Potentiostated, self-humidifying, solid polymer electrolyte carbon monoxide dosimeter

• US 4,123,700 A
• Filed: 11/14/1977
• Issued: 10/31/1978
• Est. Priority Date: 11/14/1977
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: LaConti, Anthony B., Jones, Robert C., Torkildsen, Robert A.
• Primary Examiner(s): Tokar, M.
• Application Number:
  US05/851,129
• Time in Patent Office: 351 Days
• Field of Search: 324/29, 324/182, 204/195 R, 204/195 S
• US Class Current: 324/425
• CPC Class Codes: G01N 27/4045 for gases other than oxygen
• CPC Class Codes: G01N 27/423 Coulometry
• CPC Class Codes: G01R 22/02 by electrolytic methods

Abstract

A dosimeter for measuring accumulated dosage of noxious gases, such as carbon monoxide (CO), oxides of nitrogen, (NO_x), etc., incorporates a gas-sensing electrochemical cell which utilizes an electrically biased, hydrated, solid polymer electrolyte (SPE) sensing cell. CO and other noxious gases are oxidized at the sensing electrode and the cell current is a measure of the gas concentration. The cell output current is applied to an electrically resettable current integrating device, which is basically an integrating coulometer in which metal is plated onto a working electrode in response to the cell output current. A fixed, reverse calibration current is driven through the coulometer during dosage readout to deplate the metal from the coulometer working electrode. An accurate timing device measures the time required to deplate the working electrode of the coulometer. This product of the fixed calibrating current and the time required to reset the coulometer, i.e., deplate the working electrode is a measure of the gas dosage.

Claims

1. A gas dosage instrumentality for measuring the total quantity of a selected gas comprising the combination of;

(a) a gas-sensing cell for electrochemically converting the selected gas to produce an electrical signal directly related to the concentration of the selected gas,

(b) means for bringing gaseous samples to said sensing cell,

(c) means for measuring the total quantity of the selected gas sensed by said cell, including

(1) a reversible, electrochemical integrating device for continuously storing the signals from said cell to provide a measure of the accumulated quantity of the selected gas,

(2) means coupled to said integrating device for selectively applying an electrical resetting signal thereto for readout of the stored information and to reset the integrating device,

(3) means responsive to said resetting signal for measuring and indicating the accumulated dosage.

2. The gas dosage instrumentality according to claim 1 wherein said integrating device is an integrating coulometer in which a metal is electrochemically plated onto an electrode in response to the signal from the sensing cell and is electrochemically removed in response to the resetting signal, said coulometer providing a triggering signal when all the metal has been removed and readout is terminated.

3. The gas dosage instrumentality according to claim 2 wherein said reset signal generating means includes a current source for driving a fixed reverse current through said coulometer to remove metal during readout.

4. The gas dosage instrumentality according to claim 3 wherein the dosage measuring and indicating means includes timing means to determine the duration of flow of the fixed, reverse, resetting current, said timing means being actuated upon initiation of reverse current flow and terminated in response to the triggering signal.

5. The gas dosage instrumentality according to claim 1 wherein said gas-sensing cell includes a solid electrolyte, catalytic sensing and counter-electrodes in contact with and positioned on opposite sides of said solid electrolyte, and means for electrically biasing said electrodes to produce electrochemical conversion of the selected gas at said sensing electrode.

6. The gas dosage instrument according to claim 5 wherein said integrating device is an integrating coulometer wherein storage occurs by electrochemical deposition of a material through electron flow into said coulometer, whereby the quantity of deposited material is a direct measure of the amount of gas sensed.

7. The dosage instrument according to claim 6 wherein said reset signal generating means includes a current source for driving a fixed, reverse current through said coulometer to remove deposited metal.

8. The gas dosage instrumentality according to claim 7 including timing means to determine the duration of flow of the fixed, reverse current as a measure of the gas dosage.

9. In a gas dosimeter, the combination comprising,

(a) a gas-sensing cell for electrochemically converting a selected gas to produce an electrical signal directly related to the concentration of that gas,

(b) means for bringing gaseous samples to the cell whereby said cell produces an electrical signal whenever the gaseous samples contain the selected gas,

(c) means to accumulate the total quantity of the selected gas sensed by said cell, including

(1) a reversible electrochemical integrating device capable of storing quantity information by electrochemical deposition of a material in the device by electron flow in one direction through the device, said deposited material being electrochemically removable by electron flow in the opposite direction,

(2) means coupled to said integrating device to convert the signals from said cell to electron flow for electrochemically depositing a material, whereby the quantity of the deposited material is a direct measure of the amount of the selected gas.

10. The gas dosimeter according to claim 9 wherein said cell comprises a non-aqueous, solid electrolyte, a sensing electrode, and a counter-electrode in contact with said solid electrolyte on opposite sides thereof, and means coupling said cell to said integrating device.

11. The gas dosimeter according to claim 10 including means to produce an indication when the output signal from said cell shows that the concentration of the selected gas sensed by the cell exceeds a predetermined level.

12. The gas dosimeter according to claim 10 wherein the integrating coulometer in which a metal is electrochemically plated onto an electrode in response to electron flow in said one direction and removed from the electrode in response to electron flow in the other direction.

13. The gas dosimeter according to claim 10 wherein the non-aqueous electrolyte in said gas-sensing cell is an ion exchange membrane and the said sensing and counterelectrodes are positioned on opposite sides of said membrane.

14. The gas dosimeter according to claim 13 wherein said cell includes a reference electrode on the same side of the said membrane as the sensing electrode, potentiostatic circuit means interconnecting said sensing, reference and counterelectrodes to maintain the potentials at the potential differences between said electrodes such as to produce rapid electrochemical conversion of the selected gas without interference due to electrochemical conversion of other gases or due to water.

15. The gas dosimeter according to claim 14 including further means for selectively maintaining said cell partially energized in a non-sensing mode of operation and fully energized in a sensing mode whereby said dosimeter rapidly reaches the sensing mode and has low power dissipation in the non-sensing mode.