Cartridge and furnace for crystal growth

• US 4,118,197 A
• Filed: 01/24/1977
• Issued: 10/03/1978
• Est. Priority Date: 01/24/1977
• Status: Expired due to Term

• Current Assignee: ASE Americas Incorporated
• Original Assignee: Mobil Tyco Solar Energy Corporation
• Inventors: Jewett, David N., Mackintosh, Brian H.
• Primary Examiner(s): Emery, Stephen J.
• Application Number:
  US05/761,941
• Time in Patent Office: 617 Days
• Field of Search: 156/608, 156/617 SP, 156/DIG. 98, 23/273 Z, 23/273 SP
• US Class Current: 117/211
• CPC Class Codes: C30B 15/002 Continuous growth
• CPC Class Codes: C30B 15/005 Simultaneous pulling of more than one crystal
• CPC Class Codes: C30B 15/14 Heating of the melt or the crystallised materials
• CPC Class Codes: C30B 15/24 using mechanical means, e.g. shaping guides shaping dies for edge-defined film-fed crystal growth C30B15/34
• CPC Class Codes: C30B 15/30 Mechanisms for rotating or moving either the melt or the crystal flotation methods C30B15/28
• CPC Class Codes: C30B 15/34 Edge-defined film-fed crystal-growth using dies or slits
• CPC Class Codes: Y10T 117/1044 including means forming a flat shape [e.g., ribbon]
• CPC Class Codes: Y10T 117/1068 including heating or cooling details [e.g., shield configuration]
• CPC Class Codes: Y10T 117/1072 including details of means providing product movement [e.g., shaft guides, servo means]

Abstract

A novel cartridge containing selected crystal growth components is provided for use in a crystal growing system. The cartridge is adapted to be mounted directly to a crystal pulling mechanism and is arranged so that it can be inserted into a furnace containing a supply of molten feed material. The cartridge includes a crystal growing die, a die holder, and associated crystal growth components arranged to permit rapid growth of selected shape. The cartridge is assembled outside of the furnace at room temperature and can be inserted into and removed from the furnace without having to cool the latter.

Claims

1. Apparatus for growing a silicon ribbon-type crystal from a melt comprising:

a furnace having (1) a chamber with a top aperture leading to the interior of said chamber, (2) means within said chamber for supporting therein a crucible containing a melt from which a crystal is to be grown so that the melt in the crucible will be in line with the aperture, and (3) means for heating a crucible supported within said chamber by said supporting means; and

at least one cartridge which is arranged to be moved into and out of said furnace through said top aperture, said cartridge being a unitary assembly comprising (1) a capillary die adapted to be used to provide a growth pool of melt from which a crystal can be pulled, (2) solid vertically elongate heat-conducting means disposed above said die and arranged so as to extend on opposite sides of and control the thermal gradient lengthwise in a ribbon-type crystal which is pulled from said growth pool of melt and (3) means holding said heat-conducting means in a fixed relation to said die;

means for moving the cartridge vertically into and out of said chamber via said aperture and for positioning the cartridge within said chamber so as to place said die in communicating relation with a melt contained by said crucible, said means for moving the cartridge including guide means for guiding said cartridge during its vertical movement into and out of said chamber; and

a pulling mechanism disposed above the furnace for pulling a crystal from said growth pool of melt past said heat-conducting means and out of said furnace via said aperture.

2. Apparatus according to claim 1 wherein said guide means comprises at least one guide member affixed to and extending vertically from the upper side of said furnace and means slidably connecting said cartridge to said at least one guide member.

3. Apparatus according to claim 1 including a crucible in said furnace supported by said supporting means, and wherein said die comprises a capillary having an upper end and a lower end, and said means for moving said cartridge is adapted to lower said cartridge within said chamber so that the lower end of said capillary terminates within said crucible.

4. Apparatus according to claim 1 wherein said cartridge includes cooling means for producing a sharp thermal gradient between the upper end of said die and said heat-conducting means, said cooling means being located between and fixed with respect to said die and said heat-conducting means.

5. Apparatus according to claim 4 wherein said cooling means comprises a pair of mutually spaced sections disposed symmetrically with opposite sides of said die, and means for conductively cooling said mutually spaced sections.

6. Apparatus according to claim 5 wherein said cooling means comprises a pair of heat conductive elements, and means for circulating a cooling fluid through said heat conductive elements.

7. Apparatus according to claim 1 wherein said heat-conducting means comprises a pair of mutually opposed vertically elongate heat-conductive members which extend parallel to the pulling axis of the pulling mechanism and which are shaped so as to provide a controlled temperature gradient along the length of a crystal disposed between and extending lengthwise of said heat-conductive members.

8. Apparatus according to claim 7 wherein each of said heat-conductive members has a lower end and an upper end, and said cartridge further includes a local heating means for supplying heat to the lower ends of said heat-conductive members, said local heating means being fixed with respect to said die.

