Method for protecting an internal combustion engine by determining the change point of the lubrication oil

• US 4,082,511 A
• Filed: 09/10/1976
• Issued: 04/04/1978
• Est. Priority Date: 09/10/1976
• Status: Expired due to Term

• Current Assignee: Patented Systems Incorporated
• Original Assignee: Pricon Incorporated
• Inventors: Bedford, John E.
• Primary Examiner(s): Serwin, R.E.
• Application Number:
  US05/722,084
• Time in Patent Office: 571 Days
• Field of Search: 23/230 HC, 23/230 M, 73/15, 73/61, 73/64, 324/61
• US Class Current: 436/60
• CPC Class Codes: G01N 33/2876 Total acid number

Abstract

A new and improved on-site method for protecting an internal combustion engine in the field for maximizing service time by determining the change point of the lubrication oil when the TBN declines to a predetermined level. The on-site method utilizes a new field system fitted in a portable carrying case or a small cabinet and containing all the equipment necessary for analyzing lubrication oil including predetermined indicator marks on equipment for simplicity of application and for facilitating use by unskilled operators. The method includes two steps of titrating samples of lubrication oil for obtaining the TBN and TAN to indicate the change point of the lubricating oil when the TBN declines to a predetermined minimum. The method also can indicate a predicted change point so downtime for engine servicing can be scheduled. The TAN serves as an indicator of the amount of acid build-up in the lubrication oil.

Claims

1. An on-site method for protecting an internal combustion engine by precisely determining the change point for the lubricating oil of the engine in the field for maximum utilization of the oil and for preventing damage to the engine, comprising the steps of:

measuring a predetermined amount of lubrication oil withdrawn from an internal combustion engine at the site in the field;

diluting the predetermined amount of lubrication oil with a predetermined amount of titration solvent;

titrating the predetermined amount of diluted lubrication oil at the site in the field with an amount of a first premixed titrating solution sufficient to reduce the pH level of the lubrication oil to a first predetermined value;

determining the Total Base Number at the site in the field from the measured amount of the first titrating solution; and

changing the lubricating oil when the Total Base Number declines to a value of from about 1.0 to 0.5.

2. The method as set forth in claim 1, wherein:

the step of titrating with the first titrating solution includes adding increments of 0.1 N HC1 alcoholic at intervals until the pH of the predetermined amount of lubrication oil has declined to the first predetermined value.

3. The method as set forth in claim 1, wherein:

the step of measuring a predetermined amount of lubrication oil at the site in the field includes determining the predetermined amount by weight on a portable scale.

4. The method as set forth in claim 1, including the steps of:

measuring an additional predetermined amount of lubrication oil withdrawn from the internal combustion engine at the site in the field;

diluting the predetermined amount of lubrication oil with a predetermined amount of the titration solvent;

titrating the additional predetermined amount of diluted lubrication oil at the site in the field with an amount of a second premixed titrating solution sufficient to increase the pH level to a second predetermined value; and

determining the Total Acid Number at the site in the field from the measured amount of the second titrating solution.

5. The method as set forth in claim 4, wherein the step of titrating with the second titration solution includes:

adding increments of 0.1 N KOH alcoholic at intervals until the pH of the second predetermined amount of lubrication oil has increased to the second predetermined value.

8. The method as set forth in claim 1, including the step of:

adding a predetermined amount of premixed titration solvent comprising in the order of 495 ml toluene, 500 ml isopropyl alcohol, 5 ml distilled water per liter of solvent to the predetermined amount of lubricating oil at the site in the field before performing the titration.

11. The method as set forth in claim 1, including the steps of:

periodically determining the Total Base Number of the lubrication oil during the operation of the internal combustion engine using the aforementioned steps for predicting the change point for changing the lubricating oil.

6. An on-site method for protecting an internal combustion engine by precisely determining the change point for the lubricating oil of the engine in the field and for preventing damage to the engine, comprising the steps of:

adding in the order of five grams of lubricating oil from the engine crankcase on-site in the field to a first container as determined by a portable scale preset for the container;

pouring in the order of 125 ml premixed titration solvent from a first storage container up to a predetermined mark on the first container;

inserting a magnetic stirrer in the first container and positioning the first container on a magnetic stirrer base for providing agitation of the solution in the first container;

installing an electrode of a portable pH meter in the first container for measuring the pH of the solution in the first container;

pouring in the order of 25 ml of 0.1 n HC1 alcoholic from a second container to a predetermined zero mark of a first burette;

titrating the solution in the first container with the first burette to lower the pH of the solution to in the order of 4 on the pH meter;

reading the first burette to determine the volume of 0.1 N HC1 alcoholic used;

determining the Total Base Number from the volume of 0.1 N HC1 alcoholic used; and

changing the lubrication oil when the Total Base Number has declined to a value of from about 1.0 to 0.5.

7. The method as set forth in claim 6, including the step of:

calibrating the pH meter prior to the step of titrating with three buffers in fourth, fifth and sixth containers and having predetermined pH values of in the order of 4, 7 and 10.

9. The method as set forth in claim 6, wherein the step of adding the premixed titration solvent includes:

adding a premixed solvent comprising in the order of 495 ml toluene, 500 ml isopropyl alcohol and 5 ml distilled water per liter of solvent.

10. The method as set forth in claim 6, including the steps of:

adding in the order of an additional 5 g of lubricating oil from the engine crankcase on-site in the field to a second container as determined by a portable scale preset for the container;

pouring in the order of 125 ml of a second premixed titration solvent from the first storage container up to a predetermined mark on the second container;

inserting a magnetic stirrer in the second container and positioning the second container on a magnetic stirrer base for providing agitation of the solution in the second container;

installing an electrode of a portable pH meter in the second container for measuring the pH of the solution in the second container;

pouring in the order of 25 ml of 0.1 N KOH alcoholic from a third storage container to a predetermined zero mark of a second burette;

titrating the solution in the second container with the second burette to raise the pH of the solution to in the order of 11 on the pH meter;

reading the second burette to determine the volume of 0.1 N KOH alcoholic used; and

determining the Total Acid Number from the volume of 0.1 N KOH alcoholic used to determine the relative acid level of the lubrication oil.

12. An on-site method for protecting an internal combustion engine by precisely determining the change point for the lubricating oil of the engine in the field and for preventing damage to the engine, comprising the steps of:

determining the Total Base Number at the site in the field; and

changing the lubrication oil when the Total Base Number has declined to a value of from about 1.0 to 0.5.

13. The method as set forth in claim 12, including the step of:

periodically determining the Total Base Number of the lubrication oil during operation of the internal combustion engine using the aforementioned steps for predicting the change point for changing the lubricating oil.

14. The method as set forth in claim 12, including the step of:

changing the lubrication oil when the Total Base Number has declined to a value of about 0.5.

17. The method as set forth in claim 14, consisting of the step:

changing the lubrication oil when the Total Base Number has declined to a value of about 0.5.

15. An on-site method for protecting an internal combustion engine by precisely determining the change point for the lubricating oil of the engine in the field for maximum utilization of the oil and for preventing damage to the engine, consisting of the steps:

determining the Total Base Number at the site in the field; and

changing the lubricating oil when the Total Base Number declines to a value of from about 1.0 to 0.5.

16. The method as set forth in claim 15, including the step of:

determining the Total Acid Number at the site in the field.