Preparation of spheroidized particles

• US 4,076,640 A
• Filed: 02/24/1975
• Issued: 02/28/1978
• Est. Priority Date: 02/24/1975
• Status: Expired due to Term

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Forgensi, Rudolph, Hagenbach, Robert J.
• Primary Examiner(s): Pianalto, Bernard D.
• Application Number:
  US05/552,589
• Time in Patent Office: 1,100 Days
• Field of Search: 427/127, 252/62.54, 252/62.1, 75/.5 AA, 75/.5 B, 75/10 R
• US Class Current: 430/137.1
• CPC Class Codes: C04B 35/653 Processes involving a melting step
• CPC Class Codes: G03G 9/1075 Structural characteristics of the carrier particles, e.g. shape or crystallographic structure
• CPC Class Codes: H05H 1/48 using an arc H05H1/26 takes precedence

Abstract

A method of manufacturing spheroidized beads comprising the steps of introducing raw ore particles in the presence of an inert non-oxidizing carrier gas to a carbon arc plasma flame assembly to which is fed a controlled amount of oxygen and argon gas, melting the ore particles to form spheroidized droplets thereof, allowing the spheroidized droplets to fall by gravity in a substantially closed chamber having a controlled atmosphere wherein the droplets cool and solidify into beads, and collecting the beads.

Claims

1. A method of manufacturing spheroidized electrostatographic magnetic carrier beads comprising the steps of providing a substantially closed spheroidization column, purging said spheroidization column with nitrogen, providing said spheroidization column with a carbon arc plasma flame assembly comprising a 400 kw arc head with one cathode and three carbon anodes, energizing said arc head with a DC power supply to provide an electrical current flow of between about 650 and 750 amperes between said cathode and each of said anodes, providing a supply of argon gas to said cathode and a supply of nitrogen gas to said anodes to form a plasma flame having temperatures of up to about 10,000°

K, providing a supply of oxygen to said plasma flame at a flow rate of between about 100 and about 200 standard cubic feet per hour, feeding to said plasma flame magnetic raw ore particles selected from the group consisting of magnetite, hematite, taconite, and ilmenite wherein said ore particles have an average particle diameter of from between about 5 microns and about 600 microns and are fed to said plasma flame in the presence of nitrogen carrier gas for said ore particles whereby said ore particles are at least partially melted to form globules thereof, and allowing said globules to fall by gravity in said spheroidization chamber wherein said globules cool and solidify into spheroidized particles having an average saturation magnetic moment of between about 50 and about 85 electromagnetic units per gram.

2. A method of manufacturing spheroidized electrostatographic magnetic carrier beads in accordance with claim 1 wherein the flow rate of said nitrogen carrier gas is from between about 700 and about 800 standard cubic feet per hour.

3. A method of manufacturing spheroidized electrostatographic magnetic carrier beads in accordance with claim 1 wherein said ore particles are fed to said plasma flame at a feed rate of between about 100 and 400 pounds per hour.

4. A method of manufacturing spheriodized electrostatographic magnetic carrier beads in accordance with claim 1 including screening said ore particles prior to feeding said ore particles to said plasma flame so as to remove ore particles therefrom having an average diameter of less than about 2 microns.

5. A method of manufacturing spheriodized electrostatographic magnetic carrier beads in accordance with claim 1 including providing an exhaust system to said spheroidization column to remove dust and fines therefrom during the spheroidization of said magnetic raw ore particles.

6. A method of manufacturing spheroidized magnetic electrostatographic carrier beads comprising the steps of screening magnetic raw ore particles, selected from the group consisting of magnetite, hematite, taconite, and ilmenite so that said raw ore particles have an average particle diameter of from between about 5 microns and about 600 microns, providing a substantially closed spheroidization chamber, purging said spheroidization column with nitrogen, providing said spheroidization chamber with a carbon arc plasma flame assembly, comprising a 400 kw arc head with one cathode and three cathode anodes, energizing said arc head with a DC power supply to provide an electrical current flow of between about 650 and 750 amperes between said cathode and each of said anodes, providing a supply of argon gas to said cathode and a supply of nitrogen gas to said anodes to form a plasma flame having temperatures of up to about 10,000°

K, providing a supply of oxygen in the amount of from between about 100 and about 200 standard cubic feet per hour to said plasma flame, feeding said raw ore particles to said plasma flame in the presence of nitrogen carrier gas for said ore particles whereby said ore particles are at least partially melted to form droplets thereof, and allowing said droplets to fall by gravity in said spheroidization chamber wherein said droplets cool and solidify into spheroidized particles having an average saturation magnetic moment of between about 50 and about 85 electromagnetic units per gram.

7. A method of manufacturing spheroidized magnetic electrostatographic carrier beads in accordance with claim 6 including coating said spheroidized particles with an insulating resinous material and mixing about 10 parts to about 200 parts of the coated spheroidized particles with about 1 part by weight of finely-divided toner material.

8. A method of manufacturing spheroidized magnetic electrostatographic carrier beads in accordance with claim 6 wherein said ore particles are fed to said plasma flame at the rate of about 300 pounds per hour, said nitrogen carrier gas is fed at the rate of about 230 standard cubic feet per hour, and said argon gas is fed to said cathode at the rate of about 230 standard cubic feet per hour.