Ferrous ion scrubbing of flue gas
First Claim
1. A method for regenerating a spent gas scrubbing solution to remove ferric chelates and sulfate ions therefrom comprising the steps of:
- introducing said solution into the cathode compartment of an electrochemical cell, said cell having an anode compartment separated from said cathode compartment by an ion transfer membrane;
circulating water through said anode compartment;
passing a current from said cathode compartment to said anode compartment to cause the reduction of the ferric chelates to ferrous chelates and the oxidation of water in the anode compartment to form hydrogen ion, said current causing the transportation of sulfate ions in said cathode compartment through said ion transfer membrane into said anode compartment, said sulfate ions reacting with said hydrogen ions to form sulfuric acid.
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Abstract
An apparatus and method for removing oxides of nitrogen and sulfur from flue gases. The apparatus comprises an enclosure wherein the flue gases are washed with a scrubbing solution, preferably containing ferrous chelates and sulfite ions, and an electrochemical cell for regenerating the spent scrubbing solution. The electrochemical cell preferably comprises a plurality of cathode and anode compartments separated by ion transfer membranes. The spent scrubbing solution is regenerated by passing the solution through the cathode compartments of the electrochemical cell. The regeneration process involves the removal of the sulfate ions from the scrubbing solutions through the ion transfer membranes and the reduction of the nonreactive ferric chelate to the reactive ferrous chelate.
53 Citations
13 Claims
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1. A method for regenerating a spent gas scrubbing solution to remove ferric chelates and sulfate ions therefrom comprising the steps of:
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introducing said solution into the cathode compartment of an electrochemical cell, said cell having an anode compartment separated from said cathode compartment by an ion transfer membrane; circulating water through said anode compartment; passing a current from said cathode compartment to said anode compartment to cause the reduction of the ferric chelates to ferrous chelates and the oxidation of water in the anode compartment to form hydrogen ion, said current causing the transportation of sulfate ions in said cathode compartment through said ion transfer membrane into said anode compartment, said sulfate ions reacting with said hydrogen ions to form sulfuric acid. - View Dependent Claims (2, 3, 4, 5, 10, 11)
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6. A method for removing oxides of nitrogen and sulfur from flue gas comprising the steps of:
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contacting said flue gas with a scrubbing solution comprising ferrous chelates and sulfite ions to cause the oxidation of said ferrous chelate to ferric chelate and the conversion of the oxides of sulfur into sulfate ions; passing the spent scrubbing solution including ferric chelate and sulfate ions into the cathode compartment of an electrochemical cell, said cell having an anode compartment separated from said cathode compartment by an ion transfer membrane; circulating water through said anode compartment; passing a current from said cathode compartment to said anode compartment to regenerate said spent solution by causing the reduction of said ferric chelates to ferrous chelates, said current causing the transportation of sulfate ions in said cathode compartment through said ion transfer membrane into said anode compartment to react with the hydrogen ions and form sulfuric acid. - View Dependent Claims (7, 8, 9, 12, 13)
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Specification