Gas scrubbing system

• US 4,096,085 A
• Filed: 10/29/1976
• Issued: 06/20/1978
• Est. Priority Date: 10/29/1976
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Asperger, Robert G., Krawczyk, Leroy S., Holoman, Smallwood Jr.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US05/736,918
• Time in Patent Office: 599 Days
• Field of Search: 252/189, 252/389 R, 252/390, 252/391, 252/392, 423/228, 423/229, 203/7, 21/2.5 R, 21/2.7 R
• US Class Current: 252/189
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: C23F 11/06 in markedly alkaline liquids
• CPC Class Codes: C23F 11/08 in other liquids

Abstract

An aqueous organic amine acid gas scrubbing system, particularly an aqueous N-methyldiethanolamine or diethanolamine acid gas scrubbing system having incorporated therein (1) a compound or mixture of compounds having the formula ##STR1## wherein n is an integer from 1 to 3, m is an integer from 2 to a number sufficient to yield a molecular weight of about 800, R₁, R₂, R₃ and R₄ are each independently selected from the group consisting of --H, --C_n'"'"' H_2n'"'"' OH, --C_n'"'"' H_2n'"'"'+1, --C_n'"'"' H_2n'"'"' N(R₃)R₄ wherein n'"'"' is an integer from 1 to 2 and wherein R₁ -R₃ and R₂ -R₄ may be joined to form cyclic amines when n is 2; said compound being present in about 10 to about 2000 parts per million parts of treating solution; (2) copper or a copper ion yielding compound in from 0 to 1000 ppm; and (3) sulfur or a sulfur atom yielding compound in from 0 to 1000 ppm.

Claims

1. A corrosion inhibited aqueous N-methyldiethanolamine or diethanolamine acid gas treating solution consisting essentially of (1) an amine compound or mixture of compounds having the formula ##STR3## wherein n is an integer from 1 to 3, m is an integer 2 to an integer to yield a molecular weight of about 800 and each R represents a member selected from the group consisting of --H, --C_n,H_2n'"'"',OH, C_n,H_2n'"'"', or --C_n,H_2n'"'"',N(R₃)R₄, n'"'"' is an integer from 1 to 2, and wherein R₁ R₃ and R₂ R₄ are joined together and n'"'"' is 2;

said compound being present in about 10 to about 2000 parts per million parts treating solution;

(2) copper or a copper ion yielding compound in from 0 to 1000 ppm; and

(3) sulfur or a sulfur atom yielding compound in from 0 to 1000 ppm.

2. The corrosion inhibited composition of claim 1 wherein the amine compound is polyethylene polyamine mixture having an average molecular weight of about 250-300.

3. The corrosion inhibited composition of claim 1 wherein the amine compound is polyethylenimine having a molecular weight of about 600.

4. The corrosion inhibited composition of claim 1 wherein the amine compound is polyethylenimine having an average molecular weight of about 300.

5. The corrosion inhibited composition of claim 1 wherein the amine compound is a polyethylene polyamine having an average molecular weight of about 250-300.

6. The corrosion inhibited composition of claim 1 wherein the amine compound is tris(aminoethyl)amine, mixed branched-linear.

7. The corrosion inhibited composition of claim 1 wherein the amine compound is a mixture of 35 to 45 weight percent diethylenetriamine, 10-15 weight percent triethylenediamine ##STR4## and 5 to 15 percent piperazine.

8. The corrosion inhibited composition of claim 1 wherein the amine compound is pentaethylenehexaamine.

9. The corrosion inhibited composition of claim 1 wherein the amine compound is a polymeric mixture of triethylenetetraamine and divinylbenzene.

10. The corrosion inhibited composition of claim 1 wherein the amine compound is the reaction product of divinylbenzene, ethylvinylbenzene and diethylenetriamine.

11. The corrosion inhibited composition of claim 1 wherein the amine compound is diethylenetriamine.

12. The corrosion inhibited composition of claim 1 wherein the amine compound is methylchloride quaternary salt of divinylbenzene diethylenetriamine.

13. The corrosion inhibited composition of claim 1 wherein the amine compound is tetraethylene pentaamine.

14. The corrosion inhibited composition of claim 1 wherein the amine compound is a solids free mixture of 8-9 weight percent tetraethylene pentamine, 30-35 weight percent pentaethylene hexamine and 55 weight percent hexaethylene heptamine and the balance branched and cyclic isomers having an average molecular weight of about 250 to 300.

15. The corrosion inhibited composition of claim 1 wherein the amine compound is a mixture of 85 weight percent aminoethyl piperazine and 15 weight percent diethylenetriamine.