Protected graft copolymers of cyclic nitrogenous and ester monomers

• US 4,091,030 A
• Filed: 06/01/1976
• Issued: 05/23/1978
• Est. Priority Date: 01/31/1974
• Status: Expired due to Term

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Schwartz, Nelson N.
• Primary Examiner(s): Gallagher, R. J.
• Assistant Examiner(s): Berch, Mark L.
• Application Number:
  US05/691,274
• Time in Patent Office: 721 Days
• Field of Search: 260/326.25, 260/239.3 R, 260/293.63, 260/326.5 FL
• US Class Current: 548/519
• CPC Class Codes: C08F 222/14 Esters having no free carboxylic acid groups , e.g. dialkyl maleates or fumarates
• CPC Class Codes: C08F 226/06 by a heterocyclic ring containing nitrogen
• CPC Class Codes: C08F 226/10 N-Vinyl-pyrrolidone
• CPC Class Codes: C08F 283/06 on to polyethers, polyoxymethylenes or polyacetals C08F283/004 takes precedence
• CPC Class Codes: C08G 2110/0025 rigid
• CPC Class Codes: C08G 2110/005 < 50kg/m3
• CPC Class Codes: C08G 65/2624 containing aliphatic amine groups
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 2451/00 Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds for ABS polymers C08J2455/02; Derivatives of such polymers
• CPC Class Codes: C08J 9/0061 characterized by the use of several polymeric components

Abstract

The protected copolymer compositions of the present invention have the following structural formula: ##STR1## WHEREIN A is a cyclic or acyclic group having 1 to 12 carbon atoms, 2 to 26 - (j + m) hydrogen atoms, 0 to 4 oxygen atoms, and 0 to 2 nitrogen atoms,

E is a group having the structure ##STR2## wherein n is 3 to 5, G is a group having the structure

--C.sub.u H.sub.2u-2 (CO.sub.2 C.sub.v H.sub.2v + 1 --.sub.2

Wherein u is 2 or 3 and v is an integer from 2 to 9,

K is a radical selected from the group consisting of

R--, RCO--, RNHCO--, ROC(CH.sub.3)H--,

##STR3## wherein R is a cyclic or acyclic radical having 1 to 18 carbon atoms and x is 3 or 4, J IS AN INTEGER FROM 0 TO 8,

m is an integer from 0 to 4,

j + m is 1 to 8,

s is an integer from 2 to 4,

w is 1 to 200,

p is 1 to 10,

q is 1 to 10, and

r is 1 to 50.

The compositions of this invention have been found to be useful as stabilizers in the preparation of cellular foams.

Claims

1. A composition which comprises the reaction product of a free radical-initiated copolymerization of a cyclic nitrogenous monomer having the structural formula:

##STR20## wherein n is 3, 4 or 5, and an esterified unsaturated dibasic acid having the structural formula;

space="preserve" listing-type="equation">C.sub.u H.sub.2u-2 (CO.sub.2 C.sub.v H.sub.2v +

     1).sub.2

wherein u is 2 or 3, and v is an integer from 2 to 9,

said free radical-initiated copolymerization being carried out substantially to completion in the presence of a polyfunctional polyether polyol, which is the reaction product of the alkylene oxide treatment of water or a polyhydric alcohol having 2 to 8 hydroxyl groups and having a weight average molecular weight in the range of about 500 to about 5,000 which has been treated with a capping agent selected from the group consisting of acetic anhydride, acetyl chloride, ketene, benzoyl chloride, benzoic acid, methyl isocyanate, ethyl isocyanate, phenyl isocyanate, and butyric, caproic, capric, lauric, myristic, palmitic, stearic and oleic acids, vinyl methyl ether, vinyl isobutyl ether, N-butyl vinyl ether and 2,3-dihydrofuran to convert substantially all of the hydroxyl groups of said polyether polyol to groups substantially inert to isocyanates.

2. The composition of claim 1 wherein said cyclic nitrogenous monomer is N-vinyl-2-pyrrolidone.

3. The composition of claim 1 wherein said esterified unsaturated dibasic acid is dibutyl maleate.