Process for cationic electrodeposition of amine acid salt-containing polymers
First Claim
1. An improved method for coating a conductive substrate serving as a cathode, which method comprises passing electric current between an anode and said cathode in electrical contact with the water dispersion of a resinous composition, the improvement wherein the resinous composition comprises the reaction product of:
- (A) a polyepoxide having a molecular weight of at least 350,(B) a secondary amine,(C) a polyester polyol containing at least two alcoholic, primary hydroxyl groups, said polyester polyol being selected from the class consisting of polylactones and polyesters prepared by polyesterification of organic polycarboxylic acids or anhydrides thereof with organic polyols;
said reaction product being dispersible in water with the aid of an acid to provide cationic groups in the resin.
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Abstract
Novel, chain-extended adducts formed from reacting high molecular weight polyepoxides and organic polyols containing at least two alcoholic, primary hydroxyls per molecule are disclosed. The chain-extended polyepoxides are adducted with a secondary amine and made dispersible in water with acid. The water-dispersed resins can be applied to a wide variety of substrates by cationic electrodeposition. When compared to resins which are not chain extended, the resins of the invention have higher rupture voltages, improved film-forming properties and deposit as films with improved flexibility.
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15 Claims
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1. An improved method for coating a conductive substrate serving as a cathode, which method comprises passing electric current between an anode and said cathode in electrical contact with the water dispersion of a resinous composition, the improvement wherein the resinous composition comprises the reaction product of:
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(A) a polyepoxide having a molecular weight of at least 350, (B) a secondary amine, (C) a polyester polyol containing at least two alcoholic, primary hydroxyl groups, said polyester polyol being selected from the class consisting of polylactones and polyesters prepared by polyesterification of organic polycarboxylic acids or anhydrides thereof with organic polyols;
said reaction product being dispersible in water with the aid of an acid to provide cationic groups in the resin. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15)
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Specification