Plasticized polymers of vinyl acetate

• US 4,111,888 A
• Filed: 08/07/1975
• Issued: 09/05/1978
• Est. Priority Date: 10/27/1970
• Status: Expired due to Term

• Current Assignee: Ciba-Geigy AG (Novartis Ag)
• Original Assignee: Ciba-Geigy AG (Novartis Ag)
• Inventors: Lamb, Frank, Cooper, Hugh Melvin, Combey, Malcolm
• Primary Examiner(s): Lieberman, Allan
• Application Number:
  US05/602,888
• Time in Patent Office: 1,125 Days
• Field of Search: 260/31.6, 260/475 P
• US Class Current: 524/290
• CPC Class Codes: C08G 63/20 Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
• CPC Class Codes: C08G 63/672 Dicarboxylic acids and dihydroxy compounds
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 31/00 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid of hydrolysed polymers C08L29/00; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 31/04 Homopolymers or copolymers of vinyl acetate
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence

Abstract

Polyesters derived from the reaction of a phthalic acid, with ethylene glycol, di-ethylene glycol or a polyethylene glycol and an aliphatic alcohol are used as plasticisers for vinyl acetate polymers.

Claims

1. A composition consisting essentially of a vinyl acetate polymer selected from the group consisting of homopolymers of vinyl acetate and copolymers of vinyl acetate with one or more ethylenically unsaturated non-halogenated comonomers wherein the proportion of vinyl acetate in the copolymer is 55-100%, and from 10 to 100% by weight based on the weight of the polymer of a polyester having a molecular weight of 350 to 1500 derived from the reaction of a phthalic acid or anhydride or a mixture thereof with a polyethylene glycol having a molecular weight of 175 to 225, and an aliphatic alcohol containing from 3 to 6 carbon atoms;

the phthalic acid or anhydride or mixture thereof being reacted with theoretical amounts of alcohol and glycol needed to effect the reaction with the proviso that the alcohol may be reacted in amounts ranging from 0-50% below the amounts necessary to effect the reaction up to 20 mol% in excess of the amount needed to produce the final product and the glycol may be reacted with the phthalic acid or phthalic acid anhydride or mixture thereof in amounts ranging from 0-10 mol % below the theoretical amount necessary to effect the reaction up to 20 mol % in excess of the theoretical amount.

2. A composition according to claim 1 in which the polyester has a molecular weight from 350 to 900.

3. A composition according to claim 1, wherein the vinyl acetate polymer is a homopolymer of vinyl acetate.

4. A composition according to claim 1 in which the alcohol from which the polyester is derived is n-butyl alcohol or iso-butyl alcohol.

5. A composition according to claim 1 in which the polyester is derived from 4 moles phthalic anhydride, 4.4 moles of n-butanol and 2.1 moles of polyethylene glycol having a molecular weight of 200.

6. A composition according to claim 1 in which the amount of polyester is from 40 to 80% by weight based on the weight of vinyl acetate polymer.