Process to separate hydrocarbons from gas streams

• US 4,072,604 A
• Filed: 07/19/1976
• Issued: 02/07/1978
• Est. Priority Date: 03/21/1974
• Status: Expired due to Term

• Current Assignee: UOP Des Plaines IL A NY General Partnership
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Ward, Dennis J.
• Primary Examiner(s): Levin, Herbert
• Application Number:
  US05/706,859
• Time in Patent Office: 568 Days
• Field of Search: 208/101, 208/341, 55/46, 55/48, 55/51, 55/223
• US Class Current: 208/341
• CPC Class Codes: C10G 5/04 with liquid absorbents

Abstract

A process for the separation of specific C₂ to C₆ hydrocarbons from a gaseous feed stream containing C₁ to C₆ -plus hydrocarbons. The feed stream enters an absorber and is first contacted by a primary lean liquid which is a portion of the bottoms product of the stripping column to which the rich absorber liquid is charged. The primary lean liquid contains the specific hydrocarbons which it is desired to separate from the feed stream. The feed stream is then contacted by a secondary lean liquid which does not contain these hydrocarbons and which is produced by fractionating a second portion of the stripper bottoms.

Claims

1. A process for the separation of C₃ and C₄ hydrocarbons from a gaseous stream which comprises the steps of:

a. introducing a feed stream comprising C₁ -C₄ hydrocarbons into a lower portion of an absorption zone while simultaneously introducing a first lean absorber liquid comprising C₇ hydrocarbons and a second lean absorber liquid comprising C₃ and C₇ hydrocarbons into an upper portion of said zone, the first absorber liquid being introduced at a higher elevation than the second absorber liquid;

b. countercurrently contacting the feed stream with the absorber liquids in the absorption zone at conditions effective to absorb C₃ and C₄ hydrocarbons in the absorber liquids;

c. withdrawing a rich absorber liquid comprising C₂, C₃, C₄ and C₇ hydrocarbons from the lower portion of the absorption zone and withdrawing from the upper portion of the absorption zone a gas stream substantially free of C₃ - C₄ hydrocarbons;

d. passing the rich absorber liquid into an upper portion of a stripping column operated at stripping conditions effective to remove C₂ hydrocarbons from the rich absorber liquid and thereby effecting the formation of a stripped liquid comprising substantially all of the C₃, C₄ and C₇ hydrocarbons contained in the rich absorber liquid and a stripping column overhead vapor stream comprising C₂ hydrocarbons but substantially free of C₄ hydrocarbons;

e. passing the stripping column overhead stream into the lower portion of the absorption zone;

f. dividing the stripped liquid into a first portion and a second portion of like composition;

g. introducing the first portion of the stripped liquid into the upper portion of the absorption zone as the second lean absorber liquid;

h. fractionating the second portion of the stripped liquid at conditions effective to provide a bottoms stream comprising a C₇ hydrocarbon and an overhead product comprising C₃ and C₄ hydrocarbons; and

,

i. supplying a portion of the bottoms stream to the upper portion of the absorption zone as the first lean absorber liquid.

2. The process of claim 1 further characterized in that the stripping column overhead stream is admixed with the feed stream prior to passage into the absorption zone.

3. The process of claim 1 further characterized in that the first absorber liquid and the bottoms stream comprises a naphtha, and in that the second absorber liquid comprises a naphtha and C₃ hydrocarbons.

4. The process of claim 1 further characterized in that a second portion of the bottoms stream from step (h) is removed as a product stream.

5. A process for the recovery of a C₂ hydrocarbon from a gaseous stream which comprises the steps of:

a. introducing a feed stream comprising C₁ and C₂ hydrocarbons into a lower portion of an absorption zone while simultaneously introducing a first lean absorber liquid comprising a hydrocarbon having from three to eight carbon atoms per molecule and a second lean absorber liquid comprising a C₂ hydrocarbon and the hydrocarbon having from three to eight carbon atoms per molecule contained in the first absorber liquid into an upper portion of said zone, the first liquid being introduced at a higher elevation than the second liquid;

b. countercurrently contacting the feed stream with the absorber liquids in the absorption zone at conditions effective to absorb C₂ hydrocarbons in the absorber liquids;

c. withdrawing a rich absorber liquid comprising methane and C₂ hydrocarbons and the hydrocarbon having from three to eight carbon atoms per molecule from the lower portion of the absorption zone and withdrawing from the upper portion of the absorption zone a gas stream having a lower concentration of C₂ hydrocarbons than the feed stream;

d. passing the rich absorber liquid into an upper portion of a stripping column operated at stripping conditions effective to remove methane from the rich absorber liquid and thereby effecting the formation of a stripped liquid comprising a C₂ hydrocarbon and substantially all of the hydrocarbon having from three to eight carbon atoms per molecule contained in the rich absorber liquid and a stripping column overhead vapor stream comprising methane and C₂ hydrocarbons but substantially free of C₃ and heavier hydrocarbons;

e. passing the stripping column overhead stream into the lower portion of the absorption zone;

f. dividing the stripping liquid into a first portion and a second portion of like composition;

g. introducing the first portion of the stripped liquid into the upper portion of the absorption zone as the second lean absorber liquid;

h. fractionating the second portion of the stripped liquid at conditions effective to provide a bottoms stream comprising the hydrocarbon having from three to eight carbon atoms per molecule and an overhead product comprising a C₂ hydrocarbon; and

,

i. supplying a portion of the bottoms stream to the upper portion of the absorption zone as the first lean absorber liquid.