9. Apparatus according to claim 8 wherein said cartridge further includes a metal heat sink in conductive engagement with the upper ends of said heat-conductive members for removing heat from said heat-conductive members.

10. Apparatus according to claim 7 wherein said cartridge further includes insulating means surrounding said heat-conductive members for substantially the full length thereof so as to substantially completely prevent radiative loss of heat to the environment surrounding said members, and means for maintaining said insulating means in surrounding relation to said heat-conductive members.

11. Apparatus according to claim 7 wherein said heat-conductive members define a space through which a crystal may be pulled, said space being sized so that said heat-conductive members nearly touch said crystal.

12. Apparatus according to claim 11 wherein said cartridge further includes means for supplying a gaseous heat conductive medium in the space encompassed by said heat conductive members.

13. Apparatus according to claim 1 wherein said cartridge is attached to said pulling mechanism.

14. Apparatus according to claim 13 wherein said pulling mechanism and cartridge are movable as a unit toward and away from said furnace.

15. Apparatus according to claim 1 comprising at least two cartridges as defined by claim 1 and a corresponding number of said cartridge moving means for selectively and individually moving said cartridges into and out of said chamber.

16. Apparatus according to claim 14 comprising at least two cartridges movable into and out of said chamber and a like number of pulling mechanisms each attached to one of said cartridges, each pulling mechanism and the cartridge attached thereto being movable as a unit toward and away from said furnace.

17. A cartridge for use in growing a ribbon-type crystal from a melt contained in a furnace, said cartridge being a unitary assembly comprising:

a capillary die;

means for holding said die;

vertically elongate heat-conductive means located above said die for controlling the temperature gradient lengthwise of a ribbon-type crystal grown from a growth pool of melt at the upper end of said die;

a heat-conductive header;

means connecting said die holder and heat-conductive means to said header so that said heat-conductive means depends from said header and is fixed with respect to said die;

said heat conductive means being arranged to extend on opposite sides of said ribbon-type crystal above said die and defining a space extending from said die to said header through which a growing ribbon-type crystal may be pulled away from said die;

heat-insulating means positioned adjacent to said heat-conductive means for substantially the full length thereof for substantially preventing radiative loss of heat to the environment surrounding said cartridge; and

means attached to said cartridge whereby said cartridge may be guided for movement into and out of a melt-containing furnace.

18. A cartridge according to claim 17 further including a housing surrounding said heat-conductive means in a spaced relation thereto and means securing said housing to said header, with said heat-insulating means disposed between said housing and said heat-conductive means for reducing radiative heat loss from said heat-conductive means.

19. A cartridge according to claim 17 further including cooling means disposed between said capillary die and said heat-conductive means and fixed with respect to said die.

20. A cartridge according to claim 19 wherein said cooling means includes a cooling member located adjacent to the upper end of said capillary die, and means for circulating a cooling fluid through a portion of said cooling member.

21. A cartridge according to claim 17 further including electrical heater means disposed adjacent to said capillary die, electrical conductor means connected at one end to said heater means and at an opposite end to said heat-conductive header, and means for connecting said electrical conductor means to a source of electrical power.

22. A cartridge according to claim 21 further including a temperature sensor disposed adjacent to said capillary die, electrical terminal means supported by said header, and means connecting said temperature sensor to said electrical terminal means.

23. A cartridge according to claim 17 further including a housing surrounding said heat-conductive means, and further wherein said means for holding said die is attached to one end of said housing and the opposite end of said housing is attached to and depends from said header.

24. A cartridge according to claim 23 wherein the bottom end of said die projects below the bottom end of said housing and wherein said heat-conductive means comprises at least one heat-conductive member having an upper end and a lower end and being elongated in a direction running from said upper end to said lower end, said heat-conductive member at least partially defining said space, one end of said heat-conductive member and header being connected so that heat can flow from one said heat-conductive member to said header by conduction, and further including means located above said die for supplying heat to the opposite end of said heat-conductive member.

25. A cartridge according to claim 23 wherein said heat-conductive means comprises at least one heat-conductive member having an upper end and a lower end, said heat-conductive member being elongate in a direction running from said top end to said bottom end and at least partially defining said space, said upper end of said heat-conductive member and said header being connected so that heat can flow by conduction from said heat-conductive member to said header, and further including electrical heater means located above said die for supplying heat to the lower end of said heat-conductive member.

26. A cartridge according to claim 25 further including means carried by said header for introducing a gas into said space.

27. A cartridge according to claim 25 further including heat insulation means surrounding said heat-conductive means between said upper and lower ends for reducing radiative heat loss laterally from said heat-conductive means.

28. A cartridge according to claim 27 further including at least one additional electrical heater means for supplying heat to the upper end of said die, all of said heater means being supported by electrically conductive means attached to said header.