Aluminum-iron-nickel alloy electrical conductor

• US 4,080,222 A
• Filed: 12/09/1975
• Issued: 03/21/1978
• Est. Priority Date: 03/01/1974
• Status: Expired due to Term

• Current Assignee: Southwire Company
• Original Assignee: Southwire Company
• Inventors: Schoerner, Roger J., Chia, Enrique C.
• Primary Examiner(s): Dean, R.
• Application Number:
  US05/639,077
• Time in Patent Office: 833 Days
• Field of Search: 75/138-148, 148/2, 148/11.5 A, 148/32, 148/32.5, 29/527.7, 164/76
• US Class Current: 148/550
• CPC Class Codes: C22F 1/04 of aluminium or alloys based thereon
• CPC Class Codes: Y10T 29/49991 Combined with rolling

Abstract

This disclosure relates to an aluminum alloy electrical conductor which contains from about 0.20% to about 1.60% by weight nickel, from about 0.30% to about 1.30% iron, optionally up to 2.00% of additional specified alloying elements, and the remainder aluminum with associated trace elements. The conductors are processed in a continuous operation which includes continuous casting, hot-rolling in the as-cast condition to form continuous rod, cold-working of the rod by drawing it through a series of wire-drawing dies, without preliminary or intermediate anneals, and thereafter annealing the wire to achieve a minimum electrical conductivity of 58% IACS, an ultimate tensile strength of at least 12,000 psi, a yield strength of at least 8,000 psi and an elongation of at least 12% when measured as a No. 10 AWG wire. The additional alloying elements are precisely controlled in order to facilitate the continuous processing of the cast bar without splitting and cracking of the subsequently rolled and cold-drawn rod.

Claims

1. The method of preparing an aluminum alloy conductor having a minimum conductivity of at least 58 percent IACS comprising the steps of:

(a) Alloying from about 0.20 to about 1.60 weight percent nickel, from about 0.30 to about 1.30 weight percent iron, more than 0.15 to about 1.00 weight percent silicon, less than 0.10 weight percent magnesium, less than 0.05 weight percent copper, and from about 97.00 to about 99.50 weight percent aluminum with associated trace elements;

(b) Casting the alloy in a moving mold formed between a groove in the periphery of a rotating casting wheel and a metal belt lying adjacent said groove for a portion of its length; and

(c) Hot rolling the cast alloy substantially immediately after casting while the cast alloy is in substantially that condition as cast to form a continuous rod;

said aluminum alloy conductor having good thermal stability, a tensile strength of at least 12,000 psi, and a yield strength of at least 8,000 psi when measured as a fully annealed wire. cm 2. The method according to claim 1 further including the step of drawing said rod through wire-drawing dies, without annealing between drawing dies, to form wire of finish gauge size.

2. The method according to claim 1 further including the step of drawing said rod through wire-drawing dies, without annealing between drawing dies, to form wire of finish gauge size.

3. The method according to claim 1 wherein nickel, iron and silicon are alloyed with aluminum to yield the following composition:

Nickel -- 0.60% to 0.80%, by weight

Iron -- 0.45% to 0.65%, by weight

Silicon -- more than 0.15 to 1.00%, by weight

Aluminum -- remainder.

4. The method according to claim 1 wherein the alloying step includes the addition of magnesium in an amount sufficient to yield an alloy having the following weight percentages:

Nickel -- 0.60% to 0.80%

Iron -- 0.45% to 0.65%

Magnesium -- 0.03% to less than 0.10%

Silicon -- more than 0.15% to 1.00%

Aluminum -- remainder.

5. The method according to claim 1 wherein the alloying step includes the addition of niobium and tantalum in an amount sufficient to yield an alloy having the following weight percentages:

Nickel -- 0.60%

Iron -- 0.65%

Silicon -- more than 0.15% to 1.00%

Niobium -- 0.30%

Tantalum -- 0.18%

Aluminum -- remainder.

6. The method according to claim 1 wherein the alloying step includes the addition of zirconium in an amount sufficient to yield an alloy having the following weight percentages:

Nickel -- 0.80%

Iron -- 0.45%

Silicon -- more than 0.15% to 1.00%

Zirconium -- 0.60%

Aluminum -- remainder.

7. The method according to claim 1 including the further step of:

(d) drawing the rod through wire-drawing dies, without annealing the rod between drawing dies, to form wire;

said wire having the following properties when measured as a No. 10 A.W.G. fully annealed wire;

Tensile strength;

12,000 - 24,000 psi

Elongation;

12% - 30%

Yield strength;

8,000 - 18,000 psi.

8. An aluminum alloy electrical conductor manufactured according to the method of claim 1 having a minimum electrical conductivity of 58% IACS, an ultimate tensile strength of at least 12,000 psi, a yield strength of at least 8,000 psi and an elongation of at least 12% when measured as a fully annealed No. 10 AWG wire.

9. Aluminum alloy electrical conductor of claim 8 wherein the weight percentages of the constituents are as follows:

Nickel -- 0.60% to 0.80%

Iron -- 0.45% to 0.65%

Magnesium -- 0.03% to less than 0.10%

Silicon -- more than 0.15% to 1.00%

Aluminum -- 97.80% to 99.20%.

10. Aluminum alloy electrical conductor of claim 8 wherein an additional alloying element is present and selected from the group consisting of the following elements in a weight percentage as shown for each element:

Magnesium -- 0.001 to less than 0.10%

Zirconium -- 0.01 to 1.00%

Niobium -- 0.01 to 2.00%

Tantalum -- 0.01 to 2.00%

Yttrium -- 0.01 to 1.00%

Scandium -- 0.01 to 1.00%

Thorium -- 0.01 to 1.00%

Rare Earth Metals -- 0.01 to 2.00%

Carbon -- 0.01 to 1.00%

Mixtures of two or more of the above -- 0.01 to 2.00%.

11. Aluminum alloy electrical conductor of claim 8 wherein the conductor is a fully annealed wire which has been cold drawn to finished wire size, without any preliminary or intermediate anneals, prior to the final anneal.