Polycondensates

• US 4,124,568 A
• Filed: 11/23/1977
• Issued: 11/07/1978
• Est. Priority Date: 11/29/1976
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Merten, Rudolf, Zecher, Wilfried, Dunwald, Willi
• Primary Examiner(s): Phynes, Lucille M.
• Application Number:
  US05/854,112
• Time in Patent Office: 349 Days
• Field of Search: 260/75 N, 260/75 TN, 260/75 UA, 260/78 UA, 260/860, 260/861
• US Class Current: 528/59
• CPC Class Codes: C08G 18/6755 Unsaturated carboxylic acids
• CPC Class Codes: C08G 73/1035 from tetracarboxylic acids or derivatives and diisocyanates
• CPC Class Codes: C08G 73/12 Unsaturated polyimide precursors
• CPC Class Codes: H01B 3/306 Polyimides or polyesterimides
• CPC Class Codes: H02J 2207/20 Charging or discharging characterised by the power electronics converter
• CPC Class Codes: H02J 7/02 for charging batteries from ac mains by converters
• CPC Class Codes: Y10T 428/2933 Coated or with bond, impregnation or core

Abstract

A process for the production of polycondensates linked by nitrogen containing five membered rings, wherein a unsaturated cyclic anhydride compound is polycondensed with alcohols and organic polyisocyanates.

Claims

1. Processes for the production of a polycondensate linked through five membered nitrogen containing rings, wherein unsaturated cyclic carboxylic acid anhydride compounds corresponding to the general formula:

##STR6## in which R₁ represents a mono-unsaturated organic radical, is reacted with a monofunctional or polyfunctional aliphatic, aliphatic-aromatic or aromatic alcohol and a polyfunctional organic isocyanate at a temperature in the range from 0°

C. to 500°

C.

2. Processes as claimed in claim 1, wherein the reaction is carried out at a temperature in the range of from 30°

C. to 400°

C.

3. Processes as claimed in claim 1, wherein the alcohol is a compound of the general formula

4. Processes as claimed in claim 3, wherein the alcohol is an aliphatic diol.

5. Processes as claimed in claim 1, wherein in the general formula R₁ represents a mono-unsaturated aliphatic radical with C₂ -C₁₀.

6. Processes as claimed in claim 1 wherein the unsaturated cyclic carboxylic acid anhydride is the anhydride of maleic acid, dimethyl- or dichloro-maleic acid, citraconic acid or itaconic acid.

7. Processes as claimed in claim 1, wherein in a first step, the polyisocyanate is reacted with the alcohol to form a carbamic ester which, in a second step, is subsequently reacted with the acid anhydride.

8. Processes as claimed in claim 1, wherein, in a first step, the acid anhydride is reacted with the alcohol to form a semiester which is subsequently reacted with the polyisocyanate.

9. Processes as claimed in claim 1, wherein the polycondensation reaction is carried out in the presence of an organic polycarboxylic acid and an aliphatic polyol.

10. Processes as claimed in claim 1, wherein the polycondensation reaction is carried out in the presence of a saturated cyclic carboxylic acid anhydride.

11. Polycondensates obtained by a process claimed in claim 1.

12. A wire insulated with a polycondensate as claimed in claim 11.