Periodic removal of cathodic deposits by intermittent reversal of the polarity of the cathodes

• US 4,088,550 A
• Filed: 05/25/1977
• Issued: 05/09/1978
• Est. Priority Date: 05/25/1977
• Status: Expired due to Term

• Current Assignee: Eltech Systems Corporation (Industrie De Nora S.p.A)
• Original Assignee: Diamond Shamrock Refining and Marketing Company (Valero Energy Corporation)
• Inventors: Malkin, Irving
• Primary Examiner(s): Tufariello, T. M.
• Application Number:
  US05/800,403
• Time in Patent Office: 349 Days
• Field of Search: 204/231, 204/95, 204/275
• US Class Current: 205/341
• CPC Class Codes: C02F 1/46104 Devices therefor; Their operating or servicing
• CPC Class Codes: C02F 1/4674 with halogen or compound of halogens, e.g. chlorine, bromine
• CPC Class Codes: C02F 2001/46133 characterised by the material
• CPC Class Codes: C02F 2103/08 Seawater, e.g. for desalination
• CPC Class Codes: C02F 2201/4613 Inversing polarity
• CPC Class Codes: C02F 2303/04 Disinfection
• CPC Class Codes: C25B 1/26 Chlorine; Compounds thereof by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34
• CPC Class Codes: C25B 15/00 Operating or servicing cells

Abstract

Electrolysis of impure solutions containing hardness impurities such as calcium and magnesium causes deposits to form on the cathodes of such an electrolysis cell which rapidly reduces the efficiency of the cell. The electrolysis cell of the instant invention contains a plurality of cathodes. The efficiency of such a cell is rejuvenated periodically by changing the polarity of less than the total number of cathodes in said cell so as to clean such cathodes while continuing normal operation of the cell by means of the remaining cathodes.

Claims

1. An electrolytic cell for electrolyzing impure saline solutions containing hardness impurities comprising a cell body, an inlet opening in said cell body for supplying electrolyte in the form of impure saline solution thereto, an outlet opening in said cell body for discharging spent electrolyte therefrom, at least one anode having a dimensionally stable coating thereon within said cell body, at least two cathodes within said cell body, a direct current power source operatively connected to said electrodes and switching means interposed between said power source and said cathodes whereby each such cathode can be made anodic selectively and sequentially so as to remove hardness deposits therefrom while continuing electrolysis with at least one cathode, said anode always remaining anodic during electrolysis so as not to damage the dimensionally stable coating thereon.

2. The electrolytic cell for electrolyzing impure saline solutions of claim 1 wherein the switching means for selectively making said cathodes anodic includes a means for limiting the current flow to the cathodes to a level below 200 milliamps per square inch when said cathodes are in the anodic mode.

3. A process for electrolyzing impure saline solutions in an electrolytic cell having at least one anode and at least two cathodes comprising intermittently discontinuing the normal electrolysis with respect to at least one cathode by reversing the current flow in said cathode so that it acts as an anode for a time sufficient to remove hardness deposits therefrom while normal electrolysis between the permanent dimensionally stable anode and at least said one other cathode continues, thereafter sequentially reversing the current to the other said cathodes so as to remove hardness impurities therefrom while returning the previously cleaned cathode to cathodic service, and the anode remaining anodic throughout electrolysis.