Gas separation membrane drying with water replacement liquid

• US 4,080,744 A
• Filed: 06/22/1976
• Issued: 03/28/1978
• Est. Priority Date: 06/22/1976
• Status: Expired due to Term

• Current Assignee: L'Air Liquide SA
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Manos, Philip
• Primary Examiner(s): Spear, Jr., Frank A.
• Application Number:
  US05/698,697
• Time in Patent Office: 644 Days
• Field of Search: 210/500 M, 210/23 H, 210/321 R, 55/16, 264/41, 264/330, 264/340, 264/344, 34/9, 260/2.5 A
• US Class Current: 34/340
• CPC Class Codes: B01D 12/00 Displacing liquid, e.g. from wet solids or from dispersions of liquids or from solids in liquids, by means of another liquid
• CPC Class Codes: B01D 67/0095 Drying

Abstract

Process for drying a water-wet permselective membrane by initially contacting the membrane with water replacement liquid having low surface tension and limited solubility for water.

Claims

1. In the process for drying a semipermeable polymeric membrane that is wet with an aqueous membrane-wetting liquid by contacting the wet membrane with at least one water replacement liquid inert to the membrane and to the membrane-wetting liquid to remove water from the membrane, and removing the replacement liquid from the membrane;

the improvement which comprises contacting said wet polymeric membrane in which the polymer has a Critical Surface Tension of at least about 42 dynes per centimeter, at a temperature of about from 0°

to 50°

C. with a water replacement liquid consisting essentially of at least one organic solvent which is selected from the group consisting of aliphatic alcohols having 4-8 carbon atoms, aliphtic aldehydes having 3-8 carbon atoms and aliphatic ketones having 3-8 carbon atoms, carboxylic acids, carboxylic esters having 4-8 carbon atoms, aliphatic nitriles, ethers, acetals, ketals, amines, halocarbons having 1-3 carbon atoms and containing at least one hydrogen atom, and aqueous solutions thereof, said solvent having a surface tension at 20°

C. of not more than about 35 dynes per centimeter, a viscosity less than about 10 centipoise, a molar volume less than about 200 cubic centimeters per mole at 20°

C, a solubility for water not greater than about 20 weight percent at the contacting temperature, and a hydrogen bonding parameter of at least about 1 (calorie per cubic centimeter)^1/2 ; and

after water has been substantially completely removed from the membrane, evaporating the replacement liquid to obtain a membrane free of water and replacement liquid.

2. A process of claim 1 wherein the quantity of the replacement liquid and its capacity for water solubility is insufficient to dissolve theoretically more than about 100 weight percent of the water with which the membrane is wet.

3. A process of claim 1 wherein the organic solvent in the replacement liquid exhibits a surface tension of not more than 30 dynes per square centimeter, a viscosity of less than about 6 centipoise and a molar volume at 20°

C of less than about 130 cubic centimeters per mole.

4. A process of claim 1 wherein the quantity of the replacement liquid and its capacity for water solubility is insufficient to dissolve more than about 50% of the water with which the membrane is wet.

5. A process of claim 1 wherein the replacement liquid is substantially saturated with water.