Copper coated, iron-carbon eutectic alloy powders

• US 4,092,223 A
• Filed: 05/14/1976
• Issued: 05/30/1978
• Est. Priority Date: 06/06/1975
• Status: Expired due to Term

• Current Assignee: Ford Motor Company
• Original Assignee: Ford Motor Company
• Inventors: Kaufman, Sydney M.
• Primary Examiner(s): Lusignan, Michael R.
• Application Number:
  US05/686,619
• Time in Patent Office: 746 Days
• Field of Search: 75/200, 75/212, 75/213, 427/216, 427/217, 427/242, 428/570, 204/10, 204/23
• US Class Current: 205/149
• CPC Class Codes: B22F 1/17 Metallic particles coated with metal
• CPC Class Codes: B22F 2207/07 Particles with core-rim gradient
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: C22C 33/0207 Using a mixture of prealloyed powders or a master alloy mixtures of metal powder in general B22F1/09
• CPC Class Codes: Y10S 75/95 Consolidated metal powder compositions of >95% theoretical density, e.g. wrought
• CPC Class Codes: Y10T 428/12014 having metal particles
• CPC Class Codes: Y10T 428/12181 Composite powder [e.g., coated, etc.]

Abstract

A mechanical mixture of selected powders is subjected to compressive forces to define a pre-compact, the pre-compact then being subjected to liquid phase sintering for producing a raw alloy steel product which is more economical and has enhanced physical properties, particularly tensile strength as compared to sintered compacts produced by the prior art to date. The improvement in physical properties and processing technique results principally from the use of a mechanical mixture consisting of a base iron powder and a coated alloyed additive powder having selected alloying ingredients (such as manganese, nickel, molybdenum, in an iron-carbon system); the particles of the alloyed powder have a thin flash coating of a low melting metal, such as copper, to control carbon diffusion into the base iron powder during liquid phase sintering.

Claims

1. A method of preconditioning a master alloy intermediate powder useful in being blended with a base metal powder for making liquid-phase sintered shapes, comprising:

(a) selecting an iron-carbon-prealloyed powder containing at least one alloying ingredient selected from the group consisting of manganese, chromium, molybdenum, nickel, copper, vanadium, said alloying ingredients each being present in an amount of about 2.5% by weight and the total of said alloying ingredients being in the range of 0.5-20% by weight,

(b) sizing said iron-carbon-alloy powder to a mesh size of -100, and

(c) substantially enveloping each particle of said iron-carbon-alloying powder with a metal which can be dissolved in said prealloyed powder and which is effective to act as a barrier to carbon diffusion in the solid state condition and which barrier metal remains substantially solid only up to the point of melting of said prealloyed powder, said envelope having a thickness of about 200 microns.

2. The method as in claim 1, in which said enveloping step is carried out by electrolytic deposition.

3. The method as in claim 1, in which said enveloping step is carried out chemically whereby said alloy particles are immersed in a copper salt solution.

4. The method as in claim 1, wherein said enveloping step is carried out mechanically by use of a ball mill containing copper abrading balls, said enveloping step being carried out for a period sufficient to coat a continuous envelope.

5. The method as in claim 1, in which the metal of step (c) is selected from the group consisting of copper, silver, platinum.