Structural laminate and method for making same

• US 4,118,533 A
• Filed: 01/19/1976
• Issued: 10/03/1978
• Est. Priority Date: 01/19/1976
• Status: Expired

• Current Assignee: Celotex Corporation
• Original Assignee: Celotex Corporation
• Inventors: Skowronski, Michael J., Hagan, Joseph R., Hipchen, Donald E.
• Primary Examiner(s): Bell, James J.
• Application Number:
  US05/649,976
• Time in Patent Office: 988 Days
• Field of Search: 156/78, 156/79, 156/309, 156/555, 260/2.5 AK, 428/297, 428/302, 428/303, 428/313, 428/317, 428/321, 428/322, 428/325, 428/332, 428/423, 428/424, 428/425, 428/160, 428/910, 428/920, 428/164, 428/426, 428/158, 264/45
• US Class Current: 442/371
• CPC Class Codes: B29C 44/30 Expanding the moulding material between endless belts or rollers B29C44/203 takes precedence
• CPC Class Codes: B29C 70/003 characterised by the matrix material, e.g. material composition or physical properties
• CPC Class Codes: B29K 2309/08 Glass
• CPC Class Codes: B32B 17/06 comprising glass as the main or only constituent of a layer, next to another layer of a specific material
• CPC Class Codes: B32B 5/12 characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
• CPC Class Codes: Y10S 428/92 Fire or heat protection feature
• CPC Class Codes: Y10T 156/1741 Progressive continuous bonding press [e.g., roll couples]
• CPC Class Codes: Y10T 428/24124 Fibers
• CPC Class Codes: Y10T 428/24479 including variation in thickness
• CPC Class Codes: Y10T 428/24999 Inorganic
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 442/648 Including a free metal or alloy constituent
• CPC Class Codes: Y10T 442/651 Plural fabric layers
• CPC Class Codes: Y10T 442/656 Preformed metallic film or foil or sheet [film or foil or sheet had structural integrity prior to association with the nonwoven fabric]

Abstract

A structural laminate comprises at least one planar facing sheet with a rigid foam attached to one surface of the facing sheet. The rigid foam is characterized in that the major recurring chemical linkage therein is the isocyanurate moiety. Distributed substantially evenly throughout the foam is a mat of long straight glass fibers arranged in layers substantially parallel to the facing sheet. The process for producing this structural laminate comprises the steps of contacting a thin, substantially incompressible yet expansible mat of long straight glass fibers with a foam-forming mixture of an organic polyisocyanate and a diol, positioning a facing sheet on each face of the mat, and passing the facing sheets having the mat and the foam-forming mixture there between through the nip of two rotating rolls.

Claims

1. A process for producing a structural laminate comprising the steps of:

I. contacting a thin, substantially incompressible yet expansible mat of glass fibers with a foam-forming mixture comprising;

A. an organic polyisocyanate, and

B. a diol having an equivalent weight between 30 and 100,

Ii. positioning a facing sheet on each face of the mat,

Iii. passing the facing sheets having the mat and the foam-forming mixture there between through the nip of two rotating rolls,

the mat of glass fibers being further characterized by

A. the glass fibers being arranged in layers,

B. the glass fibers within each layer being long, straight and substantially parallel, and

C. the glass fibers in each layer being at an acute angle to the glass fibers in each next adjacent layer, and

Iv. permitting the mat of glass fibers to expand under the sole influence of the expansion of the foam-forming mixture.

2. The process of claim 1 wherein the organic polyisocyanate is polymethylene polyphenyl isocyanate.

3. The process of claim 2 wherein the polymethylene polyphenyl isocyanate is a mixture of those of Formula I:

##STR2## wherein n is an integer from 0 to 8 inclusive.

4. The process of claim 3 wherein the polymethylene polyphenyl isocyanate has a functionality of at least 2.1.

5. The process of claim 3 wherein the polymethylene polyphenyl isocyanate has an equivalent weight of 120 to 180.

6. The process of claim 3 wherein the polymethylene polyphenyl isocyanate has a viscosity between 100 and 4,000 centipoises.

7. The process of claim 1 wherein the diol is one of Formula II:

space="preserve" listing-type="equation">ho--r.sup.1 --oh (ii)

wherein R¹ is selected from the group consisting of lower alkylene and lower alkoxyalkylene.

8. The process of claim 1 wherein the diol consists essentially of diethylene glycol.

9. The process of claim 1 wherein the equivalent ratio of A:

B is 2;

1 to 6;

1.

