Process for producing polycarbonate oligomers

• US 4,122,112 A
• Filed: 06/06/1977
• Issued: 10/24/1978
• Est. Priority Date: 06/09/1976
• Status: Expired due to Term

• Current Assignee: Mitsubishi Gas Chemical Company Incorporated (Mitsubishi Electric Corporation)
• Original Assignee: Mitsubishi Gas Chemical Company Incorporated (Mitsubishi Electric Corporation)
• Inventors: Yoshizaki, Hiroyuki, Megumi, Takeaki, Koda, Hiroyuki
• Primary Examiner(s): Pertilla, Theodore E.
• Application Number:
  US05/804,169
• Time in Patent Office: 505 Days
• Field of Search: 260/463, 260/47 XA, 260/77.5 D, 260/95 C, 260/49
• US Class Current: 558/268
• CPC Class Codes: C07C 68/02 from phosgene or haloformates
• CPC Class Codes: C07C 69/96 Esters of carbonic or haloformic acids
• CPC Class Codes: C08G 64/00 Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule polycarbonate-amides C08G69/44; polycarbonate-imides C08G73/16

Abstract

A process for producing polycarbonate oligomers by the reaction of dihydroxy compounds with phosgene, which comprises contacting a mixture of a dihydroxy compound and an aqueous alkali solution with phosgene in the presence of an organic solvent in a tubular reactor to perform a first-stage reaction, introducing the first-stage reaction mixture into a tank-type reactor equipped with a stirrer and containing the aqueous alkali solution and a solution in the organic solvent of a polycarbonate oligomer formed by the reaction of the first-stage reaction product in a second stage, and performing the second-stage reaction while stirring the reaction mixture in the tank-type reactor and maintaining it at a predetermined temperature by sufficient removal of the heat of reaction.

Claims

1. A process for producing polycarbonate oligomers by the reaction of dihydroxy compounds with phosgene, which comprises contacting a mixture of a dihydroxy compound and an aqueous alkali solution with phosgene in the presence of an organic solvent in a tubular reactor to perform a first-stage reaction wherein the reaction time is from 0.5 to 15 seconds, introducing the first-stage reaction mixture into a tank-type reactor equipped with a stirrer and containing the aqueous alkali solution and a solution in the organic solvent of a polycarbonate oligomer formed by the reaction of the first-stage reaction product in a second stage, and performing the second-stage reaction, wherein the reaction time is from 5 to 20 minutes, while stirring the reaction mixture in the tank-type reactor and maintaining it at a predetermined temperature by sufficient removal of the heat of reaction.

2. The process of claim 1 wherein the dihydroxy compound is at least one compound of the formula ##STR5## wherein Y represents an alkylene group containing 1 to 12 carbon atoms, --O--, --S--, ##STR6## and R₁, R₂, R₃ and R₄, independently from each other, represent a hydrogen atom, an alkyl group containing 1 to 3 carbon atoms, a chlorine atom or a bromine atom.

3. The process of claim 1 wherein the aqueous alkali solution is a 5-10% by weight aqueous solution of a basic hydroxide selected from the group consisting of sodium hydroxide and potassium hydroxide, the basic hydroxide being used in an amount of 2.2 to 3.0 moles per mole of the dihydroxy compound.

4. The process of claim 1 wherein the organic solvent is an organic solvent which is inert to the reaction and can dissolve the polycarbonate oligomer and a polycarbonate obtained by polymerizing it.

5. The process of claim 1 wherein a mixture at 10°

to 30°

C. of the dihydroxy compound and the aqueous alkali solution and a solution at -10°

to +20°

C. of the phosgene in the organic solvent are fed into the tubular reactor.