Isolation of pure ammonia from gas mixtures containing ammonia and carbon dioxide

• US 4,120,667 A
• Filed: 10/12/1977
• Issued: 10/17/1978
• Est. Priority Date: 10/16/1976
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Gettert, Hans, Schier, Ernst-Juergen, Schneehage, Hans Henning, Molzahn, Martin, Fromm, Hermann Dieter
• Primary Examiner(s): Wyse, Thomas G.
• Assistant Examiner(s): Burks, Richard W.
• Application Number:
  US05/841,552
• Time in Patent Office: 370 Days
• Field of Search: 55/46, 55/48, 55/56, 55/68, 55/70, 55/89, 55/93
• US Class Current: 95/179
• CPC Class Codes: B01D 53/14 by absorption
• CPC Class Codes: B01D 53/1406 Multiple stage absorption
• CPC Class Codes: C01C 1/12 Separation of ammonia from gases and vapours as part of the ammonia synthesis process C01C1/04
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

To isolate ammonia from gas mixtures containing ammonia and carbon dioxide, the gas mixture is first partially absorbed in a solvent, with residence times of at most 0.1 second, and the non-absorbed gas is then separated from the solution obtained. The solution is then subjected to a first desorption stage, in which only the ammonia present in an excess over a molar ratio of 3 parts of ammonia to 1 part of carbon dioxide is expelled by heating, and the entrained carbon dioxide is washed out of the expelled ammonia by means of solutions containing free ammonia. The solution remaining after the first desorption stage is substantially freed from ammonia and carbon dioxide in a second desorption stage and the expelled gas, containing solvent, together with fresh gas mixture is fed to the adsorption stage, while the solvent obtained from the second desorption stage is employed for the absorption.

Claims

1. A process for isolating ammonia from gas mixtures containing ammonia and carbon dioxide by partially absorbing the gas mixture in a solvent, with intimate mixing and using residence times of at most 0.1 second, then separating the non-absorbed gas mixture and the solution obtained, and desorbing the solution containing excess ammonia, wherein, in a first desorption stage, only the ammonia present in an excess over a molar ratio of 3 parts of ammonia to 1 part of carbon dioxide is expelled by heating and the entrained carbon dioxide is washed out of the expelled ammonia with solutions which contain free ammonia, the residual solution from the first desorption stage is substantially freed from ammonia and carbon dioxide in a second desorption stage, the expelled solvent-containing gas together with fresh gas mixture is recycled to the absorption and the solvent obtained from the second desorption stage is employed as solvent in the absorption.

2. A process as claimed in claim 1, in which only a part-stream of the solution to be desorbed is introduced directly into the desorption zone and the remaining part-stream is employed to wash out the carbon dioxide expelled with the ammonia in the first desorption stage, before passing said part-stream to the desorption zone.

3. A process as claimed in claim 1, in which the first desorption stage is operated at from 75°

to 90°

C.

4. A process as claimed in claim 1, in which the second desorption stage is operated at from 87°

to 98°

C.

5. A process as claimed in claim 1, in which the solution leaving the second desorption stage still has a residual content of up to 4% by weight of ammonia.

6. A process as claimed in claim 1, in which the carbon dioxide is washed out in one stage, at from 35°

to 50°

C.

7. A process as claimed in claim 1, in which the carbon dioxide is washed out of the ammonia, expelled in the first desorption stage, in at least two stages.

8. A process as claimed in claim 7, in which the wash stage immediately following the desorption is carried out at from 50°

to 80°

C and the last wash stage is carried out at from 35°

to 50°

C.

9. A process as claimed in claim 8, in which the wash stage immediately following the desorption is operated adiabatically.

10. A process as claimed in claim 1, in which the amount of the solution, containing free ammonia, used to wash out the carbon dioxide is so chosen that after washing out the carbon dioxide the said solution does not contain more than 12% by weight of carbon dioxide at from 35°

to 50°

C, when saturated with ammonia.