10. The process of claim 1 wherein the mat of glass fibers has an initial thickness less than 1 and 1/2 times the separation of the facing sheets at the nip of the two rotating rolls.

11. The process of claim 1 wherein the mat of glass fibers has a low loft such that pressure applied to the faces of the mat will not substantially reduce the thickness of the mat.

12. The process of claim 1 wherein the fibers forming the mat are wetable by the foam-forming mixture to the extent that the foam-forming mixture will penetrate and completely fill the interstices between the glass fibers of the mat.

13. The process of claim 1 wherein the glass fibers of the mat are arranged in layers which are parallel to the faces of the mat.

14. The process of claim 1 wherein the glass fibers in each layer of the mat are at an angle of less than 60°

to the glass fibers in each of the next adjacent layers.

15. The process of claim 1 wherein the glass fibers are attached to one another by an amount of fiber binder sufficient to make the mat of glass fibers dimensionally stable but insufficient to fill the interstices between the glass fibers.

16. The process of claim 1 wherein the mat of glass fibers is included in an amount sufficient to insure the continued structural integrity of the structural laminate when the laminate is exposed to open flame.

17. A process for producing a structural laminate comprising the steps of:

I. contacting a thin, substantially incompressible mat of glass fibers with a foam-forming mixture comprising;

A. a mixture of polymethylene polyphenyl isocyanates of Formula I;

##STR3## wherein n is an integer from 0 to 8 inclusive, and B. a diol having an equivalent weight of 30 to 100 of Formula II;

space="preserve" listing-type="equation">ho--r.sup.1 --oh (ii)

wherein R¹ is selected from the group consisting of lower alkylene and lower alkoxyalkylene.

wherein the equivalent ratio of A;

B is 2;

1 to 6;

1,

Ii. positioning a facing sheet comprising a metal on each face of the mat,

Iii. passing the facing sheets having the mat of glass fibers and the foam-forming mixture there between through the nip of two rotating rolls wherein;

A. the thickness of the mat remains substantially the same as prior to passing through the nip,

B. the velocity of the mat is equal to the velocity of the facing sheets,

C. the glass fibers of the mat are arranged in layers,

D. the glass fibers within each layer are substantially parallel,

E. the glass fibers in each layer are at an acute angle to the glass fibers in each next adjacent layer, and

F. the foam-forming mixture completely fills the interstices between the fibers of the mat, and

Iv. permitting the foam-forming mixture to expand under the influence of heat generated in an exothermic reaction between the components of the mat separating under the sole influence of the expansion of the foam-forming mixture, the layers of fibers in the mat maintaining their same order but being distributed throughout the resultant structural laminate.

18. The process of claim 17 wherein the layers of fibers in the mat are evenly distributed throughout the structural laminate in planes substantially parallel to the planes of the facing sheets.

19. The process of claim 17 wherein the foam-forming mixture cures under the influence of heat added by the controlled introduction of hot air.

20. The process of claim 17 wherein the thickness of the mat prior to passing through the nip is less than 0.1 inches.

21. The process of claim 20 wherein the thickness of the mat prior to passing through the nip is between 0.010 and 0.050 inches.

22. The process of claim 17 wherein the glass fibers have an average length that exceeds five feet.

23. The process of claim 17 wherein the glass fibers in each layer of the mat are at an angle of less than 60°

to the glass fibers in each of the next adjacent layers.

24. The process of claim 17 wherein the glass fibers are attached to one another by an amount of fiber binder sufficient to make the mat of glass fibers dimensionally stable but insufficient to fill the interstices between the glass fibers and insufficient to resist the separation of the glass fibers under the influence of the expanding foam-forming mixture.

25. The process of claim 17 wherein the mat of glass fibers are included in the amount of 4-24 gms. per board-foot of the resulting structural laminate.

26. A process for producing a structural laminate comprising the steps of:

I. contacting a thin, substantially incompressible mat of glass fibers with a foam-forming mixture comprising;

A. a mixture of polymethyl polyphenyl isocyanates of Formula I;

##STR4## wherein n is an integer from 0 to 8 and the polyisocyanates have an equivalent weight of 120 to 180 and a functionality of 2.5 to 3.5 and the mixture has a viscosity of 250 to 2500 centipoises;

B. diethylene glycol, wherein the equivalent ratio of A;

B is between 3.0;

1 and 5.0;

1;

C. a catalyst composition in an amount and of a type sufficient to give the foam-forming mixture a cream time between 15 to 20 seconds and a firm time between 25 and 60 seconds;

