Novel cathode and bipolar electrode incorporating the same

• US 4,118,294 A
• Filed: 09/19/1977
• Issued: 10/03/1978
• Est. Priority Date: 09/19/1977
• Status: Expired due to Term

• Current Assignee: Electrode Corporation
• Original Assignee: Diamond Shamrock Technologies SA (Valero Energy Corporation)
• Inventors: Pellegri, Alberto
• Primary Examiner(s): Andrews, R. L.
• Application Number:
  US05/834,418
• Time in Patent Office: 379 Days
• Field of Search: 204/290 R, 204/291, 204/294, 204/278, 204/129, 204/270, 204/290 F
• US Class Current: 205/638
• CPC Class Codes: C25B 1/26 Chlorine; Compounds thereof by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34
• CPC Class Codes: C25B 11/04 characterised by the material
• CPC Class Codes: C25B 9/00 Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features

Abstract

A hydrogen evolution cathode for electrochemical reactions consists of a body formed of a powdered electrically conductive material embedded in a cured thermosetting resin and having a cathodically operative surface enriched with powder of a hydrogen evolution catalyst, the powdered conductive material preventing the diffusion of atomic hydrogen through the cathode body. The cathode may be incorporated in a bipolar electrode by bonding it to a thin sheet of valve metal coated with an anodic electrocatalytic material, the body being advantageously extended by projecting parts of electrically insulating cured resin.

Claims

1. A hydrogen-evolution cathode for electrochemical reactions, comprising a body which is substantially impervious to the diffusion therethrough of atomic hydrogen, said body being formed of an aggregate of powdered electrically conductive material embedded in electrically conducting relationship in a cured thermosetting resin and having a cathodically active surface enriched with a powder of a hydrogen evolution catalyst.

2. Cathode of claim 1, wherein the thermosetting resin is selected from the group consisting of furane, phenolic, epoxy, and plastic alloys thereof.

3. Cathode of claim 1, wherein the powdered electrically conductive material comprises at least one material selected from the group consisting of carbon, graphite, chromium, tungsten, iron, nickel, cobalt, cadmium, zinc, copper, molybdenum, silver, and metal carbides, hydrides, nitrides, borides and silicides.

4. Cathode of claim 1, wherein the hydrogen evolution catalyst is iron powder.

5. Cathode of claim 1, wherein the hydrogen evolution catalyst is nickel powder.

6. Cathode of claim 1, wherein the thermosetting resin is an epoxy-based plastic alloy, the powdered electrically conductive material is graphite and the hydrogen evolution catalyst is iron powder.

7. Cathode of claim 1, in which said body comprises a substrate layer havng a thickness of at least 1 mm and a cathodically active surface layer having a thickness of at least 0.5 mm, said substrate layer containing 65 to 80% by weight of the powdered electrically conductive material and said surface layer containing 90 to 97% by weight of the hydrogen evolution catalyst.

8. Cathode of claim 1, in which the thermosetting resin is an epoxy-based plastic, the powdered electrically conductive material comprises at least one material selected from the group consisting of copper, graphite, molybdenum, chromium and TiC, and the hydrogen evolution catalyst is selected from the group consisting of iron and nickel powder and mixtures thereof.

9. A bipolar electrode for electrochemical reactions involving cathodic hydrogen evolution, comprising a valve metal anode having an anodically active surface coated over with a layer of an electrocatalytic anodically resistant material and a cathode bonded to the anode in electrically conducting relationship, the cathode comprising a body which is substantially impervious to the diffusion therethrough of atomic hydrogen, said body being formed of powdered electrically conductive material embedded in electrically conducting relationship in a cured thermosetting resin and having a cathodically active surface enriched with a powder of hydrogen evolution catalyst.

10. Bipolar electrode of claim 9, wherein the hydrogen evolution catalyst is selected form the group consisting of iron and nickel powder.

11. Bipolar electrode of claim 9, wherein the thermosetting resin is selected from the group consisting of furane, phenolic, epoxy, and plastic alloys thereof.

12. Bipolar electrode of claim 9, wherein the powdered electrically conductive material comprises at least one material selected from the group consisting of carbon, graphite, chromium, tungsten, iron, nickel, cobalt, cadmium, zinc, copper, molybdenum, silver and metal carbides, hydrides, nitrides, borides and silicides.

13. A bipolar electrode for electrochemical reactions involving cathodic hydrogen evolution in bipolar diaphragm-less electrolyzers, comprising a substantially planar valve metal anode having an anodically active surface coated over with a layer of an electrocatalytic anodically resistant material and a cathode bonded to the anode in electrically conducting relationship, the cathode comprising a body which is substantially impervious to the diffusion therethrough of atomic hydrogen, said body being formed of an aggregate of powdered electrically conductive material embedded in electrically conducting relationship in a cured thermosetting resin and having a cathodically active surface enriched with a powder of a hydrogen evolution catalyst, said body being extended beyond at least one edge of the cathode and the active surface of the anode by at least one part of cured electrically insulating resin.

14. The bipolar electrode of claim 13, wherein said body and said active surface of the anode are rectangular and are disposed in substantially coincident juxtaposition with two electrically insulating parts of cured resin extending from the opposite edges thereof.

15. In a cell for electrochemical reactions involving cathodic hydrogen evolution, comprising a housing and co-operating electrodes disposed in said housing to provide means for the passage of an electrolyte through the cell, the improvement in which said electrodes operating as cathodes each comprise a body which is substantially impervious to the diffusion of hydrogen, said body being formed of an aggregrate of powdered electrically conductive material embedded in electrically conducting relationship in a cured thermosetting resin and having a cathodically active surface enriched with a powder of a hydrogen evolution catalyst.

16. The cell of claim 15, wherein the thermosetting resin is selected from the group consisting of furane, phenolic, epoxy, and plastic alloys thereof.

17. The cell of claim 15, wherein the powdered electrically conductive material comprises at least one material selected from the group consisting of carbon, graphite, chromium, tungsten, iron, nickel, cobalt, cadmium, zinc, copper, molybdenum, silver, and metal carbides, hydrides, nitrides, borides and silicides.

18. The cell of claim 15, wherein the hydrogen catalyst is selected from the group if iron and nickel powder.

19. The cell of claim 15, wherein each cathode is extended beyond at least one edge by at least one baffle-forming part of cured electrically insulating resin.

20. In a method of electrolysis wherein hydrogen is evolved at a cathodically polarized electrode, the improvement comprising using as the cathodically polarized electrode a body formed of an aggregate of powdered electrically conductive material embedded in electrically conducting relationship in a cured thermosetting resin and having a cathodically active surface enriched with a powder of a hydrogen evolution catalyst whereby atomic hydrogen evolved at the cathodically active surface is substantially prevented from diffusing through said body.