Laundering process for dual bleaching stained fabrics

• US 4,120,650 A
• Filed: 12/05/1977
• Issued: 10/17/1978
• Est. Priority Date: 12/05/1977
• Status: Expired due to Term

• Current Assignee: Diversey Wyandotte Corporation
• Original Assignee: BASF Wyandotte Corporation
• Inventors: Kappler, Frank Robert, Killian, Roma Jean, Cramer, John Joseph
• Primary Examiner(s): Schulz, William E.
• Application Number:
  US05/857,675
• Time in Patent Office: 316 Days
• Field of Search: 8/109, 8/108 A, 8/111, 8/137, 252/95
• US Class Current: 8/109
• CPC Class Codes: C11D 3/39 Organic or inorganic per-compounds
• CPC Class Codes: C11D 3/395 Bleaching agents
• CPC Class Codes: D06L 4/10 using agents which develop oxygen D06L4/20 takes precedence
• CPC Class Codes: D06L 4/20 using agents which contain halogen
• CPC Class Codes: D06L 4/21 combined with specific additives D06L4/24 takes precedence
• CPC Class Codes: D06L 4/22 using inorganic agents
• CPC Class Codes: D06L 4/23 using hypohalogenites

Abstract

Stained textile fabrics, especially cotton-polyester, rayon-polyester blends stained in use with blood stains, can be reclaimed and returned to use by the process of washing and bleaching said fabrics in the presence of a non-ionic or anionic surface-active agent, together with an oxygen-releasing bleaching agent and a chlorine-releasing bleaching agent, said bleaching agents used either successively or simultaneously. The laundering process involves the use of aqueous solutions of bleaching agents at elevated temperatures and at high pH. The process of the invention provides a synergistic improvement in the removal of stains as compared with the use of either an oxygen-releasing bleaching agent or a chlorine-releasing bleaching agent. The process can include a hot aqueous acid sour treatment to remove rust stains and an aqueous sour to neutralize alkalies in the bleached fabric. The treatment can be completed in a period of time of about 30 to about 90 minutes.

Claims

1. A method of reclaiming stained cellulosic and cellulosic-polyester blend textile fabrics by a washing and bleaching process comprising:

bleaching said textile fabrics in an aqueous solution of at least one anionic or non-ionic surface-active agent at a concentration of about 0.01 percent to about 0.25 percent by weight in admixture with (a) about 0.01 percent to about 1 percent by weight of a chlorine-releasing agent and (b) about 0.01 percent to about 2 percent by weight of an oxygen-releasing agent at a pH of about 9 to about 12, a temperature of about 160°

F. to about 190°

F. for a period of time of about 5 minutes to about 30 minutes.

2. The method of claim 1 wherein said process includes a pre-treatment with a rust-removing acid sour at a pH of about 1 to about 7, at a temperature of about 120°

F. to about 180°

F. for a period of time of about 2 minutes to about 15 minutes.

3. The method of claim 2 wherein said process includes a post-treatment with an acid sour and said acid sour is an acid fluoride salt selected from the group consisting of sodium silicofluoride and sodium bifluoride.

4. The method of claim 2 wherein said acid sour is oxalic acid.

5. The process of claim 2 wherein said bleaching solution contains an alkaline builder.

6. The method of claim 2 wherein said fabric is (a) a cotton or polyester-cotton blend fabric containing blood stains or (b) said fabric containing blood stains and treated with a synthetic resin, wrinkle-resistant finish.

7. The method of claim 2 wherein said chlorine-releasing bleaching agent is selected from the group consisting of alkali metal and alkaline earth metal hypochlorites, chlorinated hydantoins, chlorinated alkali metal isocyanurates, chlorinated isocyanuric acid, and mixtures thereof, and wherein said oxygen-releasing bleaching agent is selected from the group consisting of at least one of hydrogen peroxide, and a peroxygen compound.

8. A method of reclaiming, by a washing and bleaching process, stained fabrics consisting of cotton, cotton-polyester blends and rayon-polyester blends at a pH of about 9 to about 12 and a temperature of about 160°

F. to about 190°

F. comprising the sequential aqueous treatment, of said fabrics in two stages with a chlorine-releasing agent and an oxygen-releasing agent in any order, wherein in each stage, said bleaching agent is present in an aqueous solution in the presence of about 0.01 percent to about 0.25 percent by weight of at least one anionic or non-ionic surface active agent, and wherein said oxygen-releasing agent is present in the concentration of about 0.01 percent to about 2 percent by weight and is selected from the group consisting of at least one of hydrogen peroxide, alkali metal and alkaline earth metal perborates, percarbonates, persilicates, and peroxides and wherein said chlorine-releasing bleaching agent is present in the concentration of about 0.01 percent to about 1 percent by weight and is selected from the group consisting of the alkali metal hypochlorites, the alkaline earth metal hypochlorites, dichlorodimethylhydantoin, the chlorinated alkali metal isocyanurates, the chlorinated isocyanuric acids, and mixtures thereof.

9. The method of claim 8 wherein said stained fabric is pre-treated with a rust-removing sour comprising an aqueous solution of an acid fluoride salt selected from the group consisting of sodium silicofluoride and sodium bi-fluoride or oxalic acid, said solution having a pH of about 1 to about 7 and at a temperature of about 120°

F. to about 180°

F., said pre-treatment being for a period of time between 2 minutes to about 15 minutes.

10. The method of claim 8 wherein said aqueous solution of a chlorine-releasing bleaching agent and an oxygen-releasing bleaching agent contains an alkaline builder.

11. The method of claim 10 wherein said builder is selected from the group consisting of at least one of the alkali metal and alkaline earth metal phosphates including polyphosphates and pyrophosphates, silicates, carbonates, sulfates, and borates.

12. The method of claim 8 wherein said fabric is (a) a cotton or polyester-cotton blend fabric containing blood stains or (b) said fabric containing blood stains and treated with a wrinkle-resistant synthetic resin finish.

13. The method of claim 8 wherein said non-ionic surface active agent is selected from the group consisting of polyoxyethylene and polyoxyalkylene ethers of higher alcohols and higher alkyl phenols, and mixtures thereof.

14. The method of claim 8 wherein said chlorine-releasing agent is trichloroisocyanuric acid and wherein said oxygen-releasing agent is sodium perborate tetrahydrate.