 obtained by reactions only involving carbon-to-carbon unsaturated bonds C04B24/243 takes precedence
• CPC Class Codes: C04B 24/383 Cellulose or derivatives thereof
• CPC Class Codes: C04B 28/06 Aluminous cements monolithic refractories or refractory mortars C04B35/66
• CPC Class Codes: C04B 40/00 Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability active ingredients C04B22/00 - C04B24/00; hardening of a well-defined composition C04B26/00 - C04B28/00; making porous, cellular or lightening C04B38/00; mechanical aspects B28, e.g. conditioning the materials prior to shaping B28B17/02
• CPC Class Codes: C04B 7/00 Hydraulic cements calcium sulfate cements C04B11/00

Abstract

Cured cementitious compositions having a modulus of rupture of greater than 15 MN/m² are prepared by curing and drying a homogeneous uncured cementitious composition which comprises in defined proportions hydraulic cement, water and a selected water-dispersible polymer.

Claims

1. A homogeneous uncured cementitious composition which comprises the ingredients:

a. a hydraulic cement selected from the group consisting of cements which comprise compounds of calcium, aluminum, silicon, oxygen and/or sulfur which set and harden by reaction with water,

b. water, and

c. a water-dispersible polymer, wherein

i. the ratio of water to hydraulic cement is in the range 15 - 28 parts by weight of water to 100 parts by weight of hydraulic cement;

ii. the ratio of water-dispersible polymer to hydraulic cement is in the range 0.1 - 3.0 parts by weight of water dispersible polymer to 100 parts by weight of hydraulic cement; and

iii. the water-dispersible polymer is selected, with reference to the hydraulic cement and to the selected proportions of polymer and water, for its suitability to facilitate homogenization and to yield on homogenization an uncured composition which can be shaped under pressure and which is shape retaining,

and wherein the ingredients (a), (b) and (c) have been subjected to a homogenization process of dispersion and homogenization so that they are regularly dispersed throughout the composition;

such that on curing and drying, the homogeneous uncured composition yields a cured and dried cementitious composition having a modulus of rupture greater than 15 MN/m².

2. A homogeneous uncured cementitious composition according to claim 1 wherein the water-dispersible polymer is further selected with reference to the hydraulic cement by a test which demonstrates a significant prolongation of the time which is required by a mixture of the water-dispersible polymer, hydraulic cement, and water in defined weight proportions to reach a maximum rate of heat evolution compared with the time which is required to reach a maximum rate of heat evolution by a mixture of hydraulic cement and water alone in the same weight proportions.

3. A homogeneous uncured cementitious composition according to claim 1 which on curing and drying yields a cured and dried cementitious composition having a modulus of rupture of greater than 20 MN/m^-2.

4. A homogeneous uncured cementitious composition according to claim 1 which on curing and drying yields a cured and dried cementitious composition having a modulus of rupture of greater than 30 MN/m^-2.

5. A homogeneous uncured cementitious composition according to claim 1 wherein the hydraulic cement comprises a Portland cement or a high alumina cement.

6. A homogeneous uncured cementitious composition according to claim 1 wherein the hydraulic cement comprises a mixture of a principal cement and 0.2-20% by weight based on the principal cement of a co-cement.

7. A homogeneous uncured cementitious composition according to claim 1 wherein the ratio of water to hydraulic cement is in the range 16 - 25 parts by weight of water to 100 parts by weight of hydraulic cement.

8. A homogeneous uncured cementitious composition according to claim 1 wherein the ratio of water-dispersible polymer to hydraulic cement is in the range 0.5 - 2.0 parts by weight of polymer to 100 parts by weight of hydraulic cement.

9. A homogeneous uncured cementitious composition according to claim 1 wherein the water-dispersible polymer is selected from non-ionic alkyl or hydroxy alkyl cellulose ethers and non-ionic polymers and copolymers of acrylamide and methacrylamide.

10. A homogeneous uncured cementitious composition according to claim 1 wherein the ingredients are subjected to a homogenisation process which comprises high shear mixing.

11. A homogeneous uncured cementitious composition according to claim 1 wherein the ingredients are subjected to a homogenisation process which comprises extrusion.

12. A homogeneous uncured cementitious composition according to claim 1 wherein the ingredients are subjected to a homogenisation process which comprises calendering.

13. A homogeneous uncured cementitious composition according to claim 1 which comprises a fibre other than an inorganic mineral fibre.

14. A homogeneous uncured cementitious composition according to claim 13 wherein the fibre is of a natural or synthetic organic polymer.

15. A homogeneous uncured cementitious composition according to claim 14 wherein the fibre is nylon fibre or polypropylene fibre.

16. A homogeneous uncured cementitious composition according to claim 13 wherein the fibre is a synthetic inorganic fibre.

17. A homogeneous uncured cementitious composition according to claim 16 wherein the fibre is glass fibre.

18. A homogeneous uncured cementitious composition according to claim 13 wherein the fibre is present in a proportion which is not greater than the critical volume of that fibre with respect to the cured composition i.e. it does not increase the modulus of rupture of the cured composition beyond the limit of proportionality of the fibre-free cured composition.

19. A homogeneous uncured cementitious composition according to claim 13 wherein the fibre is present in a proportion which is greater than the critical volume of that fibre with respect to the cured composition i.e. it increases the modulus of rupture of the cured composition beyond the limit of proportionality of the fibre-free cured composition.

20. A method of producing a homogeneous uncured cementitious composition, which when cured and dried yields a cured cementitious composition having a modulus of rupture greater than 15 MN/m^-2, which comprises subjecting to a homogenization process of dispersion and homogenization ingredients (a), (b) and (c) as defined in claim 1 so that they are regularly dispersed throughout the composition.

21. A method according to claim 20 wherein the homogenisation process comprises a mixing process followed by an extrusion process.

22. A method according to claim 20 wherein the homogenisation process comprises a mixing process followed by a calendering process.

23. A method according to claim 20 wherein the uncured composition is shaped.

24. A method of producing a cured and dried cementitious composition having a modulus of rupture greater than 15 MN/m^-2 which comprises curing and drying a homogeneous uncured cementitious composition as claimed in claim 1.

25. A method according to claim 24 wherein the uncured cementitious composition is cured for at about least 3 days, and preferably at least 7 days, at 100% relative humidity at a temperature of at least 20°

C and is thereafter dried for at least 24 hours at a temperature of at least 50°

C.

31. A cured and dried cementitious composition prepared by curing and drying a homogeneous uncured cementitious composition according to claim 1.

32. A shaped article which comprises a cured and dried cementitious composition according to claim 31.

26. A cured and dried cementitious composition comprising cured hydraulic cement and a water-dispersible polymer which has a modulus of rupture greater than 15 MN/m².

27. A cured and dried cementitious composition according to claim 26 which has a modulus of rupture greater than 20 MN/m².

28. A cured and dried cementitious composition according to claim 27 which has a modulus of rupture greater than 30 MN/m^-2.

29. A cured and dried cementitious composition according to claim 26 which comprises a fibrous material in a proportion not greater than the critical volume of that fibre with respect to the fibre-free composition.

30. A cured and dried cementitious composition according to claim 26 which comprises a fibrous material in a proportion greater than the critical volume of that fibre with respect to the fibre-free composition.