D. fluorotrichloromethane in an amount from 5 to 20 weight percent based on the weight of the foam-forming mixture;

E. a surfactant in an amount from 0.1 to 2.0 weight percent based on the weight of the foam-forming mixture.

Ii. positioning a facing sheet comprising a metal foil between 0.010 and 0.001 inches thick on each face of the mat,

Iii. passing the facing sheets having the mat of glass fibers and the foam-forming mixture there between through the nip of two rotating rolls wherein;

A. the thickness of the mat before passing through the nip of the two rotating rolls is between 0.010 and 0.050 inches,

B. the thickness of the mat immediately after passing through the nip remains substantially the same as prior to passing through the nip,

C. the velocity of the mat is equal to the velocity of the facing sheets,

D. the glass fibers of the mat are arranged in layers,

E. the glass fibers within each layer are substantially parallel,

F. the glass fibers in each layer are at an angle of less than 60°

to the glass fibers in each next adjacent layer,

G. the glass fibers are attached to one another by an amount of fiber binder sufficient to make the mat of glass fibers dimensionally stable but insufficient to fill the interstices between the glass fibers and insufficient to resist the expansion of the glass fibers under the influence of the expansion of the foam-forming mixture,

H. the fibers forming the mat are wetable by the foam-forming mixture to the extent that the foam-forming mixture will penetrate and completely fill the interstices between the glass fibers of the mat,

I. the foam-forming mixture completely fills the interstices between the fibers of the mat,

J. the glass fibers of the mat have an average length that exceeds five feet.

Iv. passing the facing sheets having the mat and the foam forming mixture therebetween from the nip of the two rotating rolls into an expansion zone wherein;

A. the facing sheets having the mat and the foam-forming mixture therebetween are subjected to the influence of heat controlably added by the circulation of hot air for regulating the expansion of the foam-forming mixture,

B. the foam-forming mixture expands under the influence of the heat added by the hot air and under influence of heat generated in an exothermic reaction between the components of the foam-forming mixture,

C. the layers of the fibers in the mat separate under the sole influence of the expansion of the foam-forming mixture,

D. the layers of the fibers in the mat maintain their same order but are distributed throughout the resultant structural laminate in planes substantially parallel to the planes of the facing sheets,

V. curing the foam-forming mixture at a temperature of 175°

F. to 250 °

F. until the resultant structural laminate is rigidly self supporting,

Vi. periodically severing the structural laminate into finite lengths thereby forming discrete panels.

27. A structural laminate comprising:

A. at least one planar facing sheet;

B. a rigid foam integrally attached upon formation of the foam to one surface of the facing sheet, the rigid foam formed from a foam-forming mixture comprising;

I. an organic polyisocyanate, and

Ii. a diol having an equivalent weight between 30 to 100;

C. a mat of glass fibers wherein;

I. the glass fibers of the mat are distributed substantially evenly throughout the rigid foam,

Ii. the glass fibers are straight,

Iii. the glass fibers are long,

Iv. the glass fibers of the mat are arranged in layers,

V. each layer of glass fibers is substantially parallel to the facing sheet.

Vi. the rigid foam completely fills the interstices between the glass fibers of the mat, the glass fibers being held in fixed relationship with respect to each other solely by the rigid foam.

28. The structural laminate of claim 27 wherein there are two parallel facing sheets, one on each face of the rigid foam.

29. The structural laminate of claim 27 wherein the facing sheet is a metal foil between 0.010 and 0.001 inches thick.

30. The structural laminate of claim 27 wherein the surface of the facing sheet obverse to that attached to the rigid foam is decoratively embossed.

31. The structural laminate of claim 27 wherein the organic polyisocyanate is polymethylene polyphenyl isocyanate.

32. The structural laminate of claim 31 wherein the polymethylene polyphenyl isocyanate is a mixture of those of Formula I:

##STR5## wherein n is an integer from 0 to 8 inclusive.

33. The structural laminate of claim 32 wherein the polymethylene polyphenyl isocyanate has a functionality of at least 2.1.

34. The structural laminate of claim 32 wherein the polymethylene polyphenyl isocyanate has an equivalent weight of 120 to 180.

35. The structural laminate of claim 32 wherein the polymethylene polyphenyl isocyanate has a viscosity between 100 and 4,000 centipoises.

36. The structural laminate of claim 27 wherein the diol is one of Formula II:

space="preserve" listing-type="equation">ho--r.sup.1 --oh (ii)

wherein R¹ is selected from the group consisting of lower alkylene and lower alkoxyalkylene.

