Steam drawing of polyester monofilament to improve loop strength and resistance to fibrillation

• US 4,098,864 A
• Filed: 04/07/1977
• Issued: 07/04/1978
• Est. Priority Date: 02/18/1976
• Status: Expired due to Term

• Current Assignee: Bridgestone Firestone North American Tire LLC (Bridgestone Corporation)
• Original Assignee: Firestone Tire & Rubber Company (Bridgestone Corporation)
• Inventors: Nelson, Charles Jay, Morris, William E.
• Primary Examiner(s): Lowe, James B.
• Application Number:
  US05/785,373
• Time in Patent Office: 453 Days
• Field of Search: 264/290 T, 264/210 F, 264/DIG. 73, 264/DIG. 28
• US Class Current: 264/289.3
• CPC Class Codes: D01D 5/16 using rollers, or like mechanical devices, e.g. snubbing pins
• CPC Class Codes: Y10S 264/28 Stretching filaments in gas or steam

Abstract

There is provided a method of improving the properties of polyester monofilaments in respect to loop strength and resistance to fibrillation. The process contemplates treating an undrawn substantially noncrystalline extensible spun linear polyethylene terephthalate monofilament with a vapor medium such as steam and, while the monofilament is exposed to such vapor, drawing the monofilament at a draw ratio of from 1.5:1 to 4:1 and further drawing the monofilament in a subsequent drawing operation to an aggregate draw ratio of from 4:1 to 10:1.

The process enables development of the maximum or a desired loop strength value for the particular monofilament being processed with optimization of specific drawing conditions such as the steam pressure within the indicated draw ratios. Thus, drawn monofilaments having loop strength values of at least 2.5 grams/denier are provided, and the drawn products are particularly useful as reinforcing elements in rubber bodies, e.g. tire cords.

Claims

1. The method of improving the loop strength and resistance to fibrillation of a polyethylene terephthalate monofilament which comprises the sequential steps of:

(a) passing, prior to any previous orientation drawing thereof, an extensible spun linear polyethylene terephthalate monofilament having an instrinsic viscosity of at least 0.6 and having a denier in the range of from 500 to 50,000 through an elongated chamber;

(b) exposing the monofilament to a vapor medium at an elevated temperature and pressure within said chamber whereby the temperature of said monofilament is raised above the apparent second order transition temperature, but below the apparent melt temperature of the particular polyethylene terephthalate;

(c) drawing the monofilament in a first drawing operation while exposed to said vapor medium at a draw ratio of from 1.5;

1 to 4;

1 and controlling the pressure of said vapor medium to optimize the loop strength of the monofilament; and

(d) further drawing the monofilament in a subsequent drawing operation to an aggregate draw ratio of from 4;

1 to 10;

1 and, thereby increasing the loop strength of the monofilament to at least 2.5 grams/denier.

2. The method of claim 1 wherein said monofilament enters said chamber at a temperature lower than that of said vapor medium and said vapor medium partially condenses on the surface of said monofilament.

3. The method of claim 1 wherein said vapor medium is radially inwardly directed onto the surface of said monofilament within said chamber.

4. The method of claim 1 wherein the subsequent drawing operation is done while the monofilament is heated to a temperature of at least 80°

C. in dry heat.

5. The method of claim 1 wherein the subsequent drawing operation is done while exposing the monofilament to a vapor medium at an elevated temperature and pressure.

6. The method of claim 1 wherein said vapor medium contains at least 1% by weight entrained droplet-type liquid.

7. The method of claim 1 wherein said vapor medium is live steam containing at least 1% by weight entrained water in droplet form.

8. The method of claim 7 wherein said monofilament is exposed to said live steam at a pressure of from 1 psig. to 150 psig. in said first drawing operation.

9. The method of claim 8 wherein said monofilament is exposed within said elongated chamber for a period of less than 5 seconds.

10. The method of improving the loop strength and resistance to fibrillation of a high denier polyethylene terephthalate monofilament which comprises the sequential steps of:

(a) passing, prior to any previous orientation drawing thereof, a spun linear polyethylene terephthalate monofilament having an intrinsic viscosity of at least 0.6 and having a denier in the range of from 500 to 50,000 through a vapor medium containing entrained water in droplet form at an elevated temperature;

(b) impinging said vapor medium onto the surface of said monofilament at substantially right angles to the longitudinal axis of the monofilament whereby the temperature of said monofilament is raised above the apparent second order transition temperature, but below the apparent melt temperature of the particular polyethylene terephthalate;

(c) drawing the monofilament in a first drawing operation by gradually tapering and deforming said monofilament from its undrawn dimensions to its drawn dimensions in a draw ratio of from 1.5;

1 to 4;

1 while exposed to said vapor medium at a predetermined pressure to optimize loop strength; and

(d) further drawing the monofilament in a subsequent drawing operation to an aggregate draw ratio of from 4;

1 to 10;

1, and thereby increasing the loop strength of the monofilament to at least 2.5 grams/denier.

11. The method of improving the loop strength and resistance to fibrillation of a polyethylene terephthalate monofilament which comprises the sequential steps of:

(a) passing, prior to any previous orientation drawing thereof, an extensible spun linear polyethylene terephthalate monofilament having an intrinsic viscosity of at least 0.6 and having a denier in the range of from 500 to 50,000 through an elongated chamber;

(b) exposing the monofilament to a steam medium at an elevated temperature and pressure within said chamber whereby the temperature of said monofilament is raised above the apparent second order transition temperature, but below the apparent melt temperature of the particular polyethylene terephthalate;

(c) drawing the monofilament in a first drawing operation while exposed to said steam medium at a draw ratio of from 1.5;

1 to 4;

1 and at a predetermined steam pressure to optimize loop strength; and

(d) further drawing of the monofilament in a subsequent drawing operation at a draw ratio of at least 1.5;

1 and to an aggregate draw ratio of from 4;

1 to 10;

1 to enable the monofilament to be provided with a loop strength of at least 2.5 grams/denier.