Particulate detergent composition containing dibasic magnesium hypochlorite

• US 4,123,377 A
• Filed: 08/25/1977
• Issued: 10/31/1978
• Est. Priority Date: 08/25/1977
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Davey, Christopher R., Buckley, Peter J.
• Primary Examiner(s): Weinblatt, Mayer
• Application Number:
  US05/827,759
• Time in Patent Office: 432 Days
• Field of Search: 252/95, 252/99, 252/103, 252/187 H, 8/108 R, 423/473, 423/474
• US Class Current: 510/302
• CPC Class Codes: C11D 3/3953 Inorganic bleaching agents C11D3/3951 takes precedence

Abstract

A particulate detergent composition containing dibasic magnesium hypochlorite having a specific small particle size as the bleaching agent.

Claims

1. A particulate detergent composition consisting essentially of

(a) from 5 to 50% by weight of an organic detergent surfactant;

(b) from 0 to 90% by weight of a detergency builder and mixtures thereof;

(c) from 1 to 50% by weight of the bleaching agent dibasic magnesium hypochlorite having an average particle diameter of less than about 88 microns; and

(d) from 0 to about 50% of a buffering agent, there being at least 1% of said buffering agent where the dibasic magnesium hypochlorite particle diameter is greater than about 45μ

m to give compositions having a pH of from about 8.0 to about 9.6 when added to water at a concentration of 1500 parts per million detergent.

2. The composition of claim 1 wherein the dibasic magnesium hypochlorite has an average particle diameter of less than 45 microns.

3. The composition of claim 2 wherein the detergency builder is selected from the group consisting of hydrated alkali metal zeolite A, zeolite X, or zeolite B, an alkali metal pyrophosphate, an alkali metal tripolyphosphate, and alkali metal silicate having an SiO₂ :

M₂ O ratio of from about 1.6 to about 4, and mixtures thereof.

4. The composition of claim 3 wherein the alkali metal silicate has a weight ratio SiO₂ :

M₂ O of about 1.6 to about 3.2.

5. The composition of claim 3 wherein the alkali metal pyrophospate is sodium pyrophosphate.

6. The composition of claim 3 wherein the builder is a mixture consisting essentially of:

(a) from 10 to about 25% by weight of the total composition of an alkali metal pyrophosphate;

(b) from 7 to about 15% by weight of the total composition of hydrated alkali metal zeolite A; and

(c) from 7 to about 15% by weight of the total composition of the alkali metal silicate.

7. The composition of claim 2 wherein the organic detergent surfactant is anionic.

8. The composition of claim 7 wherein the anionic detergent is selected from the group consisting of alkyl benzene sulfonates, alkyl polyethoxy sulfates, alkyl sulfates, paraffin sulfonates, and mixtures thereof.

9. The composition of claim 8 wherein the anionic detergent composition is a mixture consisting essentially of:

(a) from about 2 to about 20% by weight of the total composition of a C₉ -C₁₅ alkali metal ammonium, or alkanolammonium alkyl benzene sulfonate;

(b) from about 2 to about 20% by weight of the total composition of a C₈ -C₁₆ alkali metal alkyl polyethoxylate sulfate, containing from one to about six ethylene oxide moieties; and

(c) from about 2% to about 20% by weight of the total composition of a C₈ -C₂₄ alkali metal, ammonium, or alkanolammonium tallow alcohol sulfate.

10. The composition of claim 8 wherein the detergency builder is selected from the group consisting of a hydrated alkali metal zeolite A, zeolite X, or zeolite B, an alkali metal pyrophosphate, an alkali metal tripolyphosphate, an alkali metal silicate having an SiO₂ :

M₂ O ratio of from about 1.6 to about 4.0, and mixtures thereof.

11. The composition of claim 1 wherein the dibasic magnesium hypochlorite has an average particle diameter of less than about 10 microns.

12. The composition of claim 11 wherein the detergency builder is selected from the group consisting of a hydrated alkali metal zeolite A, zeolite X, or zeolite B, an alkali metal pyrophosphate, an alkali metal tripolyphosphate, an alkali metal silicate having an SiO₂ :

M₂ O ratio of from about 1.6 to about 4.0, and mixtures thereof.

