Method of determining ion activity using coated ion selective electrodes

• US 4,115,209 A
• Filed: 10/20/1977
• Issued: 09/19/1978
• Est. Priority Date: 10/30/1974
• Status: Expired due to Term

• Current Assignee: Research Corporation
• Original Assignee: Research Corporation
• Inventors: Freiser, Henry, Cattrall, Robert W., James, Helen J., Kneebone, Barbara M., Carmack, Gary
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US05/844,146
• Time in Patent Office: 334 Days
• Field of Search: 204/195 M, 204/1 T
• US Class Current: 205/781.5
• CPC Class Codes: G01N 27/3335 the membrane containing at least one organic component G01N27/3271 takes precedence; aspects concerning the enzyme reagent in enzyme electrodes C12Q1/001

Abstract

The potentiometric responses caused by ion activity changes in solution are measured with an electrode formed by coating an ion exchange material which is molecularly dispersed throughout an insoluble film-forming polymeric matrix directly onto a conductive substrate such that an oxidation-reduction mechanism is not operative in the response of said electrode to the activity of ions in said solution.

Claims

1. In a process for measuring the potentiometric responses caused by ion activity changes in solution, the improvement which comprises:

using an electrode formed by coating an ion exchange material which is molecularly dispersed throughout an insoluble film-forming polymeric matrix directly onto a conductive substrate such that an oxidation-reduction mechanism is not operative in the response of said electrode to the activity of ions in said solutions.

2. The process of claim 1, wherein said ion exchange material in said polymeric matrix is an ion exchange resin.

3. The process of claim 2, wherein said ion exchange resin is sulfonated polystyrene.

4. The process of claim 2, wherein said ion exchange resin is characterized by 2-6 meq. of exchangeable sites per gram of resin.

5. The process of claim 1, wherein said conductive substrate is in the form of a conductive wire.

6. The process of claim 1, wherein said dispersion of ion exchange material in said polymeric matrix is a colloidal dispersion or a true solution of ion exchange material in a polymeric matrix.

7. The process of claim 6, wherein said ion exchange material is dispersed in said polymeric matrix in an amount of from 1-25% by weight based on the total weight.