Process for preparing a foamed body

• US 4,084,980 A
• Filed: 08/18/1976
• Issued: 04/18/1978
• Est. Priority Date: 12/26/1975
• Status: Expired due to Term

• Current Assignee: Shikoku Kaken Kogyo Kabushiki Kaisha
• Original Assignee: Shikoku Kaken Kogyo Kabushiki Kaisha
• Inventors: Motoki, Hideo
• Primary Examiner(s): Poer, J.
• Application Number:
  US05/715,502
• Time in Patent Office: 608 Days
• Field of Search: 106/75, 106/87, 106/40 R
• US Class Current: 106/601
• CPC Class Codes: C04B 12/04 Alkali metal or ammonium silicate cements ; Alkyl silicate cements; Silica sol cements; Soluble silicate cements alkali metal silicates per se, their preparation C01B33/32; ammonium silicates per se, their preparation C01C1/00
• CPC Class Codes: C04B 14/02 Granular materials , e.g. microballoons
• CPC Class Codes: C04B 14/38 Fibrous materials; Whiskers
• CPC Class Codes: C04B 22/04 Metals, e.g. aluminium used as blowing agent
• CPC Class Codes: C04B 28/00 Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
• CPC Class Codes: C04B 28/34 containing cold phosphate binders
• CPC Class Codes: C04B 38/02 by adding chemical blowing agents
• CPC Class Codes: C04B 7/00 Hydraulic cements calcium sulfate cements C04B11/00

Abstract

A process for preparing a foamed body comprising a step of mixing the four components of:

A. an aqueous solution having a pH of up to 2.0 and containing at least one of acids and water-soluble acidic phosphates,

B. at least one of cement materials and anhydrous alkali metal silicates,

C. a metal blowing agent, and

D. a foaming stabilizer

To obtain a pasty mixture, the acids having an electric dissociation constant (pKa) of up to 4.0 at 25° C, the foaming stabilizer being at least one member selected from the group consisting of activated carbon, zeolite, silica gel, carbon black, talc and mica.

Claims

1. A process for preparing a foamed body comprising steps of (1) mixing the following four components:

a. an aqueous solution having a pH of up to 2.0 and containing at least one member selected from the group consisting of acids and water-soluble acidic phosphates,

b. at least one member selected from the group consisting of cement materials and anhydrous alkali metal silicates,

c. a metal blowing agent, and

d. a foaming stabilizer

in the proportion of about 10 to about 400 parts by weight of the component (a), 100 parts by weight of component (b) calculated as a metal oxide M₂ O or M'"'"'O wherein M is alkali metal and M'"'"' is alkaline earth metal, about 0.5 to about 30 parts by weight of the component (c) and about 3 to about 50 parts by weight of the component (d), to obtain a pasty mixture, (2) shaping the resulting pasty mixture to a desired shaped mass and (3) leaving the shaped mass to stand to effect foaming, the acids having an electric dissociation constant (pKa) of up to 4.0 at 25°

C, the foaming stabilizer being at least one member selected from the group consisting of activated carbon, zeolite, silica gel, carbon black, talc and mica.

2. A process according to claim 1 wherein said aqueous solution has a pH of up to 1.5.

3. A process according to claim 1 wherein said electric dissociation constant is from 0.3 to 1.5 at 25°

C.

4. A process according to claim 3 wherein said acid comprises an inorganic acid.

5. A process according to claim 4 wherein said inorganic acid is selected from the group consisting of hydrochloric acid, sulfuric acid, sulfurous acid, nitric acid, nitrous acid, phosphoric acid and chromic acid.

6. A process according to claim 1, in which said aqueous solution comprises a solution of water-soluble acidic phosphate.

7. A process according to claim 6, in which said water-soluble acidic phosphate comprises acidic aluminum orthophosphate.

8. A process according to claim 1, in which said cement material comprises at least one member selected from the group consisting of aluminates and silicates of alkaline earth metal.

9. A process according to claim 1, in which said alkali metal silicate comprises at least one water glass represented by Na₂ O.nSiO₂ or K₂ O.nSiO₂, wherein n is 2.0 to 4.0.

10. A process according to claim 1, in which said metal blowing agent is selected from the group consisting of metal elements of Groups IIIA, IIIB, IVA, IVB, VA and VB of the Periodic Table.

11. A process according to claim 1, wherein said metal blowing agent is selected from the group consisting of aluminum and zinc.

12. A process according to claim 1, in which said proportion is 100 parts by weight of the component (b) calculated as a metal oxide M₂ O or M'"'"'O wherein M is alkali metal and M'"'"' is alkaline earth metal, about 20 to about 300 parts by weight of the component (a), about 1.0 to about 5.0 parts by weight of the component (c) and about 5 to about 10 parts by weight of the component (d).

13. A process according to claim 1, in which gypsum is mixed with said four components in an amount of 0.5 to 20 weight percent based on component (b).

14. A process according to claim 1 in which inorganic fibrous material is mixed with said four components in an amount of 0.5 to 20 weight percent based on component (b).