Electrolytic generation of halogen biocides

• US 4,100,052 A
• Filed: 11/11/1976
• Issued: 07/11/1978
• Est. Priority Date: 11/11/1976
• Status: Expired due to Term

• Current Assignee: Lectranator Corporation Chardon Oh 44024 A Corporation of
• Original Assignee: Diamond Shamrock Refining and Marketing Company (Valero Energy Corporation)
• Inventors: Stillman, Neil W.
• Primary Examiner(s): Prescott, Arthur C.
• Application Number:
  US05/740,870
• Time in Patent Office: 607 Days
• Field of Search: 204/94, 204/95, 204/98, 204/149, 204/152, 204/268, 204/275, 204/290 P, 204/269
• US Class Current: 204/268
• CPC Class Codes: C02F 1/4674 with halogen or compound of halogens, e.g. chlorine, bromine
• CPC Class Codes: C02F 2001/46119 Cleaning the electrodes
• CPC Class Codes: C02F 2001/46128 Bipolar electrodes
• CPC Class Codes: C02F 2103/023 Water in cooling circuits
• CPC Class Codes: C02F 2103/42 from bathing facilities, e.g. swimming pools
• CPC Class Codes: C02F 2201/4615 Time
• CPC Class Codes: C02F 2301/022 Laminar
• CPC Class Codes: C02F 2303/04 Disinfection
• CPC Class Codes: C25B 1/24 Halogens or compounds thereof
• CPC Class Codes: C25B 11/036 Bipolar electrodes

Abstract

Disclosed is an electrolytic cell for the generation of low cost halogen biocidally active agent from an aqueous solution having a low halogen salt content for use in the treatment of sewage or other liquid affluents, especially those of fresh water swimming pools or fresh water cooling towers. The electrolytic cell is used in line with pumps generally associated with the distribution of waters for swimming pools or cooling towers.

Claims

1. An electrolytic cell for the production of halogen for use as a biocidal agent comprising:

an enclosure;

means for connecting said enclosure to a liquid distribution system of the facility to be biocidally affected so that the liquid must flow therethrough;

a plurality of spaced planar electrode plates attached to said enclosure interior in parallel fashion across the entire cross-section area of said means for connecting said enclosure to a liquid distribution system;

each of said spaced planar electrode plates having coatings on one side thereof to promote ionic potential travel in one direction through each of said spaced planar electrode plates;

said means for connecting said enclosure to said liquid distribution system consisting of openings at opposing ends of said enclosure of a size nearly as large as the height of said spaced planar electrode plates;

means for connecting a power source to substantially less than all of said spaced planar electrode plates to promote an electrical field thereacross to evolve halogen which is dissolved in the liquid flowing through said distribution system; and

a halogen salt concentration in the liquid greater than 0.5 grams per liter.

2. An electrolytic cell according to claim 1 wherein said enclosure is made of an electrically nonconducting material.

3. An electrolytic cell according to claim 1 wherein said plurality of spaced planar electrode plates consists of two end electrode plates, a center electrode plate, and one to 30 bipolar electrode plates.

4. An electrolytic cell according to claim 3 wherein said bipolar electrode plates number in the preferred range of six to 20.

5. An electrolytic cell according to claim 4 wherein said means for connecting a power source is connected to said end electrode plates and said center electrode plate.

6. An electrolytic cell according to claim 5 wherein said bipolar electrode plates have a surface coating of an electrocatalytically active corrosion resistant material and said coated side of said bipolar electrode plates face the cathode.

7. An electrolytic cell according to claim 1 wherein said spaced planar electrode plates have a thickness in the range of 0.02 to 0.06 inch (0.508 to 1.524 mm).

8. An electrolytic cell according to claim 1 wherein the spacing between said spaced planar electrode plates is in the range of 0.025 to 0.5 inch (0.635 to 12.7 mm).

9. An electrolytic cell according to claim 8 wherein the spacing between said spaced planar electrode plates is 0.075 inch (1.9 mm).

10. An electrolytic cell according to claim 1 wherein said halogen salt concentration is within the preferred range of 1 to 3 grams per liter.

11. An electrolytic cell according to claim 1 wherein said plurality of planar electrode plates are held in place by a plurality of slots 1/8 inch (3.175 mm) deep and a width equal to the thickness of said planar electrode plates in two sides of said enclosure.

12. An electrolytic cell according to claim 1 wherein said spaced planar electrode plates have a total anode area in the range of 180 to 220 square inches (1161 to 1419 sq. cm.).