Method of machine washing of solid soiled materials by contacting the circulating wash liquid with aluminosilicates

• US 4,121,903 A
• Filed: 11/02/1977
• Issued: 10/24/1978
• Est. Priority Date: 11/02/1976
• Status: Expired due to Term

• Current Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Original Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Inventors: Smolka, Heinz
• Primary Examiner(s): Schulz, William E.
• Application Number:
  US05/847,791
• Time in Patent Office: 356 Days
• Field of Search: 8/137, 8/141, 252/179, 68/13 A, 210/24, 210/38 A
• US Class Current: 8/137
• CPC Class Codes: A47L 15/4229 Water softening arrangements
• CPC Class Codes: C11D 2111/12 Soft surfaces, e.g. textile
• CPC Class Codes: C11D 2111/14 Hard surfaces
• CPC Class Codes: C11D 2111/46 applying energy, e.g. irradiation
• CPC Class Codes: C11D 3/12 Water-insoluble compounds
• CPC Class Codes: C11D 3/1246 Silicates, e.g. diatomaceous earth
• CPC Class Codes: C11D 3/128 Aluminium silicates, e.g. zeolites C11D3/1253 takes precedence
• CPC Class Codes: D06F 39/10 Filtering arrangements
• CPC Class Codes: D06L 1/12 using aqueous solvents

Abstract

An improvement in the machine washing of solid soiled materials comprising withdrawing and recycling the tap water in contact with said solid soiled materials through a silicate cation exchange compound having some combined water and a particle size of between 10 μ and 100 μ of the formula

(M.sub.2/n O).sub.x . Me.sub.2 O.sub.3 . (SiO.sub.2).sub.y

wherein M is a cation of valence n exchangeable with calcium, Me is a member selected from aluminum and boron, x is a number from 0.7 to 1.5 and y is a number from 0.8 to 6, said agent having a calcium binding power of at least 50 mg of CaO per gram, said agent being maintained out of contact with said solid soiled materials, for such time until the water has a hardness of not more than 70 mg CaO/liter, then adding other soluble washing and cleaning compounds to said softened tap water and washing said solid materials while continuing the recycling of the wash solution through said silicate cation exchange compound.

Claims

1. A method for machine washing and cleaning of solid materials utilizing washing and cleaning solutions in the presence of water-insoluble cation exchange agents which are capable of binding the hardness components of the water and the soil, comprising withdrawing and recycling the tap water having a hardness of more than 80 mg CaO/liter in contact with said solid soiled materials through a silicate cation exchange compound having some combined water and a particle size of between 10μ

and 100μ

of the formula

space="preserve" listing-type="equation">(M.sub.2/n O).sub.x . Me.sub.2 O.sub.3 . (SiO.sub.2).sub.y

wherein M is a cation of valence n exchangeable with calcium, Me is a member selected from aluminum and boron, x is a number from 0.7 to 1.5 and y is a number from 0.8 to 6, said agent having a calcium binding power of at least 50 mg of CaO per gram, said silicate cation exchange compound being maintained out of contact with said solid soiled materials in a separate area from the washing area, for such time until the water has a hardness of not more than 70 mg CaO/liter, then adding other soluble washing and cleaning compounds to said softened tap water and washing said solid materials while continuing the recycling of the wash solution through said silicate cation exchange compound, wherein the total amount of washing solution is continuously or intermittently cyclically circulated from the washing area through the separate area with the cation exchange compound and then back to the washing area at least five times during the cleaning process, and where the amount of the cation exchange compound is 0.2 gm to 10 gm per liter of washing solution, and said washing solution contains from 0.2 to 10 gm per liter of other soluble washing and cleaning compounds.

2. The process of claim 1 wherein said tap water is recycled until the water has a hardness of less than 50 mg CaO/liter.

3. The process of claim 1 wherein said tap water is recycled until the water has a hardness of less than 30 mg CaO/liter.

4. The process of claim 1 wherein said solid soiled materials are textiles.

5. The process of claim 1 wherein said silicate cation exchange compound is maintained out of contact with said solid soiled materials in a separate area from the washing area by a filter means.

6. The process of claim 5 wherein said filter means is a static bed filter means.

7. The process of claim 5 wherein said filter means is a fluidized bed filter means.

8. The process of claim 1 wherein said silicate cation exchange compound has a calcium binding power of from 100 to 200 mg CaO/gm.

9. The process of claim 1 wherein said silicate cation exchange compound has the formula:

space="preserve" listing-type="equation">(Na.sub.2 O).sub.0.7-1.5 . Al.sub.2 O.sub.3 . (SiO.sub.2).sub.1.3-3.3.

10. The process of claim 1 wherein said silicate cation exchange compound is crystalline.

11. The process of claim 1 wherein said other soluble washing and cleaning compounds include an anionic surface-active compound.

12. The process of claim 1 wherein said other soluble washing anc cleaning compounds include a water-soluble sequestering agent for calcium ions.