Method of recovering heat as well as fractions containing volatile alcohols and sulphur compounds from black liquor in connection with pulping

• US 4,111,743 A
• Filed: 04/04/1977
• Issued: 09/05/1978
• Est. Priority Date: 04/12/1976
• Status: Expired due to Term

• Current Assignee: Rauma-Repola Oy (UPM-Kymmene Oyj)
• Original Assignee: Arvi Ronnholm
• Inventors: Ronnholm, Arvi
• Primary Examiner(s): Bashore, S. Leon
• Assistant Examiner(s): Smith, William F.
• Application Number:
  US05/784,315
• Time in Patent Office: 519 Days
• Field of Search: 162/15, 162/16, 162/47, 162/68, 159/47 WL, 203/91, 203/98, 203/96
• US Class Current: 162/16
• CPC Class Codes: D21C 1/02 with water or steam
• CPC Class Codes: D21C 11/0007 Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for volatile compounds obtained by decomposition of spent liquors in order to regenerate them D21C11/125; compounds obtained by fractionating the liquors in order to regenerate them D21C11/0042
• CPC Class Codes: D21C 11/06 Treatment of pulp gases; Recovery of the heat content of the gases; Treatment of gases arising from various sources in pulp and paper mills; Regeneration of gaseous SO2, e.g. arising from liquors containing sulfur compounds
• CPC Class Codes: Y02P 70/10 Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Abstract

A method of recovering heat as well as fractions containing volatile alcohols and sulphur compounds from black liquor obtained from pulping. In a vapor generator, water is, by means of vapor, liberated at a high temperature and under a high pressure from the expansion of black liquor removed from a digester, indirectly vaporized into low-pressure vapor, which is used for vapor treatment of chips before their introduction into the digester. The condensate produced in the vapor generator is, under pressure control, passed into a condenser device, which is operated at a pressure that is lower than the pressure in the black liquor escaping from the digester, preferably at the atmospheric pressure. The condensate fraction formed in the condenser device as well as the uncondensed gas fraction are cooled by means of indirect cooling and the volatile alcohols and sulphur compounds are recovered from these fractions. Waste water, preferably secondary condensate from the evaporation plant, is used as the vaporization liquid in the vapor generator.

Claims

1. A method of recovering heat and fractions containing alcohols and sulphur compounds from black liquor obtained from pulping cellulosic materials which comprises

expanding black liquor removed from a digester into a low pressure vapor mixture,

passing said low pressure vapor mixture to a vapor generator where said vapor mixture is brought into indirect heat exchange contact with water,

passing the condensate formed in the vapor generator to a surface condenser while controlling the pressure to obtain a temperature difference between said vapor mixture and said water sufficient to vaporize said water to steam, said surface condenser being at a pressure lower than the pressure of the black liquor from the digester and said steam being used for presteaming chips before introducing the chips into the digester,

cooling the condensate fraction formed in the surface condenser and the uncondensed gas fraction by indirect cooling, and

recovering the volatile alcohols and sulphur compounds from said fractions.

2. A method as claimed in claim 1 which comprises using waste water as the water in the vapor generator for generating steam for said presteaming of said chips.

3. A method as claimed in claim 2, which comprises condensing the aeration vapors removed from said presteaming of said chips in said surface condenser.

4. A method as claimed in claim 1, which comprises using primary condensate as said water vaporized to steam, and combining the steam produced with the low-pressure steam network.

5. A method as claimed in claim 4, which comprises condensing the aeration vapors removed from said presteaming of said chips in said surface condenser.