Removal of heavy metal ions from aqueous solutions with insoluble crosslinked-starch-xanthates

• US 4,083,783 A
• Filed: 06/03/1977
• Issued: 04/11/1978
• Est. Priority Date: 10/16/1974
• Status: Expired due to Term

• Current Assignee: United States Department Of Agriculture
• Original Assignee: United States Department Of Agriculture
• Inventors: Doane, William M., Wing, Robert E.
• Primary Examiner(s): Hart, Charles N.
• Assistant Examiner(s): Castel, Benoit
• Application Number:
  US05/803,190
• Time in Patent Office: 312 Days
• Field of Search: 210/54 R, 210/38 B, 210/54 C, 536/104, 536/107, 536/106, 536/108, 536/109
• US Class Current: 210/688
• CPC Class Codes: C02F 1/286 using natural organic sorbents or derivatives thereof
• CPC Class Codes: C08B 31/06 of inorganic acids

Abstract

An insoluble alkali metal-magnesium starch-xanthate composition is prepared which is capable of removing most heavy metal ions from aqueous solutions. Concentrations of heavy metal ions obtained in several industrial effluents were reduced to below the most stringent aqueous discharge limits.

Claims

1. A process of removing heavy metal ions from aqueous solution comprising:

(1) contacting heavy metal ions in aqueous solutions with an amount of alkali metal-magnesium salt of crosslinked-starch-xanthate,

wherein said salt has a degree of crosslinking (DCL) such that it exhibits a degree of swelling in water at 95°

C. of from 65% to 450%,

wherein said magnesium is present in an amount ranging from about 0.5% to about 12%,

wherein said crosslinking occurs between the starch molecules of said salt through the hydroxyl oxygens of said molecules, and

wherein said amount of salt in said contacting step is such that the molar ratio of the xanthate moiety to metal ions is about 1;

1; and

(2) removing said heavy metal ions from said aqueous solution.

2. A process as described in claim 1 wherein the alkali metal-magnesium salt of crosslinked-starch-xanthate has the following general structure:

##STR5## where ##STR6## and M ═

Na.sup.⊕

or K.sup.⊕

;

##STR7## where n = 1, 2, or 3 and M ═

Na.sup.⊕

or K.sup.⊕

;

or ##STR8## where M ═

Na.sup.⊕

or K.sup.⊕

.

3. A process as described in claim 1 wherein said salt exhibits a degree of swelling of from 65% to 75%.

4. A process as described in claim 1 wherein said salt has a xanthate degree of substitution of from 0.1 to 1.

5. A process as described in claim 1 wherein said alkali metal is sodium.

6. A process as described in claim 1 wherein said alkali metal is potassium.