Process for manufacturing foamed materials involving contacting a thin unbroken film of liquid resin with a gaseous blowing agent under pressure

• US 4,120,923 A
• Filed: 08/15/1975
• Issued: 10/17/1978
• Est. Priority Date: 08/21/1974
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Kloker, Werner, Bovender, Franz, Gromping, Franz, Goerden, Leonhard, Niesel, Harald
• Primary Examiner(s): Anderson, Philip
• Application Number:
  US05/605,026
• Time in Patent Office: 1,159 Days
• Field of Search: 264/50, 264/54, 264/45.3, 264/DIG. 5, 264/DIG. 13, 264/DIG. 17, 264/DIG. 2, 264/45.8, 260/2.5 BC, 260/2.5 BD, 260/2.5 R, 260/2.5 F, 260/2.5 BP, 260/2.5 N, 23/289, 23/290, 261/112
• US Class Current: 264/45.3
• CPC Class Codes: B29B 7/7409 with supply of gas
• CPC Class Codes: B29B 7/7621 involving introducing a gas or another component in at least one of the components
• CPC Class Codes: B29C 44/06 Making multilayered articles B29C44/0407 - B29C44/0492 take precedence
• CPC Class Codes: B29C 44/3453 Feeding the blowing agent to solid plastic material
• CPC Class Codes: Y10S 264/02 Molding cellular aldehyde resins
• CPC Class Codes: Y10S 264/05 Use of one or more blowing agents together
• CPC Class Codes: Y10S 264/13 Cell size and distribution control while molding a foam
• CPC Class Codes: Y10S 264/17 Molding a foam containing a filler
• CPC Class Codes: Y10S 521/917 Specialized mixing apparatus utilized in cell forming process

Abstract

Stable foams of reaction resins and/or condensation resins can be obtained by adding a blowing agent which is gaseous under normal conditions to the resin under pressure, the gas liquid interface being enlarged while dispensing with moving equipment, allowing the mixture to expand and to cure.

Claims

1. A process of manufacturing foamed materials from a liquid thermosetting resin having a viscosity less than 6000 cP, comprising the steps of contacting a thin unbroken film of the liquid resin in a pressure vessel under pressure of 3 to 350 bars at a temperature of between 0°

to 50°

C. for a residence time of 0.1 to 120 minutes with a blowing agent having a boiling point under normal pressure which is below 0°

C., causing the liquid resin to smoothly flow without absorbing discernible bubbles of the blowing agent down and over an elongated surface means having a vertical component disposed within the pressure vessel whereby the liquid resin film absorbs the blowing agent so rapidly that the resin film flowing off from the elongated surface means can immediately be withdrawn from the pressure vessel, deposited on a surface, subjected to pressure release, allowed to expand and to cure into a foamed resin.

2. The process as set forth in claim 1, wherein the liquid resin is caused to flow over a series of vertically disposed smooth plates in the pressure vessel by disposing the series of plates vertically in the pressure vessel with their upper ends passing through substantially closed apertures in a horizontal distributing bulkhead, the upper ends of the plates constituting overflow weirs within the pressure vessel, the liquid resin being supplied in front of the first overflow weir whereby liquid film first flows down the front and then the back surfaces of the first plate and thereafter down the following front and back surfaces of successive plates as the liquid resin builds up on the bulkhead and flows successively over each of the weirs.

3. The process of claim 1 wherein the liquid resin contacted in said pressure vessel contains at least one member selected from the group consisting of curing agents, accelerators and fillers.