13. The composition of claim 11 wherein the anionic detergent is selected from the group consisting of a C₉ -C₁₅ alkali metal alkyl benzene sulfonate, a C₈ -C₁₆ alkali metal alkyl polyethoxylate sulfate, containing from one to about six ethylene oxide moieties, a C₈ -C₂₄ alkali metal tallow alcohol sulfate, a C₈ -C₂₀ alkali metal paraffin sulfonate, and mixtures thereof.

14. The composition of claim 13 wherein the detergency builder is selected from the group consisting of a hydrated alkali metal zeolite A, zeolite X, or zeolite B, an alkali metal pyrophosphate, an alkali metal tripolyphosphate, an alkali metal silicate having an SiO₂ :

M₂ O ratio of from 1.6 to about 4.0, and mixtures thereof.

15. The composition of claim 1 wherein the dibasic magnesium hypochlorite has an average particle diameter in the range 6-12 microns.

16. The composition of claim 15 wherein the detergency builder is selected from the group consisting of a hydrated alkali metal zeolite A, zeolite X, or zeolite B, an alkali metal pyrophosphate, an alkali metal tripolyphosphate, an alkali metal silicate having an SiO₂ :

M₂ O ratio of from about 1.6 to about 4.0, and mixtures thereof.

17. The composition of claim 15 wherein the anionic detergent is selected from the group consisting of a C₉ -C₁₉ alkali metal alkyl benzene sulfonate, a C₈ -C₁₆ alkali metal polyethoxylate sulfate, containing from one to about six ethylene oxide moieties, a C₈ -C₂₄ alkali metal tallow alcohol sulfate, a C₈ -C₂₀ alkali metal paraffin sulfonate, and mixtures thereof.

18. The composition of claim 17 wherein the detergency builder is selected from the group consisting of a hydrated alkali metal zeolite A, zeolite X, or zeolite B, an alkali metal pyrophosphate, an alkali metal tripolyphosphate, an alkali metal silicate having an SiO₂ :

M₂ O ratio of from 1.6 to about 4.0, and mixtures thereof.

19. The composition of claim 1 wherein the dibasic magnesium hypochlorite has an average particle diameter in the range of 45-88 microns.

20. The composition of claim 19 wherein the buffering agent is sodium bicarbonate.

21. The composition of claim 20 wherein the detergency builder is selected from the group consisting of a hydrated alkali metal zeolite Z, zeolite X, or zeolite B, an alkali metal pyrophosphate, an alkali metal tripolyphosphate, an alkali metal silicate having an SiO₂ :

M₂ O ratio of from 1.6 to about 4, and mixtures thereof.

22. The composition of claim 20 wherein the anionic detergent is selected from the group consisting of a C₉ -C₁₅ alkali metal alkyl benzene sulfonate, a C₈ -C₁₆ alkali metal polyethoxylate sulfate containing from one to about six ethylene oxide moieties, a C₈ -C₂₄ alkali metal tallow alcohol sulfate, a C₈ -C₂₀ alkali metal paraffin sulfonate, and mixtures thereof.

23. The composition of claim 22 wherein the detergency builder is selected from the group consisting of a hydrated alkali metal zeolite A, zeolite X, or zeolite B, and alkali metal pyrophosphate, an alkali metal tripolyphosphate, and alkali metal silicate having SiO₂ :

M₂ O ratio of about 1.6 to about 4.0, and mixtures thereof.

24. The composition of claim 20 wherein the buffering agent sodium bicarbonate is present in such quantity to give an initial pH in solution of from 8.5 to about 9.5.

25. The composition of claim 24 wherein the detergency builder is selected from the group consisting of a hydrated alkali metal zeolite A, zeolite X, or zeolite B, and alkali metal pyrophosphate, an alkali metal tripolyphosphate, an alkali metal silicate having SiO₂ :

M₂ O ratio of about 1.6 to about 4.0, and mixtures thereof.

26. The composition of claim 24 wherein the anionic detergent is selected from the group consisting of alkyl benzene sulfonates, alkyl polyethoxy sulfates, and alkyl sulfates, paraffin sulfonates, and mixtures thereof.

27. The composition of claim 26 wherein the detergency builder is selected from the group consisting of a hydrated alkali metal zeolite A, zeolite X, or zeolite B, and alkali metal pyrophosphate, an alkali metal tripolyphosphate, and alkali metal silicate having SiO₂ :

M₂ O ratio of about 1.6 to about 4.0, and mixtures thereof.