Gas desulphurization

• US 4,115,518 A
• Filed: 11/04/1975
• Issued: 09/19/1978
• Est. Priority Date: 11/06/1974
• Status: Expired due to Term

• Current Assignee: Unibra
• Original Assignee: Unibra
• Inventors: Delmon, Bernard, Van Houte, Ghislain
• Primary Examiner(s): Vertiz, O. R.
• Assistant Examiner(s): Heller, Gregory A.
• Application Number:
  US05/628,663
• Time in Patent Office: 1,050 Days
• Field of Search: 423/242, 423/244, 423/554, 423/555, 55/73, 252/189, 252/192, 252/193
• US Class Current: 423/244.08
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/508 by treating the gases with solids
• CPC Class Codes: B01J 20/043 Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
• CPC Class Codes: B01J 20/046 containing halogens, e.g. halides
• CPC Class Codes: B01J 20/28004 Sorbent size or size distribution, e.g. particle size
• CPC Class Codes: B01J 20/3236 containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts

Abstract

A desulphurization reagent comprising an intimate mixture, in the solid state, of a main component selected from the group consisting of alkaline-earth, oxides, hydroxides, carbonates, bicarbonates, and mixtures, thereof, and an additive selected from the group consisting of hydrogen halide acids, salts of such acids of alkaline metals, ammonium, and alkaline-earth metals, sulphuric acid, and mixtures thereof, said additive being present in an amount of from 0.1 to 15% by mole respect to said main component.

Claims

1. A method for desulfurizing flue gases wherein said gases are contacted at a temperature of 250°

to 1300°

C with a reagent in powdered form consisting of a main component selected from the group consisting of calcium, magnesium and mixed calcium and magnesium oxides, hydroxides and carbonates, said main component being impregnated with an additive in an amount of from 0.1 to 15% by mole, said additive being selected from the group consisting of hydrochloric acid, hydrobromic acid and sulfuric acid followed by drying, thus converting said reagent into a sulfate and recovering said sulfate.

2. A method according to claim 1 wherein said contact is effected at a temperature from 350°

to 600°

C.

3. The method according to claim 1 wherein said reagent is a desulfurization reagent consisting of an intimate mixture of a main component selected from the group consisting of alkaline earth oxides, hydroxides, carbonates, bicarbonates and mixtures thereof, said main component being first impregnated with an additive selected from the group consisting of hydrochloric acid, hydrobromic acid and sulfuric acid and mixtures thereof, said additive being present in an amount of from 0.1 to 10% by mole with respect to said main component, and then dried prior to use.

4. The method according to claim 3 wherein in said reagent said additive is a chloride.

5. The method according to claim 3 wherein in said reagent said additive is sulphuric acid.

6. The method according to claim 5 wherein in said reagent said main component is a magnesium compound.

7. A method for desulfurizing flue gases wherein said gases are contacted with a reagent in powdered form consisting of a solid main component selected from the group consisting of alkaline earth oxides, hydroxides, and carbonates, bicarbonates, and mixtures thereof and a solid additive in an amount of from 0.1 to 15% by mole, selected from the group consisting of the chloride and bromide salts of alkali metals, ammonium, and alkaline-earth metals, at a temperature of 250°

C to 1300°

C, thus converting said reagent into a sulfate salt of calcium, magnesium or a mixture thereof, and recovering said sulfate.

8. A method according to claim 7 wherein said contact is effected at a temperature from 600°

to 1100°

C.

9. A method according to claim 7 wherein the oxygen content of the flue gases is adjusted to at least half a mole O₂ per each mole SO₂.

10. The method according to claim 7, wherein said flue gases are circulated through a bed of said reagent.

11. The method according to claim 7 wherein the temperature is 350°

C to 600°

C.

12. The method according to claim 7 wherein contacting is continued until all said reagent is converted into a sulfate.

13. The method according to claim 7 wherein said reagent is a desulphurization reagent consisting of an intimate mixture, in a solid state, of a main component selected from the group consisting of alkaline-earth oxides, hydroxides, carbonates, bicarbonates, and mixtures thereof, and an additive selected from the group consisting of chloride and bromide salts with alkali metals, ammonium, and alkaline-earth metals, and mixtures thereof, said additive being present in an amount of from 0.1 to 10% by mole with respect to said main component.

14. The method according to claim 13 wherein in said reagent said main component is selected from the group consisting of calcium, magnesium, and mixed calcium and magnesium oxides, hydroxides and carbonates.

15. The method according to claim 13 wherein in said reagent said main component is CaCO₃ and said additive is selected from the group consisting of CaCl₂, KCl, or NaCl.

16. The method according to claim 13 wherein in said reagent the amount of said additive is from 0.1 to 5% with respect to said main component.

17. The method according to claim 16 wherein said reagent is in the form of a powder with an average grain size from 1 to 200 microns.

18. The method according to claim 13 wherein said reagent is obtained by impregnating said main component in powdered form with a solution of said additive in a solvent and then drying to remove said solvent.