37. The structural laminate of claim 27 wherein the diol consists essentially of diethylene glycol.

38. The structural laminate of claim 27 wherein the equivalent ratio of the constituents of the foam-forming mixture I:

II is from 2;

1 to 6;

1.

39. The structural laminate of claim 27 wherein the glass fibers within each layer are substantially parallel to each other.

40. The structural laminate of claim 27 wherein the glass fibers in each layer are an acute angle to the glass fibers in each next adjacent layer.

41. A structural laminate comprising:

A. two planar facing sheets;

B. a rigid foam integrally attached upon formation of the foam between the facing sheets, the rigid foam formed from a foam-forming mixture comprising;

I. a mixture of polymethylene polyphenyl isocyanates of Formula a;

##STR6## wherein n is an integer from 0 to 8 inclusive, and II. a diol having an equivalent weight of 30 to 100 of Formula b;

Ho--r¹ --oh (b)

wherein R¹ is selected from the group consisting of lower alkylene and lower alkoxyalkylene,

wherein the equivalent ratio of I;

II is 2;

1 to 6;

1,

C. a mat of glass fibers wherein;

I. the glass fibers of the mat are distributed substantially evenly throughout the rigid foam,

Ii. the glass fibers are non-crimped,

Iii. the glass fibers are long,

Iv. the glass fibers of the mat are arranged in layers,

V. each layer of glass fibers is substantially parallel to the facing sheet,

Vi. the glass fibers within each layer are substantially parallel,

Vii. the glass fibers in each layer are at an acute angle to the glass fibers in each next adjacent layer and

Viii. the foam-forming mixture completely fills the interstices between the fibers of the mat, the fibers being held in fixed relationship with respect to each other solely by the rigid foam.

42. The structural laminate of claim 41 wherein each facing sheet is a metal foil between 0.010 and 0.001 inches thick.

43. The structural laminate of claim 41 wherein the surface of one facing sheet obverse to that attached to the rigid foam is decoratively embossed.

44. The structural laminate of claim 41 wherein the glass fibers have an average length that exceeds 5 feet.

45. The structural laminate of claim 41 wherein the glass fibers in each layer of the mat are at an angle of less than 60°

to the glass fibers in each the next adjacent layers.

46. The structural laminate of claim 41 wherein the mat of glass fibers is included in an amount of 4-24 gms. per board foot of structural laminate.

47. The structural laminate of claim 41 wherein the glass fibers in each layer are arranged in non-contiguous undulations in a plane parallel to the facing sheets.

48. A structural laminate comprising:

A. two planar facing sheets wherein;

I. each facing sheet is a metal foil between 0.010 and 0.001 inches thick,

Ii. the surface of one facing sheet observe to that attached to the rigid foam is decoratively embossed;

B. a rigid foam integrally attached upon formation of the foam to one surface of each facing sheet, the rigid foam formed from a foam-forming mixture comprising;

I. a mixture of polymethyl polyphenyl isocyanates, of Formula a;

##STR7## wherein n is an integer from 0 to 8 and the polyisocyanates have an equivalent weight of 120 to 180 and a functionality of 2.5 to 3.8 and the mixture has a vecosity of 250 to 2500 centipoises;

Ii. diethylene glycol, wherein the equivalent ratio of I;

II is between 3.0;

1 and 5.0;

1;

Iii. a catalyst composition in an amount and of a type sufficient to give the foam-forming mixture a cream time between 15 and 20 seconds and a firm time between 25 and 60 seconds;

Iv. fluorotrichloromethane in an amount from 5 to 20 weight percent based on the weight of the foam-forming mixture;

V. a surfactant in an amount from 0.1 to 2.0 weight percent based on the weight of the foam-forming mixture.

C. a mat of glass fibers wherein;

I. the glass fibers of the mat are distributed substantially evenly throughout the rigid foam,

Ii. the glass fibers are non-crimped,

Iii. the glass fibers have an average length that exceeds five feet,

Iv. the glass fibers of the mat are arranged in layers,

V. each layer of glass fibers is substantially parallel to the facing sheet,

Vi. the glass fibers within each layer are substantially parallel,

Vii. the glass fibers in each layer are at an angle of less than 60°

to the glass fibers in each next adjacent layer, and

Viii. the foam-forming mixture completely fills the interstices between the fibers of the mat, the fibers being held in fixed relationship to each other solely by the rigid foam,

Ix. the mat of glass fibers being included in the amount of 6-20 gms. per board-foot of structural laminate.